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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-Phenyl-8,9,10,11-tetrahydro-5H,17H-dibenzo<d,h><1,6,10,2>oxadithiaphosphacyclotetradecin-6-oxid 122278-89-1 C24H25O2PS2
    6-Phenyl-8,9,10,11-tetrahydro-5H,17H-dibenzo<d,h><1,6,10,2>oxadithiaphosphacyclotetradecin-6-oxid
    —— N,N-dimethyl-2-[4-(1-methylpyrrol-2-yl)pyrimidin-2-yl]sulfanylethanamine;hydron;bromide —— C13H19BrN4S
    N,N-dimethyl-2-[4-(1-methylpyrrol-2-yl)pyrimidin-2-yl]sulfanylethanamine;hydron;bromide
    —— <2-(Methylthio)phenyl>methylphosphonsaeure-dimethylester 122278-83-5 C10H15O3PS
    <2-(Methylthio)phenyl>methylphosphonsaeure-dimethylester
    —— 2-[2-(2-pyridine)thioethyl]-1-methylpyrrolidine 228573-72-6 C12H18N2S
    2-[2-(2-pyridine)thioethyl]-1-methylpyrrolidine
    —— 4-[3-(myristoylamino)propylthio]-pyridine 155965-61-0 C22H38N2OS
    4-[3-(myristoylamino)propylthio]-pyridine
    —— 6-Phenyl-9,10,11,12-tetrahydro-5H,8H,18H-dibenzo<d,h><1,6,10,2>oxadithiaphosphacyclopentadecin-6-oxid 122297-29-4 C25H27O2PS2
    6-Phenyl-9,10,11,12-tetrahydro-5H,8H,18H-dibenzo<d,h><1,6,10,2>oxadithiaphosphacyclopentadecin-6-oxid
    —— S-Ethylsulfenyl O-Ethyl Thiocarbonate 30453-25-9 C5H10O2S2
    S-Ethylsulfenyl O-Ethyl Thiocarbonate
    —— 5,7,8,14-Tetrahydro-7-phenyldibenzo<d,h><1,6,2>oxathiaphosphecin-7-oxid 122278-90-4 C21H19O2PS
    5,7,8,14-Tetrahydro-7-phenyldibenzo<d,h><1,6,2>oxathiaphosphecin-7-oxid
    —— 2-bromomethyl-7-methyl-6-nitro-2,3-dihydrothiazolo[3,2-a]pyrimidin-5-one 1556679-46-9 C8H8BrN3O3S
    2-bromomethyl-7-methyl-6-nitro-2,3-dihydrothiazolo[3,2-a]pyrimidin-5-one
    —— 6-bromo-2-bromomethyl-7-methyl-2,3-dihydrothiazolo[3,2-a]pyrimidin-5-one 1556679-40-3 C8H8Br2N2OS
    6-bromo-2-bromomethyl-7-methyl-2,3-dihydrothiazolo[3,2-a]pyrimidin-5-one
    —— <2-(Ethylthio)phenyl>methylphosphonsaeure-diethylester 122297-28-3 C13H21O3PS
    <2-(Ethylthio)phenyl>methylphosphonsaeure-diethylester
    —— 2-(2-(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)benzo[d][1,3]dithiol-5-yl)pyridine 1268612-21-0 C17H13NS6
    2-(2-(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)benzo[d][1,3]dithiol-5-yl)pyridine
    —— 2-[4,5-bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-N-(4-pyridyl)-1,3-dithiolo[4,5-c]pyrrole 1214754-14-9 C15H12N2S6
    2-[4,5-bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-N-(4-pyridyl)-1,3-dithiolo[4,5-c]pyrrole
    —— 2-phenylbenzo[1,4]oxathiin-6-ol 1616377-40-2 C14H10O2S
    2-phenylbenzo[1,4]oxathiin-6-ol
    —— 4,5-(1,4-dimethoxy-2,3-phenylenedithio)-1,3-dithiole-2-one 259813-16-6 C11H8O3S4
    4,5-(1,4-dimethoxy-2,3-phenylenedithio)-1,3-dithiole-2-one
