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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5-Nonyl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid ethyl ester 221356-25-8 C15H26N2O2S2
    (5-Nonyl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid ethyl ester
    —— 1-ethyl-1-propenylthiobenzene 99965-74-9 C11H14S
    1-ethyl-1-propenylthiobenzene
    —— 5-(5-((2-chlorobenzyl)thio)-4-cyclopropyl-4H-1,2,4-triazol-3-yl)-4-methyl-1,2,3-thiadiazole 1352551-68-8 C15H14ClN5S2
    5-(5-((2-chlorobenzyl)thio)-4-cyclopropyl-4H-1,2,4-triazol-3-yl)-4-methyl-1,2,3-thiadiazole
    —— 9,13-dimethyl-1,5-dithia-dispiro[5.1.5.1]tetradecan-7-one 56063-34-4 C14H22OS2
    9,13-dimethyl-1,5-dithia-dispiro[5.1.5.1]tetradecan-7-one
    —— 2,6-bis[(phenylthio)methyl]phenyl phenyl telluride 201865-06-7 C26H22S2Te
    2,6-bis[(phenylthio)methyl]phenyl phenyl telluride
    —— 2-(2,4-Dinitrophenylthio)-3-benzyl-4(3H)-chinazolinon 70927-79-6 C21H14N4O5S
    2-(2,4-Dinitrophenylthio)-3-benzyl-4(3H)-chinazolinon
    —— 2-Methyl-2-propanyl {trans-4-[(methylsulfonyl)amino]cyclohexyl}carbamate 251947-23-6 C12H24N2O4S
    2-Methyl-2-propanyl {trans-4-[(methylsulfonyl)amino]cyclohexyl}carbamate
    —— N,N-Diisopropyl-thiocarbaminsaeure-S-pentylester 100387-12-0 C12H25NOS
    N,N-Diisopropyl-thiocarbaminsaeure-S-pentylester
    —— 3-phenyl-3-phenylsulfanyl-1-pyrrolidin-1-ylpropan-1-one 99507-55-8 C19H21NOS
    3-phenyl-3-phenylsulfanyl-1-pyrrolidin-1-ylpropan-1-one
    —— S-(5,5-Dichlor-penten-(4)-yl-(1))-isothioharnstoff 92576-63-1 C6H10Cl2N2S
    S-(5,5-Dichlor-penten-(4)-yl-(1))-isothioharnstoff
    —— 1,1-bis-ethanesulfonyl-D-1-deoxy-arabinitol 31818-57-2 C9H20O8S2
    1,1-bis-ethanesulfonyl-D-1-deoxy-arabinitol
    —— dipropyl-thiocarbamic acid <i>S</i>-<i>tert</i>-pentyl ester 100387-15-3 C12H25NOS
    dipropyl-thiocarbamic acid <i>S</i>-<i>tert</i>-pentyl ester
    —— (4-{4-[3-(2-nitrophenyl)-1-(3-phenylpropyl)ureido]phenylsulphanyl}phenyl)acetic acid 735314-14-4 C30H27N3O5S
    (4-{4-[3-(2-nitrophenyl)-1-(3-phenylpropyl)ureido]phenylsulphanyl}phenyl)acetic acid
    —— 2-(hexylthio)-1-methylbenzene 59693-89-9 C13H20S
    2-(hexylthio)-1-methylbenzene
    —— 1-Benzyl-3,4-bis-hexadecyloxy-2,5-bis-phenylsulfanylmethyl-1H-pyrrole 210431-57-5 C57H87NO2S2
    1-Benzyl-3,4-bis-hexadecyloxy-2,5-bis-phenylsulfanylmethyl-1H-pyrrole
    —— 5-chloro-3-(2-(methylthio)phenyl)-2,1-benzisoxazole 94100-13-7 C14H10ClNOS
    5-chloro-3-(2-(methylthio)phenyl)-2,1-benzisoxazole
    —— N-[5-(4-methoxyphenylsulfanyl)thiazol-2-yl]-3-phenylpropionamide 1384184-07-9 C19H18N2O2S2
