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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Cyanomethylsulfanyl-6-oxo-4-phenethyl-1,6-dihydro-pyrimidine-5-carbonitrile 95534-89-7 C15H12N4OS
    2-Cyanomethylsulfanyl-6-oxo-4-phenethyl-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 3-Chloro-4-trifluoromethyl-2,6-dinitro-4'-methyldiphenylthioether 67364-62-9 C14H8ClF3N2O4S
    3-Chloro-4-trifluoromethyl-2,6-dinitro-4'-methyldiphenylthioether
    —— 3-Chloro-4-trifluoromethyl-2,6-dinitrodiphenylthioether 67364-61-8 C13H6ClF3N2O4S
    3-Chloro-4-trifluoromethyl-2,6-dinitrodiphenylthioether
    —— 3-Chloro-4-trifluoromethyl-2,6-dinitro-4'-chlorodiphenylthioether 67383-53-3 C13H5Cl2F3N2O4S
    3-Chloro-4-trifluoromethyl-2,6-dinitro-4'-chlorodiphenylthioether
    —— 2-(1-thiophenylcycloprop-1-yl)-pyrrole 87385-11-3 C13H13NS
    2-(1-thiophenylcycloprop-1-yl)-pyrrole
    —— 2,2-Dimethyl-1-(1'-phenylthiocycloprop-1-yl)cyclobutan-1-ol 63365-70-8 C15H20OS
    2,2-Dimethyl-1-(1'-phenylthiocycloprop-1-yl)cyclobutan-1-ol
    —— Cyclopropanemethanol, a-[1-methyl-2-(phenylthio)ethyl]-1-(phenylthio)- 63048-99-7 C19H22OS2
    Cyclopropanemethanol, a-[1-methyl-2-(phenylthio)ethyl]-1-(phenylthio)-
    —— (E)-7-Methyl-1-phenylsulfanyl-oct-4-en-3-one 83022-92-8 C15H20OS
    (E)-7-Methyl-1-phenylsulfanyl-oct-4-en-3-one
    —— 2-((4-methoxyphenyl)thio)-1-methyl-1H-benzo[d]imidazole 1335609-19-2 C15H14N2OS
    2-((4-methoxyphenyl)thio)-1-methyl-1H-benzo[d]imidazole
    —— Propanamide, 3,3'-sulfinylbis- 105596-09-6 C6H12N2O3S
    Propanamide, 3,3'-sulfinylbis-
    —— 2-bromo-3<i>t</i>-phenylsulfanyl-acrylic acid 90279-93-9 C9H7BrO2S
    2-bromo-3<i>t</i>-phenylsulfanyl-acrylic acid
    —— 4-Phenylsulfanyl-5-((E)-propenyl)-5H-furan-2-one 77199-29-2 C13H12O2S
    4-Phenylsulfanyl-5-((E)-propenyl)-5H-furan-2-one
    —— 5-Isopropyl-4-phenylsulfanyl-5H-furan-2-one 77199-27-0 C13H14O2S
    5-Isopropyl-4-phenylsulfanyl-5H-furan-2-one
    —— 3-Methyl-4-phenylsulfanyl-1-oxa-spiro[4.5]dec-3-en-2-one 77199-37-2 C16H18O2S
    3-Methyl-4-phenylsulfanyl-1-oxa-spiro[4.5]dec-3-en-2-one
    —— 2-[(4-Chlorophenyl)thio]-N-(2-methoxyethyl)ethanamine 434309-05-4 C11H16ClNOS
    2-[(4-Chlorophenyl)thio]-N-(2-methoxyethyl)ethanamine
    —— 2-[(3-methylbenzyl)thio]-3,5,6,7-tetrahydro-4H-cyclopenta[d]pyrimidin-4-one 371118-18-2 C15H16N2OS
    2-[(3-methylbenzyl)thio]-3,5,6,7-tetrahydro-4H-cyclopenta[d]pyrimidin-4-one
    —— 2-Methyl-1-(1-phenylsulfanyl-cyclopropyl)-cyclohexanol 63048-70-4 C16H22OS
    2-Methyl-1-(1-phenylsulfanyl-cyclopropyl)-cyclohexanol
    —— 1-Methyl-5-[3-(4-methyl-5-thiazolyl)carbonylpropyl]thio-1,2,3,4-tetrazole 80087-60-1 C10H13N5OS2
    1-Methyl-5-[3-(4-methyl-5-thiazolyl)carbonylpropyl]thio-1,2,3,4-tetrazole
    —— 13-p-Bromphenyl-5.11-imino-5H.11H-dipyrido<2.3-b:2'.3'-f><1.5>dithiocin 72397-26-3 C18H12BrN3S2
    13-p-Bromphenyl-5.11-imino-5H.11H-dipyrido<2.3-b:2'.3'-f><1.5>dithiocin
    —— 2-Methylthiopyridine-3-carboxaldehyde Diethylacetal 74405-28-0 C11H17NO2S
    2-Methylthiopyridine-3-carboxaldehyde Diethylacetal
    —— 2,3,4-Trihydrodibenzo<f,h><1,5>dithionin 23019-53-6 C15H14S2
    2,3,4-Trihydrodibenzo<f,h><1,5>dithionin
    —— 6,7,8,9-tetrahydrodibenzo<b,d><1,6>dithiecin 34119-94-3 C16H16S2
    6,7,8,9-tetrahydrodibenzo<b,d><1,6>dithiecin
    —— 4,5-Diamino-2,6-dimethylthiopyrimidine 61772-85-8 C6H10N4S2
    4,5-Diamino-2,6-dimethylthiopyrimidine
    —— 6-methyl-2-(methylthio)-3-nitropyridine 66665-84-7 C7H8N2O2S
    6-methyl-2-(methylthio)-3-nitropyridine
    —— 6-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine 96592-33-5 C10H12N4S
    6-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine
    —— 8-[4-(2-Pyridyl)thiazol-2-ylmethyl]-10H-pyrazino[2,3-b][1,4]benzothiazine 203655-34-9 C19H13N5S2
    8-[4-(2-Pyridyl)thiazol-2-ylmethyl]-10H-pyrazino[2,3-b][1,4]benzothiazine
