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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— cis-1-(4'-chloro-2'-buten-1'-yl)-6-(thiophenyl)uracil 209908-62-3 C14H13ClN2O2S
    cis-1-(4'-chloro-2'-buten-1'-yl)-6-(thiophenyl)uracil
    —— 1-(2,2-dichloro-1-chloromethyl-ethylsulfanyl)-butane 4458-99-5 C7H13Cl3S
    1-(2,2-dichloro-1-chloromethyl-ethylsulfanyl)-butane
    —— 5-chloro-3-methyl-3-phenylthiohex-5-en-2-ol 108362-38-5 C13H17ClOS
    5-chloro-3-methyl-3-phenylthiohex-5-en-2-ol
    —— 2-(2-ethylsulfanyl-4-methyl-6-oxo-1,6-dihydro-pyrimidin-5-yl)-<i>N</i>-methyl-acetamide 14352-28-4 C10H15N3O2S
    2-(2-ethylsulfanyl-4-methyl-6-oxo-1,6-dihydro-pyrimidin-5-yl)-<i>N</i>-methyl-acetamide
    —— 3-chloromethyl-3-(phenylsulfanyl-methyl)-oxetane 100126-70-3 C11H13ClOS
    3-chloromethyl-3-(phenylsulfanyl-methyl)-oxetane
    —— 1-(Diethylcarbamoyl)-3-(2,4-difluorophenylthio)-4-fluoropyrazole 143531-35-5 C14H14F3N3OS
    1-(Diethylcarbamoyl)-3-(2,4-difluorophenylthio)-4-fluoropyrazole
    —— N,N-Dihexylthiobutyramid 68506-65-0 C16H33NS
    N,N-Dihexylthiobutyramid
    —— 2-[(1-ethoxycarbonyl-1-methyl)ethylthio]thiazolo[5,4-b]pyridine 133903-30-7 C12H14N2O2S2
    2-[(1-ethoxycarbonyl-1-methyl)ethylthio]thiazolo[5,4-b]pyridine
    —— 2-methoxy-3,7-bis-<i>p</i>-tolylsulfanyl-cycloheptatrienone 872287-77-9 C22H20O2S2
    2-methoxy-3,7-bis-<i>p</i>-tolylsulfanyl-cycloheptatrienone
    —— 2-methyldithiocarbazic acid isopropyl ester 156839-06-4 C5H12N2S2
    2-methyldithiocarbazic acid isopropyl ester
    —— methyl N-(C-ethylsulfanylcarbonimidoyl)carbamate 62946-41-2 C5H10N2O2S
    methyl N-(C-ethylsulfanylcarbonimidoyl)carbamate
    —— Pentachlorbutadienyl-phenyl-sulfid 14621-81-9 C10H5Cl5S
    Pentachlorbutadienyl-phenyl-sulfid
    —— 1-[5-(3-methylthiophenylamino)-1,2,4-thiadiazol-3-yl]-propan-2-ol 1361124-46-0 C12H15N3OS2
    1-[5-(3-methylthiophenylamino)-1,2,4-thiadiazol-3-yl]-propan-2-ol
    —— 5-(2-acetylamino-4-chloro-phenylsulfanyl)-4-bromo-2H-pyridazin-3-one 37150-11-1 C12H9BrClN3O2S
    5-(2-acetylamino-4-chloro-phenylsulfanyl)-4-bromo-2H-pyridazin-3-one
    —— 5-Methyl-2-[(4-methylsulfanylphenyl)methyl]-1,2,6-thiadiazinane 1,1-dioxide 1263429-65-7 C12H18N2O2S2
    5-Methyl-2-[(4-methylsulfanylphenyl)methyl]-1,2,6-thiadiazinane 1,1-dioxide
    —— 2-Ethoxy-4-sulfanilylamino-6-p-dimethylaminophenylthio-pyrimidin 750-18-5 C20H23N5O3S2
    2-Ethoxy-4-sulfanilylamino-6-p-dimethylaminophenylthio-pyrimidin
    —— 3-Ethyl-2-nitro-5-phenylsulfanyl-thiophene 82834-53-5 C12H11NO2S2
