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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-benzylthio-6-(2-furyl)-4-oxo-3,4-dihydropyrimidine-5-carbonitrile 137447-01-9 C16H11N3O2S
    2-benzylthio-6-(2-furyl)-4-oxo-3,4-dihydropyrimidine-5-carbonitrile
    —— 7-cyano-8-(2-furyl)-3-(4-tolyl)-3,4-dihydro-2H-pyrimido[2,1-b]-1,3,5-thiadiazin-6-one 1262508-85-9 C18H14N4O2S
    7-cyano-8-(2-furyl)-3-(4-tolyl)-3,4-dihydro-2H-pyrimido[2,1-b]-1,3,5-thiadiazin-6-one
    —— 2-Amino-6-(5-brom-2-methylmercapto-pyrimidinyl-(4)-mercapto)-purin 68498-46-4 C10H8BrN7S2
    2-Amino-6-(5-brom-2-methylmercapto-pyrimidinyl-(4)-mercapto)-purin
    —— 7-cyano-3-ethyl-8-(2-furyl)-3,4-dihydro-2H-pyrimido[2,1-b]-1,3,5-thiadiazin-6-one 1262508-81-5 C13H12N4O2S
    7-cyano-3-ethyl-8-(2-furyl)-3,4-dihydro-2H-pyrimido[2,1-b]-1,3,5-thiadiazin-6-one
    —— 2-(4'-Oxobutyl)-2-(5"-oxopentyl)-1,3-dithiane 146353-23-3 C13H22O2S2
    2-(4'-Oxobutyl)-2-(5"-oxopentyl)-1,3-dithiane
    —— 2-(3'-Oxopropyl)-2-(5"-oxopentyl)-1,3-dithiane 146353-22-2 C12H20O2S2
    2-(3'-Oxopropyl)-2-(5"-oxopentyl)-1,3-dithiane
    —— N-(2-azidoethyl)-2-(phenylthio)acetamide 1192358-12-5 C10H12N4OS
    N-(2-azidoethyl)-2-(phenylthio)acetamide
    —— 2-<3'-(1,3-Dioxolanyl)propyl>-2-<4"-(1,3-dioxolanyl)butyl>-1,3-dithiane 146353-21-1 C17H30O4S2
    2-<3'-(1,3-Dioxolanyl)propyl>-2-<4"-(1,3-dioxolanyl)butyl>-1,3-dithiane
    —— (5R)-1-[4-(1,3-dioxolan-2-yl)butyl]-5-{[(1-tert-butyl-1H-tetrazol-5-yl)sulfanyl]methyl}pyrrolidin-2-one 1197897-14-5 C17H29N5O3S
    (5R)-1-[4-(1,3-dioxolan-2-yl)butyl]-5-{[(1-tert-butyl-1H-tetrazol-5-yl)sulfanyl]methyl}pyrrolidin-2-one
    —— 3,4-Trimethylen-1,6-dioxa-6a-thia<sup>IV</sup>-2,5-diazapentalen 70820-83-6 C6H6N2O2S
    3,4-Trimethylen-1,6-dioxa-6a-thia<sup>IV</sup>-2,5-diazapentalen
    —— 4-Chlor-2-benzylmercapto-pyrimidin 78494-41-4 C11H9ClN2S
    4-Chlor-2-benzylmercapto-pyrimidin
    —— 10H-Pyrazino[2,3-b][1,4]benzothiazine-8-carboxylic acid 203659-84-1 C11H7N3O2S
    10H-Pyrazino[2,3-b][1,4]benzothiazine-8-carboxylic acid
    —— N-(10H-Pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-1-methylpiperidine-4-carboxamide 203657-14-1 C18H21N5OS
    N-(10H-Pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-1-methylpiperidine-4-carboxamide
    —— 3-(2,4-difluorophenyl)-1-methyl-7-methylsulfanyl-1H-pyrimido[4,5-e][1,3,4]oxadiazine 691864-48-9 C13H10F2N4OS
    3-(2,4-difluorophenyl)-1-methyl-7-methylsulfanyl-1H-pyrimido[4,5-e][1,3,4]oxadiazine
    —— 1,4-Phenylenbis(benzodithioketal) 63866-46-6 C20H14S4
    1,4-Phenylenbis(benzodithioketal)
    —— 6-(4-cholorobutyl)-4-(phenylthio)-1,2,5,6-tetrahydro-2-pyridinone 871950-83-3 C15H18ClNOS
    6-(4-cholorobutyl)-4-(phenylthio)-1,2,5,6-tetrahydro-2-pyridinone
    —— 4-(4-bromophenylsulfanyl)-3,5-dimethyl-1H-pyrazole 394237-22-0 C11H11BrN2S
