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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— diallyl α-phenylthio-4-pentenylphosphonate 870193-93-4 C17H23O3PS
    diallyl α-phenylthio-4-pentenylphosphonate
    —— 4-[[(3-methyl isothiazol-5-yl)methyl]sulfanyl]aniline 497853-75-5 C11H12N2S2
    4-[[(3-methyl isothiazol-5-yl)methyl]sulfanyl]aniline
    —— 6-[(3-pyridinylmethyl)sulfanyl]-3-pyridinylamine 497855-36-4 C11H11N3S
    6-[(3-pyridinylmethyl)sulfanyl]-3-pyridinylamine
    —— 3-{[4-(azetidin-3-yloxy)phenyl]thio}-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide 1018966-45-4 C21H20N8O2S3
    3-{[4-(azetidin-3-yloxy)phenyl]thio}-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide
    —— 4-{[(2-pyridyl)methyl]sulfanyl}aniline 69751-36-6 C12H12N2S
    4-{[(2-pyridyl)methyl]sulfanyl}aniline
    —— 4-[2-(4-aminophenylthio)ethyl]-4H-1,2,4-triazole 497855-10-4 C10H12N4S
    4-[2-(4-aminophenylthio)ethyl]-4H-1,2,4-triazole
    —— 4-[(1,3-thiazol-2-ylmethyl)sulfanyl]aniline 497853-74-4 C10H10N2S2
    4-[(1,3-thiazol-2-ylmethyl)sulfanyl]aniline
    —— 6-[[(1-propylimidazol-2-yl)methyl]sulfanyl]pyridine-3-amine 497853-66-4 C12H16N4S
    6-[[(1-propylimidazol-2-yl)methyl]sulfanyl]pyridine-3-amine
    —— 4-{[(2-pyridyl)sulfanyl]methyl}aniline 497851-93-1 C12H12N2S
    4-{[(2-pyridyl)sulfanyl]methyl}aniline
    —— 4-{[(1-methyl-1H-pyrazol-5-yl)methyl]sulfanyl}aniline 497855-73-9 C11H13N3S
    4-{[(1-methyl-1H-pyrazol-5-yl)methyl]sulfanyl}aniline
    —— (2-methyl-4-phenylbutan-2-yl)(p-tolyl)sulfane 1025927-62-1 C18H22S
    (2-methyl-4-phenylbutan-2-yl)(p-tolyl)sulfane
    —— 4-[2-(4-propyl-4H-1,2,4-triazol-3-yl) ethylthio]aniline 497851-62-4 C13H18N4S
    4-[2-(4-propyl-4H-1,2,4-triazol-3-yl) ethylthio]aniline
    —— 6-[[(1-propylimidazol-5-yl)methyl]sulfanyl]pyridine-3-amine 497853-67-5 C12H16N4S
    6-[[(1-propylimidazol-5-yl)methyl]sulfanyl]pyridine-3-amine
    —— 4-{[(1-ethyl-1H-imidazol-5-yl)methyl]sulfanyl}aniline 497853-80-2 C12H15N3S
    4-{[(1-ethyl-1H-imidazol-5-yl)methyl]sulfanyl}aniline
    —— 5-amino-2-(4-propyl-4H-1,2,4-triazol-3-yl) methylthiopyridine 497854-82-7 C11H15N5S
    5-amino-2-(4-propyl-4H-1,2,4-triazol-3-yl) methylthiopyridine
    —— 4-[[[5-(trifluoromethyl)-2-pyridinyl]sulfanyl]methyl]aniline 497851-95-3 C13H11F3N2S
    4-[[[5-(trifluoromethyl)-2-pyridinyl]sulfanyl]methyl]aniline
    —— Boc-D-valine thioamide 143364-86-7 C10H20N2O2S
    Boc-D-valine thioamide
    —— 1-<4-Methylmercapto-phenyl>-biguanid 46456-71-7 C9H13N5S
    1-<4-Methylmercapto-phenyl>-biguanid
    —— 1-benzyl-4-methylthio-5-fluoropyrimidin-2-one 81560-12-5 C12H11FN2OS
    1-benzyl-4-methylthio-5-fluoropyrimidin-2-one