    3-Ethyl-2-nitro-5-phenylsulfanyl-thiophene
    —— di-[2]pyridyl sulfide; dihydrobromide 96592-11-9 2BrH*C10H8N2S
    di-[2]pyridyl sulfide; dihydrobromide
    —— 4-chlorophenyl 2-(trimethylsilyl)ethyl sulfide 353243-81-9 C11H17ClSSi
    4-chlorophenyl 2-(trimethylsilyl)ethyl sulfide
    —— 1-bromo-2-<i>tert</i>-butylsulfanyl-ethene 89490-16-4 C6H11BrS
    1-bromo-2-<i>tert</i>-butylsulfanyl-ethene
    —— {(2S,3S)-3-[1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-oxo-azetidin-2-yl}-methoxy-thioacetic acid S-m-tolyl ester 101765-70-2 C21H33NO4SSi
    {(2S,3S)-3-[1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-oxo-azetidin-2-yl}-methoxy-thioacetic acid S-m-tolyl ester
    —— 3-imino-5-methylsulfanyl-3<i>H</i>-[1,2,4]thiadiazole-2-carboxylic acid ethyl ester 71466-80-3 C6H9N3O2S2
    3-imino-5-methylsulfanyl-3<i>H</i>-[1,2,4]thiadiazole-2-carboxylic acid ethyl ester
    —— 4-(1,1-dimethyl-butylsulfanyl)-2-methyl-pent-2-ene 99114-53-1 C12H24S
    4-(1,1-dimethyl-butylsulfanyl)-2-methyl-pent-2-ene
    —— p-(2-Methylthioethylthio)-phenol 37708-59-1 C9H12OS2
    p-(2-Methylthioethylthio)-phenol
    —— N-[3-(2-nitro-phenylsulfanyl)-1-pyridin-3-ylmethyl-1H-indol-6-yl]-acetamide 691400-39-2 C22H18N4O3S
    N-[3-(2-nitro-phenylsulfanyl)-1-pyridin-3-ylmethyl-1H-indol-6-yl]-acetamide
    —— 1-butylsulfanyl-N-phenyl-1-phenylsulfanylmethanimine 115197-95-0 C17H19NS2
    1-butylsulfanyl-N-phenyl-1-phenylsulfanylmethanimine
    —— [2,3-bis(isopropylthio)phenyl](2-thienyl)methanol 332101-42-5 C17H22OS3
    [2,3-bis(isopropylthio)phenyl](2-thienyl)methanol
    —— ethylenedithiodimethylbenzotetrathiafulvalene 101683-16-3 C14H12S6
    ethylenedithiodimethylbenzotetrathiafulvalene
    —— 5,6-Bis-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidenemethyl)-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione 162470-22-6 C17H14S13
    5,6-Bis-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidenemethyl)-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione
    —— cis-1-chloro-2-p-tolylsulfanyl-ethene 127934-16-1 C9H9ClS
    cis-1-chloro-2-p-tolylsulfanyl-ethene
    —— DL-2-Xanthogenpropionsaeure-tert.-butylester 59854-07-8 C10H18O3S2
    DL-2-Xanthogenpropionsaeure-tert.-butylester
    —— (2<i>RS</i>,3<i>RS</i>)-2-bromo-3-ethylsulfanyl-butane 23289-25-0 C6H13BrS
    (2<i>RS</i>,3<i>RS</i>)-2-bromo-3-ethylsulfanyl-butane
    —— (RS)-O-(methoxymethyl)-S-((ethylthio)methyl)-D-cysteinol S-oxide 220322-96-3 C8H19NO3S2
    (RS)-O-(methoxymethyl)-S-((ethylthio)methyl)-D-cysteinol S-oxide
