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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-methyl-3-phenylsulfanyl-pyridine 1-oxide 1350294-25-5 C12H11NOS
    2-methyl-3-phenylsulfanyl-pyridine 1-oxide
    —— 3,7-bis[(2-bromo-5-octylphenyl)thio]benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylic acid 1618666-20-8 C40H44Br2O4S4
    3,7-bis[(2-bromo-5-octylphenyl)thio]benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylic acid
    —— ((Z)-2-Cyclohexyl-2-ethoxy-vinylsulfanyl)-benzene 89005-25-4 C16H22OS
    ((Z)-2-Cyclohexyl-2-ethoxy-vinylsulfanyl)-benzene
    —— 3-(2-methylsulfanyl-pyrimidin-4-yl)-1-oxo-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazole-2-carboxylic acid 2-chloro-benzylamide 852164-86-4 C19H18ClN5O2S
    3-(2-methylsulfanyl-pyrimidin-4-yl)-1-oxo-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazole-2-carboxylic acid 2-chloro-benzylamide
    —— 1-(2-cyanoethyl)-2-(4-nitrophenylthio)-imidazole 683276-73-5 C12H10N4O2S
    1-(2-cyanoethyl)-2-(4-nitrophenylthio)-imidazole
    —— (<i>E</i>)-2,3-dimethyl-1-methylsulfanyl-buta-1,3-diene 39198-73-7 C7H12S
    (<i>E</i>)-2,3-dimethyl-1-methylsulfanyl-buta-1,3-diene
    —— 3-(2-aminophenylthio)-1-(2,4-dimethoxypyrimidin-5-yl)prop-1-yne 260803-80-3 C15H15N3O2S
    3-(2-aminophenylthio)-1-(2,4-dimethoxypyrimidin-5-yl)prop-1-yne
    —— (1'R,2R,3R,4S,5S)-4-azido-2-(1'-hydroxy-2',2'-bis-phenylsulfanylethyl)-5-methoxy-tetrahydropyran-3-ol 828914-54-1 C20H23N3O4S2
    (1'R,2R,3R,4S,5S)-4-azido-2-(1'-hydroxy-2',2'-bis-phenylsulfanylethyl)-5-methoxy-tetrahydropyran-3-ol
    —— 4H-1,2,4-Triazol-3-amine, 4-methyl-5-[(phenylmethyl)thio]- 87866-45-3 C10H12N4S
    4H-1,2,4-Triazol-3-amine, 4-methyl-5-[(phenylmethyl)thio]-
    —— (5-Benzylsulfanyl-4-methyl-4H-[1,2,4]triazol-3-yl)-[1-phenyl-meth-(Z)-ylidene]-amine 99472-19-2 C17H16N4S
    (5-Benzylsulfanyl-4-methyl-4H-[1,2,4]triazol-3-yl)-[1-phenyl-meth-(Z)-ylidene]-amine
    —— N,N'-ethylene-4-nitro-2,2'-thiodibenzamide 1393085-57-8 C16H13N3O4S
    N,N'-ethylene-4-nitro-2,2'-thiodibenzamide
    —— 2-methylthio-4-vinylpyrimidine 131467-05-5 C7H8N2S
    2-methylthio-4-vinylpyrimidine
    —— 1-methyl-2-nitro-4-(phenylthio)benzene 1240287-70-0 C13H11NO2S
    1-methyl-2-nitro-4-(phenylthio)benzene
    —— 3-<(3,4-Dioxo-2-phenylcyclobut-1-enylthio)methyl>-4-phenylcyclobuten-1,2-dion 81758-67-0 C21H12O4S
    3-<(3,4-Dioxo-2-phenylcyclobut-1-enylthio)methyl>-4-phenylcyclobuten-1,2-dion