    —— 2-benzylthio-5-chloropyrimidine 79685-96-4 C11H9ClN2S
    2-benzylthio-5-chloropyrimidine
    —— 4-(3-Fluorophenyl)-3-[5-[4-(3-fluorophenyl)-5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazol-3-yl]pentyl]-5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazole 128156-11-6 C35H24F8N8O4S2
    4-(3-Fluorophenyl)-3-[5-[4-(3-fluorophenyl)-5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazol-3-yl]pentyl]-5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazole
    —— (R)-2-Chloro-thiirane 1,1-dioxide 10038-13-8 C2H3ClO2S
    (R)-2-Chloro-thiirane 1,1-dioxide
    —— 3-(2,4-Dinitrophenyl)sulfanyl-5-[5-[5-(2,4-dinitrophenyl)sulfanyl-4-phenyl-1,2,4-triazol-3-yl]pentyl]-4-phenyl-1,2,4-triazole 128156-01-4 C33H26N10O8S2
    3-(2,4-Dinitrophenyl)sulfanyl-5-[5-[5-(2,4-dinitrophenyl)sulfanyl-4-phenyl-1,2,4-triazol-3-yl]pentyl]-4-phenyl-1,2,4-triazole
    —— 3-[2-Nitro-4-(trifluoromethyl)phenyl]sulfanyl-5-[5-[5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-4-phenyl-1,2,4-triazol-3-yl]pentyl]-4-phenyl-1,2,4-triazole 128156-00-3 C35H26F6N8O4S2
    3-[2-Nitro-4-(trifluoromethyl)phenyl]sulfanyl-5-[5-[5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-4-phenyl-1,2,4-triazol-3-yl]pentyl]-4-phenyl-1,2,4-triazole
    —— 3-(2,4-Dinitrophenyl)sulfanyl-5-[5-[5-(2,4-dinitrophenyl)sulfanyl-4-(3-fluorophenyl)-1,2,4-triazol-3-yl]pentyl]-4-(3-fluorophenyl)-1,2,4-triazole 128156-13-8 C33H24F2N10O8S2
    3-(2,4-Dinitrophenyl)sulfanyl-5-[5-[5-(2,4-dinitrophenyl)sulfanyl-4-(3-fluorophenyl)-1,2,4-triazol-3-yl]pentyl]-4-(3-fluorophenyl)-1,2,4-triazole
    —— 4-(3-Fluorophenyl)-3-[5-[4-(3-fluorophenyl)-5-(4-nitrophenyl)sulfanyl-1,2,4-triazol-3-yl]pentyl]-5-(4-nitrophenyl)sulfanyl-1,2,4-triazole 128156-12-7 C33H26F2N8O4S2
    4-(3-Fluorophenyl)-3-[5-[4-(3-fluorophenyl)-5-(4-nitrophenyl)sulfanyl-1,2,4-triazol-3-yl]pentyl]-5-(4-nitrophenyl)sulfanyl-1,2,4-triazole
    —— Cyclobutanemethanamine, 1-(ethylsulfonyl)- 1779131-51-9 C7H15NO2S
    Cyclobutanemethanamine, 1-(ethylsulfonyl)-
    —— 2-fluoro-4-phenylsulphanylaniline 76105-39-0 C12H10FNS
    2-fluoro-4-phenylsulphanylaniline
    —— 2-chloro-4-(methylthio)nicotinonitrile 1257072-10-8 C7H5ClN2S
    2-chloro-4-(methylthio)nicotinonitrile
    —— 131136-76-0 C4H6S
    —— Trifluoro-methanesulfonic acid 8-nitro-5-oxo-2,3-dihydro-5H-thiazolo[3,2-a]pyridin-7-yl ester 1303510-60-2 C8H5F3N2O6S2
    Trifluoro-methanesulfonic acid 8-nitro-5-oxo-2,3-dihydro-5H-thiazolo[3,2-a]pyridin-7-yl ester
    —— 1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-(3-(trifluoromethyl)phenyl)thiourea 1395063-26-9 C24H21F3N4OS2
    1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-(3-(trifluoromethyl)phenyl)thiourea