    —— rac-1-((4aR,5R,6R)-6-cyano-6-((S)-hex-5-en-1-yn-3-yl)-1,4a-dimethyl-4,4a,5,6,7,8-hexahydro-3H-spiro[naphthalene-2,2'-[1,3]dithian]-5-yl)vinyl methyl carbonate 134827-03-5 C26H33NO3S2
    rac-1-((4aR,5R,6R)-6-cyano-6-((S)-hex-5-en-1-yn-3-yl)-1,4a-dimethyl-4,4a,5,6,7,8-hexahydro-3H-spiro[naphthalene-2,2'-[1,3]dithian]-5-yl)vinyl methyl carbonate
    —— 2,2-ditert-butyl-4-(2-tert-butyl-3,3-dimethylbut-1-enylidene)thietane-3-thione 126091-75-6 C21H36S2
    2,2-ditert-butyl-4-(2-tert-butyl-3,3-dimethylbut-1-enylidene)thietane-3-thione
    —— 6-Benzyloxy-2-methylsulfanyl-pyrimidin-4-ol 151699-85-3 C12H12N2O2S
    6-Benzyloxy-2-methylsulfanyl-pyrimidin-4-ol
    —— 1,1,3-Trichlor-2-phenylmercapto-propan 4459-03-4 C9H9Cl3S
    1,1,3-Trichlor-2-phenylmercapto-propan
    —— (4-phenylsulfanyl-phenyl)-thiourea 859736-87-1 C13H12N2S2
    (4-phenylsulfanyl-phenyl)-thiourea
    —— N-{4-(Z)-2-[(tert-butylamino)-2-phenylvinyl]-2-(methylthio)-6-morpholin-1-ylpyrimidin-5-ylmethylene}-2-methylpropan-2-amine 1104638-73-4 C26H37N5OS
    N-{4-(Z)-2-[(tert-butylamino)-2-phenylvinyl]-2-(methylthio)-6-morpholin-1-ylpyrimidin-5-ylmethylene}-2-methylpropan-2-amine
    —— (1-(4-(trifluoromethylthio)benzyl)-1H-1,2,3-triazol-4-yl)methanol 1232164-31-6 C11H10F3N3OS
    (1-(4-(trifluoromethylthio)benzyl)-1H-1,2,3-triazol-4-yl)methanol
    —— 3-Methyl-4-pentylmercapto-benzylmercaptan 106214-06-6 C13H20S2
    3-Methyl-4-pentylmercapto-benzylmercaptan
    —— 2,5-dimethylhexa-1,5-dienylsulfanylbenzene 144650-19-1 C14H18S
    2,5-dimethylhexa-1,5-dienylsulfanylbenzene
    —— trans-1-bromo-2-tert-butylsulfanyl-ethene 53715-44-9 C6H11BrS
    trans-1-bromo-2-tert-butylsulfanyl-ethene
    —— 5-<4-Acetamino-phenylmercapto>-furfurol-thiosemicarbazon 57590-91-7 C14H14N4O2S2
    5-<4-Acetamino-phenylmercapto>-furfurol-thiosemicarbazon
    —— 2-[2-Methylsulfanyl-3-(4,5,6,7-tetrahydro-benzo[1,3]dithiol-2-ylidene)-cyclopent-1-enyl]-4,5,6,7-tetrahydro-benzo[1,3]dithiol-1-ylium; iodide 55785-90-5 C20H23S5*I
    2-[2-Methylsulfanyl-3-(4,5,6,7-tetrahydro-benzo[1,3]dithiol-2-ylidene)-cyclopent-1-enyl]-4,5,6,7-tetrahydro-benzo[1,3]dithiol-1-ylium; iodide
    —— 57438-65-0 C11H14OS2
    —— Trimethylsilanyl-ethynesulfonic acid amide 55499-87-1 C5H11NO2SSi
    Trimethylsilanyl-ethynesulfonic acid amide
    —— 1-ethylsulfanyl-2,2-bis-methanesulfonyl-propane 40455-27-4 C7H16O4S3
    1-ethylsulfanyl-2,2-bis-methanesulfonyl-propane
    —— 7-(2-morpholin-4-yl-ethylsulfanyl)-thieno[2,3-d]pyridazine 19137-29-2 C12H15N3OS2
    7-(2-morpholin-4-yl-ethylsulfanyl)-thieno[2,3-d]pyridazine
    —— 57482-66-3 C12H24S2