    4-(4-bromophenylsulfanyl)-3,5-dimethyl-1H-pyrazole
    —— 2-ethylsulfanyl-6-phenyl-4H-thiopyran-4-one 500169-87-9 C13H12OS2
    2-ethylsulfanyl-6-phenyl-4H-thiopyran-4-one
    —— 5-Methyl-4-[(4-methylsulfanylphenyl)methylidene]-2-phenylpyrazol-3-one 146795-14-4 C18H16N2OS
    5-Methyl-4-[(4-methylsulfanylphenyl)methylidene]-2-phenylpyrazol-3-one
    —— 5-methyl-2-[4,5-bis(pentylthio)-1,3-dithiole-2-yliden]-(1,3)-dithiolo[4,5-c]pyrrole 860306-27-0 C19H27NS6
    5-methyl-2-[4,5-bis(pentylthio)-1,3-dithiole-2-yliden]-(1,3)-dithiolo[4,5-c]pyrrole
    —— (S)-2-amino-4-[2-chloro-4-(2-hydroxy-5-methylphenylthio)phenyl]-2-methylbutylphosphoric acid monoester 1260512-05-7 C18H23ClNO5PS
    (S)-2-amino-4-[2-chloro-4-(2-hydroxy-5-methylphenylthio)phenyl]-2-methylbutylphosphoric acid monoester
    —— (R)-N-[1-(hydroxymethyl)-2-methylpropyl]cyclohexanethiocarboxamide 420133-83-1 C12H23NOS
    (R)-N-[1-(hydroxymethyl)-2-methylpropyl]cyclohexanethiocarboxamide
    —— (R)-2-cyclohexyl-4-isopropyl-2-thiazoline 420134-20-9 C12H21NS
    (R)-2-cyclohexyl-4-isopropyl-2-thiazoline
    —— (S)-2-t-butoxycarbonylamino-4-[2-chloro-4-(2-methoxymethoxy-5-methylphenylthio)phenyl]-2-methylbutan-1-ol 1260511-77-0 C25H34ClNO5S
    (S)-2-t-butoxycarbonylamino-4-[2-chloro-4-(2-methoxymethoxy-5-methylphenylthio)phenyl]-2-methylbutan-1-ol
    —— (S)-4-methoxy-4-(phenylthio)-2-butanone 1207593-83-6 C11H14O2S
    (S)-4-methoxy-4-(phenylthio)-2-butanone
    —— (S)-2-t-butoxycarbonylamino-4-[2-chloro-4-(2-methoxymethoxy-5-methylphenylthio)phenyl]-1-dimethoxyphosphoryloxy-2-methylbutane 1260511-92-9 C27H39ClNO8PS
    (S)-2-t-butoxycarbonylamino-4-[2-chloro-4-(2-methoxymethoxy-5-methylphenylthio)phenyl]-1-dimethoxyphosphoryloxy-2-methylbutane
    —— 3-benzylthio-4-phenylfurazan 1198084-52-4 C15H12N2OS
    3-benzylthio-4-phenylfurazan
    —— 2-[1-(2-Phenyl-1,3-dithian-2-yl)pent-4-en-2-yl]phenol 1015689-73-2 C21H24OS2
    2-[1-(2-Phenyl-1,3-dithian-2-yl)pent-4-en-2-yl]phenol
    —— 3,5,7,10,10-pentamethyl-2,4,6,8-tetrathia-adamantane-1-thiol 17443-98-0 C11H18S5
    3,5,7,10,10-pentamethyl-2,4,6,8-tetrathia-adamantane-1-thiol
    —— [3-fluoro-2-(1-methyl-7-methylsulfanyl-1H-pyrimido[4,5-e][1,3,4]oxadiazin-3-yl)-phenyl]-dimethyl-amine 691864-51-4 C15H16FN5OS
    [3-fluoro-2-(1-methyl-7-methylsulfanyl-1H-pyrimido[4,5-e][1,3,4]oxadiazin-3-yl)-phenyl]-dimethyl-amine
    —— ethyl (1S,2S,4aR,6S,8aS)-1,2,4a,5,6,7,8,8a-octahydro-8-(dimethylenedithio)-2,6-dimethylnaphthalene-1-carboxylate 175358-23-3 C17H26O2S2
    ethyl (1S,2S,4aR,6S,8aS)-1,2,4a,5,6,7,8,8a-octahydro-8-(dimethylenedithio)-2,6-dimethylnaphthalene-1-carboxylate
    —— ethyl (1S,2S,4aR,6S,8aS)-1,2,4a,5,6,7,8,8a-octahydro-2-methyl-6-<<<(methylthio)thiocarbonyl>oxy>methyl>-8-oxonaphthalene-1-carboxylate 175358-21-1 C17H24O4S2