    —— 4,6-dichloro-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenyl)-1,3,5-triazin-2-aminium chloride 1602768-48-8 C15H7Cl2N7O3S*ClH
    4,6-dichloro-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenyl)-1,3,5-triazin-2-aminium chloride
    —— 4,6-dichloro-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenyl)-1,3,5-triazin-2-amine 1602768-45-5 C15H7Cl2N7O3S
    4,6-dichloro-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenyl)-1,3,5-triazin-2-amine
    —— 4-methyl-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenylcarbamoyl)benzenesulfonamide 1602768-43-3 C20H15N5O6S2
    4-methyl-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenylcarbamoyl)benzenesulfonamide
    —— N-(naphthalen-2-ylmethyl)-3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)benzenamine 1602768-53-5 C23H16N4O3S
    N-(naphthalen-2-ylmethyl)-3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)benzenamine
    —— 4-amino-3-methylsulfanyl-phenol 37407-24-2 C7H9NOS
    4-amino-3-methylsulfanyl-phenol
    —— (10H-pyrazino[2,3-b][1,4]benzothiazin-8-yl)thioacetamide 203657-45-8 C12H10N4S2
    (10H-pyrazino[2,3-b][1,4]benzothiazin-8-yl)thioacetamide
    —— 1,1,2,2-Tetrafluor-1-aethylenmercapto-aethan 428-95-5 C4H6F4S
    1,1,2,2-Tetrafluor-1-aethylenmercapto-aethan
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(tetrazol-1-ylmethyl)pyridin-2(1H)-one 1185190-27-5 C16H16IN5OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(tetrazol-1-ylmethyl)pyridin-2(1H)-one
    —— 1,3,4,6-tetrakis(isopropylthio)-2λ<sup>4</sup>δ<sup>2</sup>-thieno<3,4-c>thiophene 98088-21-2 C18H28S6
    1,3,4,6-tetrakis(isopropylthio)-2λ<sup>4</sup>δ<sup>2</sup>-thieno<3,4-c>thiophene
    —— 4-[(4-bromophenyl)sulfanyl]furo[3,2-c]pyridine 1609581-10-3 C13H8BrNOS
    4-[(4-bromophenyl)sulfanyl]furo[3,2-c]pyridine
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(tetrazol-2-ylmethyl)pyridin-2(1H)-one 1185190-17-3 C16H16IN5OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(tetrazol-2-ylmethyl)pyridin-2(1H)-one
    —— 6,6-Dimethyl-3-isopropylthio-1-(tetrazol-5-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one 207307-78-6 C14H18N4OS2
    6,6-Dimethyl-3-isopropylthio-1-(tetrazol-5-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one
    —— 2-Nitro-1-(phenylsulfanylmethyl)imidazole 1569296-97-4 C10H9N3O2S
    2-Nitro-1-(phenylsulfanylmethyl)imidazole
    —— (R)-1-(phenylthio)-2-aminopropane hydrochloride 56216-00-3 C9H13NS*ClH
    (R)-1-(phenylthio)-2-aminopropane hydrochloride
    —— 2-(2-(methylthio)phenyl)-4,5-dihydrooxazole 1445591-10-5 C10H11NOS
    2-(2-(methylthio)phenyl)-4,5-dihydrooxazole
    —— 4-(phenylthio)-6-phenylpyrimido[4,5-b][1,4]benzothiazepine 873106-33-3 C23H15N3S2
    4-(phenylthio)-6-phenylpyrimido[4,5-b][1,4]benzothiazepine
    —— Ethyl 2,4-dimethyl-5-({[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetyl)-1H-pyrrole-3-carboxylate 785711-83-3 C18H18N4O4S
    Ethyl 2,4-dimethyl-5-({[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetyl)-1H-pyrrole-3-carboxylate
    —— 4-(p-tolylthio)-6-phenyl-8-methylpyrimido[4,5-b][1,4]benzothiazepine 873106-41-3 C25H19N3S2
    4-(p-tolylthio)-6-phenyl-8-methylpyrimido[4,5-b][1,4]benzothiazepine
    —— 2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(3-methylbutyl)pyrrol-3-yl]ethanone 5519-26-6 C21H26N4OS2
    2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(3-methylbutyl)pyrrol-3-yl]ethanone
    —— 2-phenylthioacetylbutylamide 71433-00-6 C12H17NOS
    2-phenylthioacetylbutylamide
    —— 1-methyl-3-methylthiopropylamine 105882-51-7 C5H13NS
    1-methyl-3-methylthiopropylamine
    —— 3-Propylsulfanylpyridin-2-amine 1532517-79-5 C8H12N2S
    3-Propylsulfanylpyridin-2-amine
    —— 5-Bromo-3-propylsulfanylpyridin-2-amine 1532517-80-8 C8H11BrN2S
    5-Bromo-3-propylsulfanylpyridin-2-amine
    —— 1-methyl-2-(2-methylphenylthio)ethylamine 104864-69-9 C10H15NS
    1-methyl-2-(2-methylphenylthio)ethylamine