    —— 7-(4-aminophenylthio)-1H-imidazo[4,5-b]pyridin-2(3H)-one 1147504-07-1 C12H10N4OS
    7-(4-aminophenylthio)-1H-imidazo[4,5-b]pyridin-2(3H)-one
    —— [(R)-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-ylmethyl]-urea 1231765-11-9 C18H19FN2OS
    [(R)-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-ylmethyl]-urea
    —— [(R)-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-yl-methyl]amine hydrochloride 1231765-10-8 C17H18FNS*ClH
    [(R)-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-yl-methyl]amine hydrochloride
    —— (S)-3-[3-(o-bromophenylthio)butanoyl]oxazolidin-2-one 1334952-07-6 C13H14BrNO3S
    (S)-3-[3-(o-bromophenylthio)butanoyl]oxazolidin-2-one
    —— 3-(allyloxy)-2-(methylsulfanyl)-N-[2-(vinyloxy)ethyl]pyrrole 1252928-26-9 C12H17NO2S
    3-(allyloxy)-2-(methylsulfanyl)-N-[2-(vinyloxy)ethyl]pyrrole
    —— 132491-46-4 C25H32S4Si
    —— 4,5-bis(hexylthio)-1,3-dithiole-2-thione 149468-17-7 C15H26S5
    4,5-bis(hexylthio)-1,3-dithiole-2-thione
    —— 132491-47-5 C25H28O2S4
    —— 4-{3-[(4-bromo-2-chlorophenyl)thio]phenyl}tetrahydro-2H-pyran-4-carboxamide 1159186-47-6 C18H17BrClNO2S
    4-{3-[(4-bromo-2-chlorophenyl)thio]phenyl}tetrahydro-2H-pyran-4-carboxamide
    —— 3-phenyl-2-(phenylsufanyl)benzo[b]thiophene 77128-61-1 C20H14S2
    3-phenyl-2-(phenylsufanyl)benzo[b]thiophene
    —— 2-[2-(1-Cyano-3,3-dimethyl-2-oxobutylidene)-4,8-dihydroxy-[1,3]dithiolo[4,5-f][1,3]benzodithiol-6-ylidene]-4,4-dimethyl-3-oxopentanenitrile 1118625-18-5 C22H20N2O4S4
    2-[2-(1-Cyano-3,3-dimethyl-2-oxobutylidene)-4,8-dihydroxy-[1,3]dithiolo[4,5-f][1,3]benzodithiol-6-ylidene]-4,4-dimethyl-3-oxopentanenitrile
    —— 2-ethylsulfanyl-4-methyl-pyrimidine 61767-95-1 C7H10N2S
    2-ethylsulfanyl-4-methyl-pyrimidine
    —— (Z)-1-[tert-butyl(dimethyl)silyl]-3-phenylsulfanylprop-2-en-1-one 152452-57-8 C15H22OSSi
    (Z)-1-[tert-butyl(dimethyl)silyl]-3-phenylsulfanylprop-2-en-1-one
    —— (E)-4-[tert-butyl(dimethyl)silyl]-4-hydroxy-6-phenylsulfanylhex-5-en-2-one 416893-36-2 C18H28O2SSi
    (E)-4-[tert-butyl(dimethyl)silyl]-4-hydroxy-6-phenylsulfanylhex-5-en-2-one
    —— Tert-butyl-[4-(4-fluorophenyl)sulfanyl-2,3,5,6-tetramethylphenoxy]-dimethylsilane 196944-23-7 C22H31FOSSi
    Tert-butyl-[4-(4-fluorophenyl)sulfanyl-2,3,5,6-tetramethylphenoxy]-dimethylsilane
    —— Tert-butyl-dimethyl-(2,3,5-trimethyl-4-phenylsulfanyl-6-prop-2-enylphenoxy)silane 1026485-13-1 C24H34OSSi