    ethyl (1S,2S,4aR,6S,8aS)-1,2,4a,5,6,7,8,8a-octahydro-2-methyl-6-<<<(methylthio)thiocarbonyl>oxy>methyl>-8-oxonaphthalene-1-carboxylate
    —— 2-[1-(2-Propan-2-yl-1,3-dithian-2-yl)pent-4-en-2-yl]phenol 1015689-74-3 C18H26OS2
    2-[1-(2-Propan-2-yl-1,3-dithian-2-yl)pent-4-en-2-yl]phenol
    —— 7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-methylthioimidazo<4,5-d>pyridazine 85732-82-7 C11H11ClN6S
    7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-methylthioimidazo<4,5-d>pyridazine
    —— 2H-Pyran, 2-(ethenylthio)-3,4-dihydro- 61645-66-7 C7H10OS
    2H-Pyran, 2-(ethenylthio)-3,4-dihydro-
    —— 2-[1-(2-Ethyl-1,3-dithian-2-yl)pent-4-en-2-yl]phenol 1015689-72-1 C17H24OS2
    2-[1-(2-Ethyl-1,3-dithian-2-yl)pent-4-en-2-yl]phenol
    —— 7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(3-chlorobenzylthio)imidazo<4,5-d>pyridazine 85732-83-8 C17H14Cl2N6S
    7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(3-chlorobenzylthio)imidazo<4,5-d>pyridazine
    —— 1-(2-hexylsulfanyl-6-methyl-pyrimidin-4-yl)-ethanol 863673-01-2 C13H22N2OS
    1-(2-hexylsulfanyl-6-methyl-pyrimidin-4-yl)-ethanol
    —— lead(II) n-butylxanthate 21256-01-9 C10H18O2PbS4
    lead(II) n-butylxanthate
    —— 2-cyano-3-(diethoxyphosphoryloxy)-5-ethylthio-thiophene 61124-88-7 C11H16NO4PS2
    2-cyano-3-(diethoxyphosphoryloxy)-5-ethylthio-thiophene
    —— 6,6-dimethyl-6,7-dihydro-5<i>H</i>-2,3-dioxa-2aλ<sup>4</sup>-thia-1,4-diaza-cyclopenta[<i>cd</i>]indene 37895-65-1 C8H10N2O2S
    6,6-dimethyl-6,7-dihydro-5<i>H</i>-2,3-dioxa-2aλ<sup>4</sup>-thia-1,4-diaza-cyclopenta[<i>cd</i>]indene
    —— Ethyl Bromofluoro(phenylthio)acetate 106636-69-5 C10H10BrFO2S
    Ethyl Bromofluoro(phenylthio)acetate
    —— ethyl 4-(hydroxymethyl)-2-(phenylsulfanyl)pent-4-enoate 927432-68-6 C14H18O3S
    ethyl 4-(hydroxymethyl)-2-(phenylsulfanyl)pent-4-enoate
    —— 1,2-Bis<(o-hydroxyphenyl)thio>ethylen 64620-82-2 C14H12O2S2
    1,2-Bis<(o-hydroxyphenyl)thio>ethylen
    —— 2-(allylthio)-5-(4-chlorophenyl)-1,3,4-oxadiazole 886509-13-3 C11H9ClN2OS
    2-(allylthio)-5-(4-chlorophenyl)-1,3,4-oxadiazole
    —— N-phenyl-4-((trifluoromethyl)thio)aniline 1333415-78-3 C13H10F3NS
    N-phenyl-4-((trifluoromethyl)thio)aniline
    —— 5-phenylthiofuran-2-sulfonyl chloride 166964-27-8 C10H7ClO3S2
    5-phenylthiofuran-2-sulfonyl chloride
    —— 2-(butylthio)-5-(4-pyridyl)-1,3,4-oxadiazole 892427-98-4 C11H13N3OS
    2-(butylthio)-5-(4-pyridyl)-1,3,4-oxadiazole
    —— (4S,6S)-4-phenyl-6-(phenylthio)tetrahydro-2H-pyran-2-one 1610597-30-2 C17H16O2S
    (4S,6S)-4-phenyl-6-(phenylthio)tetrahydro-2H-pyran-2-one
    —— (4S,6S)-4-(furan-2-yl)-6-(phenylthio)tetrahydro-2H-pyran-2-one 1610597-38-0 C15H14O3S
    (4S,6S)-4-(furan-2-yl)-6-(phenylthio)tetrahydro-2H-pyran-2-one