    —— N,N-dimethyl-2-<<4'-(1''-methylpyrrol-2''-yl)pyrimidin-2'-yl>thio>ethylamine 113669-49-1 C13H18N4S
    N,N-dimethyl-2-<<4'-(1''-methylpyrrol-2''-yl)pyrimidin-2'-yl>thio>ethylamine
    —— Aethyl-N-<methoxy(methylthio)methylen>carbamat 51291-78-2 C6H11NO3S
    Aethyl-N-<methoxy(methylthio)methylen>carbamat
    —— 5-Methylmercapto-nonan 2198-48-3 C10H22S
    5-Methylmercapto-nonan
    —— (E)-1-(tridecafluorohexane-1-sulfonyl)-propene 881901-11-7 C9H5F13O2S
    (E)-1-(tridecafluorohexane-1-sulfonyl)-propene
    —— 4-Hydrazino-5-methyl-2-methylthio-pyrimidin 30150-44-8 C6H10N4S
    4-Hydrazino-5-methyl-2-methylthio-pyrimidin
    —— 1-(2,5-bis-methylsulfanyl-thiophen-3-yl)-ethanone 81931-47-7 C8H10OS3
    1-(2,5-bis-methylsulfanyl-thiophen-3-yl)-ethanone
    —— 4-ethoxyphenyl 4-fluorophenyl sulfide 1361950-28-8 C14H13FOS
    4-ethoxyphenyl 4-fluorophenyl sulfide
    —— 4-(Methylthio)-5-(thien-2-yl)-1,2,3-thiadiazole 114393-69-0 C7H6N2S3
    4-(Methylthio)-5-(thien-2-yl)-1,2,3-thiadiazole
    —— 6-chloro-3-thioxo-2,3-dihydro-1,4,2-benzodithiazine 1,1-dioxide 642442-13-5 C7H4ClNO2S3
    6-chloro-3-thioxo-2,3-dihydro-1,4,2-benzodithiazine 1,1-dioxide
    —— 6-chloro-3-({6-[2-(dimethylamino)ethoxy]pyridin-3-yl}thio)-N-(1-methyl-1H-pyrazol-3-yl)pyridine-2-carboxamide 1164103-46-1 C19H21ClN6O2S
    6-chloro-3-({6-[2-(dimethylamino)ethoxy]pyridin-3-yl}thio)-N-(1-methyl-1H-pyrazol-3-yl)pyridine-2-carboxamide
    —— 3-[[5-(2-Thienyl)-1,2,3-thiadiazol-4-yl]thio]propanoic acid, ethyl ester 114393-37-2 C11H12N2O2S3
    3-[[5-(2-Thienyl)-1,2,3-thiadiazol-4-yl]thio]propanoic acid, ethyl ester
    —— 3-[5-(Tetrahydro-pyran-2-yl)-[1,2,3]thiadiazol-4-ylsulfanyl]-propionic acid methyl ester 114414-87-8 C11H16N2O3S2
    3-[5-(Tetrahydro-pyran-2-yl)-[1,2,3]thiadiazol-4-ylsulfanyl]-propionic acid methyl ester
    —— 3-[[5-(4-Fluorophenyl)-1,2,3-thiadiazol-4-yl]thio]propanoic acid, ethyl ester 114393-42-9 C13H13FN2O2S2
    3-[[5-(4-Fluorophenyl)-1,2,3-thiadiazol-4-yl]thio]propanoic acid, ethyl ester
    —— 3-[[5-(4-Chlorophenyl)-1,2,3-thiadiazol-4-yl]thio]propanoic acid, ethyl ester 114393-40-7 C13H13ClN2O2S2
    3-[[5-(4-Chlorophenyl)-1,2,3-thiadiazol-4-yl]thio]propanoic acid, ethyl ester
    —— N,N-dimethyl-2-(4-methyl-6-thiophen-2-ylpyrimidin-2-yl)sulfanylethanamine;hydron;bromide —— C13H18BrN3S2
    N,N-dimethyl-2-(4-methyl-6-thiophen-2-ylpyrimidin-2-yl)sulfanylethanamine;hydron;bromide
    —— (4-(1-bromoethyl)phenyl)(trifluoromethyl)-sulfane 1353991-72-6 C9H8BrF3S
    (4-(1-bromoethyl)phenyl)(trifluoromethyl)-sulfane
    —— 9-(cyclobutylmethyl)-6-(1-methyl-1H-tetrazol-5-ylthio)-9H-purine 1384277-49-9 C12H14N8S
    9-(cyclobutylmethyl)-6-(1-methyl-1H-tetrazol-5-ylthio)-9H-purine