    N-[5-(4-methoxyphenylsulfanyl)thiazol-2-yl]-3-phenylpropionamide
    —— 5-(4-methylmercaptophenyl)-3-(2-thienyl)-pyrazoline 1097966-24-9 C14H14N2S2
    5-(4-methylmercaptophenyl)-3-(2-thienyl)-pyrazoline
    —— 6-benzylsulfanyl-2,4-bis(pyrrolidinocarbonylmethylsulfanyl)pyrimidine-5-carbonitrile 948046-75-1 C24H27N5O2S3
    6-benzylsulfanyl-2,4-bis(pyrrolidinocarbonylmethylsulfanyl)pyrimidine-5-carbonitrile
    —— 2-(6-methoxybenzo[d][1,3]dioxol-5-ylthio)-1-(4-methoxybenzyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061318-40-8 C22H20N4O4S
    2-(6-methoxybenzo[d][1,3]dioxol-5-ylthio)-1-(4-methoxybenzyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— tris(phenylthiomethyl)phosphane selenide 186770-43-4 C21H21PS3Se
    tris(phenylthiomethyl)phosphane selenide
    —— 8-methyl-6-(2,4-dimethylimidazol-1-yl)-(4H)-3,1-benzothiazin-2-thione 145622-91-9 C14H15N3S2
    8-methyl-6-(2,4-dimethylimidazol-1-yl)-(4H)-3,1-benzothiazin-2-thione
    —— (R)-N-<2-methyl-1-(phenylthio)heptan-2-yl>acetamide 136904-22-8 C16H25NOS
    (R)-N-<2-methyl-1-(phenylthio)heptan-2-yl>acetamide
    —— 1-((Z)-1-Chloromethyl-2-methoxy-vinylsulfanyl)-4-methyl-benzene 116859-04-2 C11H13ClOS
    1-((Z)-1-Chloromethyl-2-methoxy-vinylsulfanyl)-4-methyl-benzene
    —— 1-(3-Bromo-4-(phenylthio)cyclohexa-1,3-dienyl)ethanone 85972-24-3 C14H13BrOS
    1-(3-Bromo-4-(phenylthio)cyclohexa-1,3-dienyl)ethanone
    —— trans-1-p-tolylthio-2-(p-bromophenylthio)ethene 120166-51-0 C15H13BrS2
    trans-1-p-tolylthio-2-(p-bromophenylthio)ethene
    —— [MoTl(SC6F5)4(η-C5H5)] 113095-64-0 C29H5F20MoS4Tl
    [MoTl(SC6F5)4(η-C5H5)]
    —— 71921-47-6 C21H17N5O5S
    —— 2-(1-hydroxyethyl)-2-methyl-3-(phenylthio)cyclohexanone 74457-15-1 C15H20O2S
    2-(1-hydroxyethyl)-2-methyl-3-(phenylthio)cyclohexanone
    —— N-[4-[4-[(5-methyl-1H-pyrazol-3-yl)amino]-6-(3-methyl-3-pyrrolidin-1-ylazetidin-1-yl)pyrimidin-2-yl]sulfanylphenyl]propanamide 936848-71-4 C25H32N8OS
    N-[4-[4-[(5-methyl-1H-pyrazol-3-yl)amino]-6-(3-methyl-3-pyrrolidin-1-ylazetidin-1-yl)pyrimidin-2-yl]sulfanylphenyl]propanamide
    —— 6H,12H,18H-Tribenzo<b,f,j><1,5,9>trithiacyclododecin 260-08-2 C21H18S3
    6H,12H,18H-Tribenzo<b,f,j><1,5,9>trithiacyclododecin
    —— 7-exo-t-butylbicyclo<3.3.1>nonane-3-exo-carboxylic acid 82570-57-8 C14H24O2
    7-exo-t-butylbicyclo<3.3.1>nonane-3-exo-carboxylic acid
    —— N,N'-di-2-methylcyclohexylthiourea 64011-31-0 C15H28N2S
    N,N'-di-2-methylcyclohexylthiourea
    —— S-Octyl-dithiobiuret 40218-80-2 C10H21N3S2
    S-Octyl-dithiobiuret
