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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-Methyl-phenylmercapto)-1-dimethylamino-aethan 153914-75-1 C11H17NS
    2-(4-Methyl-phenylmercapto)-1-dimethylamino-aethan
    —— Tris(trimethylsilyl)(phenylthio)methane 87729-80-4 C16H32SSi3
    Tris(trimethylsilyl)(phenylthio)methane
    —— (E)-1-(phenylthio)-N-methyl-4-hydroxy-1-hexene-2-carboxamide 105970-85-2 C14H19NO2S
    (E)-1-(phenylthio)-N-methyl-4-hydroxy-1-hexene-2-carboxamide
    —— (E)-1-(phenylthio)-N-methyl-1-butene-2-carboxamide 105970-80-7 C12H15NOS
    (E)-1-(phenylthio)-N-methyl-1-butene-2-carboxamide
    —— 2-ethynyl-2-methyldithiolane 183270-70-4 C6H8S2
    2-ethynyl-2-methyldithiolane
    —— 1,1-bis(p-tolylthio)-2-<(benzyloxy)methoxy>octane 91191-97-8 C30H38O2S2
    1,1-bis(p-tolylthio)-2-<(benzyloxy)methoxy>octane
    —— 7-methoxy-6-(2-morpholinoethoxy)-4-(thiazol-2-ylthio)quinazoline 1234579-16-8 C18H20N4O3S2
    7-methoxy-6-(2-morpholinoethoxy)-4-(thiazol-2-ylthio)quinazoline
    —— 2-(benzyloxymethylthio)-6-benzyluracil 1616298-80-6 C19H16F2N2O2S
    2-(benzyloxymethylthio)-6-benzyluracil
    —— 4-{2-[5-(2-phenylthiazol-4-yl)-1,3,4-oxadiazol-2-ylthio]ethyl}morpholine 1416716-49-8 C17H18N4O2S2
    4-{2-[5-(2-phenylthiazol-4-yl)-1,3,4-oxadiazol-2-ylthio]ethyl}morpholine
    —— 2-(benzyloxymethylthio)-6-(3,5-dimethylbenzyl)uracil 1616298-64-6 C21H22N2O2S
    2-(benzyloxymethylthio)-6-(3,5-dimethylbenzyl)uracil
    —— {2-[3-(3-hydroxy-phenyl)-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl]benzyl}carbamic acid tert-butyl ester 946051-01-0 C24H24N4O3S
    {2-[3-(3-hydroxy-phenyl)-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl]benzyl}carbamic acid tert-butyl ester
    —— 6-methoxy-7-(2-morpholinoethoxy)-4-(thiazol-2-ylthio)quinazoline 1370256-60-2 C18H20N4O3S2
    6-methoxy-7-(2-morpholinoethoxy)-4-(thiazol-2-ylthio)quinazoline
    —— 5-[(E)-2-(ethoxycarbonyl)ethenyl]-1-methoxymethyl-2-phenylsulfanyl-1H-imidazole 460990-46-9 C16H18N2O3S
    5-[(E)-2-(ethoxycarbonyl)ethenyl]-1-methoxymethyl-2-phenylsulfanyl-1H-imidazole
    —— 5-formyl-1-methoxymethyl-2-phenylsulfanyl-1H-imidazole 460990-43-6 C12H12N2O2S
    5-formyl-1-methoxymethyl-2-phenylsulfanyl-1H-imidazole
    —— (2-{3-[3-(2-morpholin-4-yl-ethoxy)phenyl]-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl}benzyl)carbamic acid tert-butyl ester 946051-02-1 C30H35N5O4S
    (2-{3-[3-(2-morpholin-4-yl-ethoxy)phenyl]-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl}benzyl)carbamic acid tert-butyl ester
    —— 2-[(R)-2-(2-hydroxy-2-phenylethyl)-1,3-dithian-2-yl]phenol 475644-95-2 C18H20O2S2
    2-[(R)-2-(2-hydroxy-2-phenylethyl)-1,3-dithian-2-yl]phenol
    —— 10,15-dihydrotribenzo<b,d,h><1,6>dithiecin 22887-76-9 C20H16S2
    10,15-dihydrotribenzo<b,d,h><1,6>dithiecin
    —— o-(Methylamino)phenylphenylsulfid 54287-73-9 C13H13NS
    o-(Methylamino)phenylphenylsulfid
    —— (5-Amino-3-methylsulfanyl-1,2,4-triazol-1-yl)-(5-methyl-3-phenyl-1,2-oxazol-4-yl)methanone 110984-36-6 C14H13N5O2S
    (5-Amino-3-methylsulfanyl-1,2,4-triazol-1-yl)-(5-methyl-3-phenyl-1,2-oxazol-4-yl)methanone
    —— 4-Acetoxy-2-(phenylthio)butanal 59377-55-8 C12H14O3S
    4-Acetoxy-2-(phenylthio)butanal
    —— 5-[(3-hydroxyphenyl)thio]-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)thieno[2,3-d]pyrimidine-2,4-(1H,3H)-dione 216685-47-1 C28H26N2O3S2
    5-[(3-hydroxyphenyl)thio]-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)thieno[2,3-d]pyrimidine-2,4-(1H,3H)-dione
    —— 4-{3-[3-(2-morpholin-4-yl-ethoxy)-phenyl]-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl}-phenylamine 1241507-40-3 C24H25N5O2S
    4-{3-[3-(2-morpholin-4-yl-ethoxy)-phenyl]-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl}-phenylamine