    —— (6-methyl-pyridin-2-ylsulfanyl)-phenyl-acetic acid 72007-07-9 C14H13NO2S
    (6-methyl-pyridin-2-ylsulfanyl)-phenyl-acetic acid
    —— 4-methyl-2-methylsulfanyl-6-trichloromethylpyrimidine 168476-20-8 C7H7Cl3N2S
    4-methyl-2-methylsulfanyl-6-trichloromethylpyrimidine
    —— 5-[(4-methylphenyl)thio]-4-phenyl-1,2,3-thiadiazole 338398-44-0 C15H12N2S2
    5-[(4-methylphenyl)thio]-4-phenyl-1,2,3-thiadiazole
    —— 4-methyl-4-phenyl-5-(p-tolylsulfanyl)dihydrofuran-2-one 823213-94-1 C18H18O2S
    4-methyl-4-phenyl-5-(p-tolylsulfanyl)dihydrofuran-2-one
    —— 5-[(4-chlorophenyl)thio]-4-phenyl-1,2,3-thiadiazole 338398-29-1 C14H9ClN2S2
    5-[(4-chlorophenyl)thio]-4-phenyl-1,2,3-thiadiazole
    —— N',N'-dimethyl-N-(4-methylsulfanyl-6-thiophen-2-ylpyrimidin-2-yl)ethane-1,2-diamine;hydron;bromide —— C13H19BrN4S2
    N',N'-dimethyl-N-(4-methylsulfanyl-6-thiophen-2-ylpyrimidin-2-yl)ethane-1,2-diamine;hydron;bromide
    —— N,N-dimethyl-2-(5-methyl-4-thiophen-2-ylpyrimidin-2-yl)sulfanylethanamine;hydron;bromide —— C13H18BrN3S2
    N,N-dimethyl-2-(5-methyl-4-thiophen-2-ylpyrimidin-2-yl)sulfanylethanamine;hydron;bromide
    —— N-((3-fluorophenylthio)methyl)-N-methylacetamide 1352121-35-7 C10H12FNOS
    N-((3-fluorophenylthio)methyl)-N-methylacetamide
    —— 2-[4-(2,4-Dinitro-phenylsulfanyl)-7-methyl-7H-pyrrolo[2,3-d]pyrimidin-5-yl]-ethanol 190771-72-3 C15H13N5O5S
    2-[4-(2,4-Dinitro-phenylsulfanyl)-7-methyl-7H-pyrrolo[2,3-d]pyrimidin-5-yl]-ethanol
    —— N-<2''-(dimethylamino)ethyl>-4-(methylthio)-6-thien-2'-ylpyrimidin-2-amine 113669-46-8 C13H18N4S2
    N-<2''-(dimethylamino)ethyl>-4-(methylthio)-6-thien-2'-ylpyrimidin-2-amine
    —— N',N'-dimethyl-N-(2-methylsulfanyl-6-thiophen-2-ylpyrimidin-4-yl)ethane-1,2-diamine;hydron;bromide —— C13H19BrN4S2
    N',N'-dimethyl-N-(2-methylsulfanyl-6-thiophen-2-ylpyrimidin-4-yl)ethane-1,2-diamine;hydron;bromide
    —— 4,6-dimethoxy-2-methylthiopyrimidine-5-carboxaldehyde 90905-47-8 C8H10N2O3S
    4,6-dimethoxy-2-methylthiopyrimidine-5-carboxaldehyde
    —— 6-Amino-2-chloro-5-ethylsulfanyl-nicotinonitrile 107450-34-0 C8H8ClN3S
    6-Amino-2-chloro-5-ethylsulfanyl-nicotinonitrile
    —— Ethyl 2-(4,6-Dimethoxypyrimidin-2-yl)thio-3-(isopropoxy)butanoate 142412-20-2 C15H24N2O5S
    Ethyl 2-(4,6-Dimethoxypyrimidin-2-yl)thio-3-(isopropoxy)butanoate
    —— 7-(phenylthio)hept-6(E)-enal 107010-55-9 C13H16OS
    7-(phenylthio)hept-6(E)-enal
    —— 1-Phenylsulfanyl-undecan-2-one 38793-76-9 C17H26OS
    1-Phenylsulfanyl-undecan-2-one
    —— N-(Thiomethyl)thioglycolsaeureamid 71831-12-4 C3H7NOS2
    N-(Thiomethyl)thioglycolsaeureamid
    —— 2-(4-Cyclopropylphenylthio)benzoesaeure 55038-74-9 C16H14O2S
    2-(4-Cyclopropylphenylthio)benzoesaeure