    —— Methyl-carbamic acid 2-(1,1,2,2-tetrachloro-ethyldisulfanyl)-ethyl ester 1185-48-4 C6H9Cl4NO2S2
    Methyl-carbamic acid 2-(1,1,2,2-tetrachloro-ethyldisulfanyl)-ethyl ester
    —— methyl (E)-2-(2-phenylthiocycloheptylidene)propionate 1194360-71-8 C17H22O2S
    methyl (E)-2-(2-phenylthiocycloheptylidene)propionate
    —— 1103976-16-4 C16H12ClNO2S
    —— 2-Fluor-5-methylthiothiophen 32415-87-5 C5H5FS2
    2-Fluor-5-methylthiothiophen
    —— 3-<(n-butylthio)methylidene>-9,9-(ethylenedithio)-1,4,4aβ,5,6,6aα,7,9,10,11,11aβ,12,12aβ,12bα-tetradecahydrobenz<a>anthracen-2(3H)-one 108121-15-9 C25H36OS3
    3-<(n-butylthio)methylidene>-9,9-(ethylenedithio)-1,4,4aβ,5,6,6aα,7,9,10,11,11aβ,12,12aβ,12bα-tetradecahydrobenz<a>anthracen-2(3H)-one
    —— (Z)-8-azido-3-(phenylthio)-1,3-octadiene 123289-36-1 C14H17N3S
    (Z)-8-azido-3-(phenylthio)-1,3-octadiene
    —— (4S)-4-benzyl-3-[2-(phenylthio)propanoyl]oxazolidin-2-one 1262022-51-4 C19H19NO3S
    (4S)-4-benzyl-3-[2-(phenylthio)propanoyl]oxazolidin-2-one
    —— (2R,3R,4S,5S)-3,4-dihydroxy-N-(2,2-diethoxycarbonylvinyl)-5-hydroxymethyl-2-p-tolylthiopyrrolidine 1258505-45-1 C20H27NO7S
    (2R,3R,4S,5S)-3,4-dihydroxy-N-(2,2-diethoxycarbonylvinyl)-5-hydroxymethyl-2-p-tolylthiopyrrolidine
    —— 79093-33-7 C11H14O2S2
    —— Heptafluorbuttersaeure-2-aminobenzolthiolester 36858-63-6 C10H6F7NOS
    Heptafluorbuttersaeure-2-aminobenzolthiolester
    —— 1,4-Bis-(2-methyl-<1,3>dithian-2-yl)-butan 5012-00-0 C14H26S4
    1,4-Bis-(2-methyl-<1,3>dithian-2-yl)-butan
    —— 2-(2,4-Dinitrophenylthio)-3-(m-tolyl)-4(3H)-chinazolinon 70927-82-1 C21H14N4O5S
    2-(2,4-Dinitrophenylthio)-3-(m-tolyl)-4(3H)-chinazolinon
    —— 6-methyl-7<i>H</i>-benzo[<i>b</i>]chromeno[4,3-<i>e</i>][1,4]thiazepine 53244-76-1 C17H13NOS
    6-methyl-7<i>H</i>-benzo[<i>b</i>]chromeno[4,3-<i>e</i>][1,4]thiazepine
    —— methyl 2-{[4-(quinolin-2-ylmethoxy)phenyl]sulfanyl}benzoate 252973-00-5 C24H19NO3S
    methyl 2-{[4-(quinolin-2-ylmethoxy)phenyl]sulfanyl}benzoate
    —— 2,13,19,30-tetraoxa-5,10,22,27,36,38-hexathia-7,8,16,24,25,33,35,37-octazapentacyclo[29.3.1.16,9.114,18.123,26]octatriaconta-1(34),6,8,14,16,18(37),23,25,31(35),32-decaene 132424-65-8 C20H20N8O4S6
    2,13,19,30-tetraoxa-5,10,22,27,36,38-hexathia-7,8,16,24,25,33,35,37-octazapentacyclo[29.3.1.16,9.114,18.123,26]octatriaconta-1(34),6,8,14,16,18(37),23,25,31(35),32-decaene
    —— 2,2,4,4-tetramethyl-5-[2-(2-methyl-[1,3]dithian-2-yl)-ethyl]-[1,3]dioxolane 56881-98-2 C14H26O2S2
    2,2,4,4-tetramethyl-5-[2-(2-methyl-[1,3]dithian-2-yl)-ethyl]-[1,3]dioxolane