    —— methyl 3,5-dibromo-4-(3-isopropyl-4-methoxyphenylthio)phenylacetate 155780-42-0 C19H20Br2O3S
    methyl 3,5-dibromo-4-(3-isopropyl-4-methoxyphenylthio)phenylacetate
    —— 5(R)-Isoxazol-3-yloxymethyl-3-(4-methylthiophenyl)oxazolidin-2-one 252260-26-7 C14H14N2O4S
    5(R)-Isoxazol-3-yloxymethyl-3-(4-methylthiophenyl)oxazolidin-2-one
    —— 2-methylsulphenyl-4-methylamino-5-methyl-pyrimidine 500352-50-1 C7H11N3S
    2-methylsulphenyl-4-methylamino-5-methyl-pyrimidine
    —— 2-(methylthio)-4-(phenylamino)pyrimidine-5-carbonitrile 280582-33-4 C12H10N4S
    2-(methylthio)-4-(phenylamino)pyrimidine-5-carbonitrile
    —— 3-methylthio-5-cyclohexyl-1,2,4-thiadiazole 699003-70-8 C9H14N2S2
    3-methylthio-5-cyclohexyl-1,2,4-thiadiazole
    —— 5-(4-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole 699003-82-2 C10H16N2S2
    5-(4-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole
    —— 5-(2-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole 699003-80-0 C10H16N2S2
    5-(2-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole
    —— 5-(3-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole 699003-76-4 C10H16N2S2
    5-(3-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole
    —— methyl[(2-chloroethyl)sulfinyl]acetate 1378712-28-7 C5H9ClO3S
    methyl[(2-chloroethyl)sulfinyl]acetate
    —— 5-(3-ethylcyclohexyl)-3-methylthio-1,2,4-thiadiazole 699003-84-4 C11H18N2S2
    5-(3-ethylcyclohexyl)-3-methylthio-1,2,4-thiadiazole
    —— 3-methylthio-5-cyclopentyl-1,2,4-thiadiazole 699003-72-0 C8H12N2S2
    3-methylthio-5-cyclopentyl-1,2,4-thiadiazole
    —— 1-methyl-3-phenylsulfanyl-2-piperidinone 59953-51-4 C12H15NOS
    1-methyl-3-phenylsulfanyl-2-piperidinone
    —— 3-methylthio-5-(cyclohexyl)methyl-1,2,4-thiadiazole 699003-74-2 C10H16N2S2
    3-methylthio-5-(cyclohexyl)methyl-1,2,4-thiadiazole
    —— (2-cyclohexyl-3,3,3-trifluoro-1-phenylsulfanylpropyl)sulfanylbenzene 144765-03-7 C21H23F3S2
    (2-cyclohexyl-3,3,3-trifluoro-1-phenylsulfanylpropyl)sulfanylbenzene
    —— 3-<bis(phenylthio)(trimethylsilyl)methyl>cyclohexanone 104115-24-4 C22H28OS2Si
    3-<bis(phenylthio)(trimethylsilyl)methyl>cyclohexanone
    —— 3-<bis(phenylthio)methylene>-1-methyl-1-cyclohexene 104115-34-6 C20H20S2
    3-<bis(phenylthio)methylene>-1-methyl-1-cyclohexene
    —— 5-phenylthiodec-5-ene 107014-79-9 C16H24S
    5-phenylthiodec-5-ene
    —— 1,1-bis(phenylthio)-2-methyl-1-(trimethylsilyl)-4-pentanone 104115-36-8 C21H28OS2Si
    1,1-bis(phenylthio)-2-methyl-1-(trimethylsilyl)-4-pentanone
    —— Bis(phenylthio)bis(trimethylsilyl)methane 87729-86-0 C19H28S2Si2
    Bis(phenylthio)bis(trimethylsilyl)methane
    —— 7-(phenylthio)-7-(trimethylsilyl)bicyclo[4.1.0]heptane 115025-76-8 C16H24SSi
    7-(phenylthio)-7-(trimethylsilyl)bicyclo[4.1.0]heptane
    —— [3,3,3-Trifluoro-1,1-bis(phenylsulfanyl)prop-1-en-2-yl]benzene 144764-92-1 C21H15F3S2
    [3,3,3-Trifluoro-1,1-bis(phenylsulfanyl)prop-1-en-2-yl]benzene
    —— 3,6-dihydro-4,5-dimethyl-2,2-bis(phenylthio)-2H-thiapyran 1-oxide 88534-34-3 C19H20OS3
    3,6-dihydro-4,5-dimethyl-2,2-bis(phenylthio)-2H-thiapyran 1-oxide
    —— (1-phenylthiopentylidene)cyclohexane 87729-85-9 C17H24S
    (1-phenylthiopentylidene)cyclohexane
    —— 2-phenylthio-1-phenylhex-1-ene 87729-83-7 C18H20S
    2-phenylthio-1-phenylhex-1-ene
    —— 4-phenyl-1,1-bis(phenylthio)but-1-ene 111171-95-0 C22H20S2
    4-phenyl-1,1-bis(phenylthio)but-1-ene
    —— 7-(phenylthio)-7-(trimethylsilyl)bicyclo<4.1.0>heptan-2-one 112022-44-3 C16H22OSSi
    7-(phenylthio)-7-(trimethylsilyl)bicyclo<4.1.0>heptan-2-one
    —— 1,1-bis(phenylthio)-3-methyl-1-(trimethylsilyl)butane 105494-77-7 C20H28S2Si
    1,1-bis(phenylthio)-3-methyl-1-(trimethylsilyl)butane
    —— 7-amino-5-(methylthio)<1,2,5>oxadiazolo<3,4-d>pyrimidine 30708-68-0 C5H5N5OS
    7-amino-5-(methylthio)<1,2,5>oxadiazolo<3,4-d>pyrimidine