    —— 1-(4-chloro-3-(trifluoromethyl)phenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea 1395063-30-5 C24H20ClF3N4OS2
    1-(4-chloro-3-(trifluoromethyl)phenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea
    —— 1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-m-tolylthiourea 1417341-33-3 C24H24N4OS2
    1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-m-tolylthiourea
    —— 1-(3,5-bis(trifluoromethyl)phenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea 1417341-32-2 C25H20F6N4OS2
    1-(3,5-bis(trifluoromethyl)phenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea
    —— 1-(4-fluorophenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)-pyridin-4-ylthio)phenyl)thiourea 1395063-29-2 C23H21FN4OS2
    1-(4-fluorophenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)-pyridin-4-ylthio)phenyl)thiourea
    —— 1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-(4-(trifluoromethoxy)phenyl)thiourea 1395063-33-8 C24H21F3N4O2S2
    1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-(4-(trifluoromethoxy)phenyl)thiourea
    —— 3-benzyl-5-bromo-2-(methylthio)pyrimidin-4(3H)-one 1036763-71-9 C12H11BrN2OS
    3-benzyl-5-bromo-2-(methylthio)pyrimidin-4(3H)-one
    —— bis{6-[6-(2-pyridyl)-4-pyrimidinyl]-2-pyridyl} sulfide 350253-46-2 C28H18N8S
    bis{6-[6-(2-pyridyl)-4-pyrimidinyl]-2-pyridyl} sulfide
    —— N-hydroxy-N-[3-(methylsulfonyl)propyl]acetamide 1003599-76-5 C6H13NO4S
    N-hydroxy-N-[3-(methylsulfonyl)propyl]acetamide
    —— 3,3,5,5-tetramethyl-3,5-dihydro-4H-pyrazole-4-thione S-oxide 65927-19-7 C7H12N2OS
    3,3,5,5-tetramethyl-3,5-dihydro-4H-pyrazole-4-thione S-oxide
    —— Bisaldicarb sulfide 51717-80-7 C14H26N4O4S3
    Bisaldicarb sulfide
    —— 2-(vinylsulfonyl)acetic acid 20854-29-9 C4H6O4S
    2-(vinylsulfonyl)acetic acid
    —— Trimethyl-3,4,4-cyclopenten-2-thion 30221-53-5 C8H12S
    Trimethyl-3,4,4-cyclopenten-2-thion
    —— 2.7-Diaza-phenothiazin 262-01-1 C10H7N3S
    2.7-Diaza-phenothiazin
    —— 1,1,3,3,7,7-hexamethyl-8-oxo-8λ<sup>4</sup>-thia-5,6-diaza-spiro[3.4]oct-5-en-2-one 39257-47-1 C11H18N2O2S
    1,1,3,3,7,7-hexamethyl-8-oxo-8λ<sup>4</sup>-thia-5,6-diaza-spiro[3.4]oct-5-en-2-one
    —— 3,3,6,6,9,9-hexamethyl-4-thia-1,2,7,8-tetraaza-spiro[4.4]nona-1,7-diene 4-oxide 65927-20-0 C10H18N4OS
    3,3,6,6,9,9-hexamethyl-4-thia-1,2,7,8-tetraaza-spiro[4.4]nona-1,7-diene 4-oxide
    —— 2-Vinylsulfonyl-essigsaeure-aethylester 20854-28-8 C6H10O4S
    2-Vinylsulfonyl-essigsaeure-aethylester
    —— 2-chloromethyl-1,3-dithiepane 54237-86-4 C6H11ClS2
    2-chloromethyl-1,3-dithiepane
    —— N-Acetyl-2-vinyl-sulfonyl-aethylamin 20854-27-7 C6H11NO3S
    N-Acetyl-2-vinyl-sulfonyl-aethylamin