    Tert-butyl-dimethyl-(2,3,5-trimethyl-4-phenylsulfanyl-6-prop-2-enylphenoxy)silane
    —— (1R)-1-(tert-butyldimethylsiloxy)-N,N-dimethylamino-1-<(4-methylphenyl)sulfanyl>acetamide 150334-50-2 C17H29NO2SSi
    (1R)-1-(tert-butyldimethylsiloxy)-N,N-dimethylamino-1-<(4-methylphenyl)sulfanyl>acetamide
    —— 2-chloro-1-(phenylthio)hexane 163840-05-9 C12H17ClS
    2-chloro-1-(phenylthio)hexane
    —— Ethyl 3-methyl-4-phenylsulfanylbutanoate 90696-17-6 C13H18O2S
    Ethyl 3-methyl-4-phenylsulfanylbutanoate
    —— 1,4-Bis-methylmercapto-octafluorbutan 3492-10-2 C6H6F8S2
    1,4-Bis-methylmercapto-octafluorbutan
    —— 1,4-bis(4-fluorophenylthio)perfluorobutane 130028-66-9 C16H8F10S2
    1,4-bis(4-fluorophenylthio)perfluorobutane
    —— 1-Phenylnon-1-en-2-ylsulfanylbenzene 153215-20-4 C21H26S
    1-Phenylnon-1-en-2-ylsulfanylbenzene
    —— (S)-2-(1-(4-chloro-3-fluorophenyl)-2-hydroxyethyl)-5-(2-(methylthio)pyrimidin-4-yl)pyridazin-3(2H)-one 1453852-65-7 C17H14ClFN4O2S
    (S)-2-(1-(4-chloro-3-fluorophenyl)-2-hydroxyethyl)-5-(2-(methylthio)pyrimidin-4-yl)pyridazin-3(2H)-one
    —— 3,3-bis-phenylsulfanyl-undecan-4-ol 62870-20-6 C23H32OS2
    3,3-bis-phenylsulfanyl-undecan-4-ol
    —— 1-<1-(Phenylthio)-cyclohexyl>-propanon 71221-53-9 C15H20OS
    1-<1-(Phenylthio)-cyclohexyl>-propanon
    —— 3-Phenylthiodecan-4-on 71221-51-7 C16H24OS
    3-Phenylthiodecan-4-on
    —— 3,3-Bis-(phenylthio)-pentan-2-on 71221-39-1 C17H18OS2
    3,3-Bis-(phenylthio)-pentan-2-on
    —— 6-methyl-4-phenylthioheptan-3-one 98711-90-1 C14H20OS
    6-methyl-4-phenylthioheptan-3-one
    —— 3-Phenylmethyl-3-phenylthio-pentan-2-on 71221-47-1 C18H20OS
    3-Phenylmethyl-3-phenylthio-pentan-2-on
    —— 2,2-bis(phenylthio)-1-phenylbutane 77815-66-8 C22H22S2
    2,2-bis(phenylthio)-1-phenylbutane
    —— 2,2-Bisphenylthiobutan-1-ol 71221-38-0 C16H18OS2
    2,2-Bisphenylthiobutan-1-ol
    —— 1-Phenyl-2,2-bis-(phenylthio)-<1-D>-butan-1-ol 71221-41-5 C22H22OS2
    1-Phenyl-2,2-bis-(phenylthio)-<1-D>-butan-1-ol
    —— 3-(Phenylsulfanyl)undecan-4-one 62870-23-9 C17H26OS
    3-(Phenylsulfanyl)undecan-4-one
    —— 6-methyl-3,3-bisphenylthioheptan-4-ol 88065-30-9 C20H26OS2
    6-methyl-3,3-bisphenylthioheptan-4-ol
    —— 3-methyl-2,4,4-tris(phenylthio)hexanal 128099-07-0 C25H26OS3
    3-methyl-2,4,4-tris(phenylthio)hexanal
    —— (E)-hex-2-ene-3,4-diylbis(phenylsulfane) 98793-21-6 C18H20S2
    (E)-hex-2-ene-3,4-diylbis(phenylsulfane)