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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-<(4-nitrophenyl)thio>-3-cyano-5-<4-(ethoxycarbonyl)-styryl>pyridine 95674-62-7 C23H17N3O4S
    2-<(4-nitrophenyl)thio>-3-cyano-5-<4-(ethoxycarbonyl)-styryl>pyridine
    —— 2-phenylsulphanylthiazole-5-carboxaldehyde 263549-98-0 C10H7NOS2
    2-phenylsulphanylthiazole-5-carboxaldehyde
    —— diethyl 2-(2-phenylsulphanylthiazol-5-yl)methylenemalonate 263549-99-1 C17H17NO4S2
    diethyl 2-(2-phenylsulphanylthiazol-5-yl)methylenemalonate
    —— (E)-3-(2-phenylsulphanylthiazol-5-yl)propenoic acid 263549-87-7 C12H9NO2S2
    (E)-3-(2-phenylsulphanylthiazol-5-yl)propenoic acid
    —— 2-(2-phenylthioethyl)tetrahydrothiophene 132525-93-0 C12H16S2
    2-(2-phenylthioethyl)tetrahydrothiophene
    —— 3-Benzyl-5,5-dimethyl-4-(4-(methylthio)phenyl)-5H-furan-2-one 189955-82-6 C20H20O2S
    3-Benzyl-5,5-dimethyl-4-(4-(methylthio)phenyl)-5H-furan-2-one
    —— (1-methylsulfonyl-2-propylidene)hydrazine 1363807-31-1 C4H10N2O2S
    (1-methylsulfonyl-2-propylidene)hydrazine
    —— N-((4-methylphenyl)methyl)-N-(1-piperidin-4-yl)(phenylthio)acetamide 359878-03-8 C21H26N2OS
    N-((4-methylphenyl)methyl)-N-(1-piperidin-4-yl)(phenylthio)acetamide
    —— (2-(methylthio)pyrimidin-4-yl)acetonitrile 897648-40-7 C7H7N3S
    (2-(methylthio)pyrimidin-4-yl)acetonitrile
    —— 2,3-dihydro-6-(1,1-dimethylethyl)benzo[b]-1,4-dithiin 127634-82-6 C12H16S2
    2,3-dihydro-6-(1,1-dimethylethyl)benzo[b]-1,4-dithiin
    —— (6R,7S,9R,11R,13R,15R,17R,19S,20E,22R,23R)-23-O-(diethylphosphonoacetyl)-7-O-(1,3-benzodithiolan-2-yl)-9,11:13,15:17,19-tris-O-(1-methylethylidene)-7,9,11,13,15,17,19,23-octahydroxy-6,22,24-trimethyl-2,4,20-pentacosatrienal 155392-02-2 C50H77O13PS2
    (6R,7S,9R,11R,13R,15R,17R,19S,20E,22R,23R)-23-O-(diethylphosphonoacetyl)-7-O-(1,3-benzodithiolan-2-yl)-9,11:13,15:17,19-tris-O-(1-methylethylidene)-7,9,11,13,15,17,19,23-octahydroxy-6,22,24-trimethyl-2,4,20-pentacosatrienal
    —— 4-tert-butylcyclohexyl propyl sulfide 130012-13-4 C13H26S
    4-tert-butylcyclohexyl propyl sulfide
    —— 2-<(p-tolylthio)acetyl>thiophen 99236-24-5 C13H12OS2
    2-<(p-tolylthio)acetyl>thiophen
    —— 1-(methylthio)-1-butene 17414-27-6 C5H10S
    1-(methylthio)-1-butene
    —— bis-(1-methyl-allyl)-disulfane 34776-57-3 C8H14S2
    bis-(1-methyl-allyl)-disulfane
    —— (+/-)-but-2<i>t</i>-enyl-methyl sulfoxide 13159-41-6 C5H10OS
    (+/-)-but-2<i>t</i>-enyl-methyl sulfoxide
    —— (S)-3-[(R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-butyl]-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 503604-08-8 C27H48O4SSi2
    (S)-3-[(R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-butyl]-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one
    —— (2R,3S,5R,7R,9R,11R,13R,15S,16E,18R,19R)-19-O-(diethylphosphonoacetyl)-3-O-(1,3-benzodithiolan-2-yl)-5,7:9,11:13,15-tris-O-(1-methylethylidene)-2,18,20-trimethyl-16-heneicosene-1,3,5,7,9,11,13,15,19-nonol 155392-00-0 C46H75O13PS2
    (2R,3S,5R,7R,9R,11R,13R,15S,16E,18R,19R)-19-O-(diethylphosphonoacetyl)-3-O-(1,3-benzodithiolan-2-yl)-5,7:9,11:13,15-tris-O-(1-methylethylidene)-2,18,20-trimethyl-16-heneicosene-1,3,5,7,9,11,13,15,19-nonol
    —— 1.3-Bis-methanthio-butan 4088-57-7 C6H14S2
    1.3-Bis-methanthio-butan
    —— 4-[4-(2-methylphenyl)(1,3-thiazol-2-yl)]-5-methylthiothiophene-2-carboxamidine hydrochloride 237381-43-0 C16H15N3S3*ClH
    4-[4-(2-methylphenyl)(1,3-thiazol-2-yl)]-5-methylthiothiophene-2-carboxamidine hydrochloride
    —— (Z)-2-(4-methylpiperazin-1-yl)-1-(4-(4-methoxy-phenylthio)-phenyl)-ethanone oxime 122379-17-3 C20H25N3O2S
    (Z)-2-(4-methylpiperazin-1-yl)-1-(4-(4-methoxy-phenylthio)-phenyl)-ethanone oxime
    —— 3-chloro-6-[(4'-fluorophenyl)-thio]-benzyl chloride 54435-29-9 C13H9Cl2FS
    3-chloro-6-[(4'-fluorophenyl)-thio]-benzyl chloride
    —— 2-[4-(4-hydroxyphenylsulfanyl)phenyl]isouronium chloride 1073524-80-7 C13H12N2O2S*ClH
    2-[4-(4-hydroxyphenylsulfanyl)phenyl]isouronium chloride
    —— 4-ethylsulfanyl-2-chloro-phenol 861009-00-9 C8H9ClOS
    4-ethylsulfanyl-2-chloro-phenol
    —— 3-chloro-6-[(4'-fluorophenyl)thio]-phenylacetic acid 54435-46-0 C14H10ClFO2S
    3-chloro-6-[(4'-fluorophenyl)thio]-phenylacetic acid
    —— 2-<7,7-(Ethylenedioxy)octyl>-1,3-dithiane-2-carboxaldehyde 175598-24-0 C15H26O3S2
    2-<7,7-(Ethylenedioxy)octyl>-1,3-dithiane-2-carboxaldehyde
    —— 4-benzylsulfanyl-2-chloro-phenol 107624-64-6 C13H11ClOS
    4-benzylsulfanyl-2-chloro-phenol
    —— 3-fluoro-6-(phenylthio)-benzyl chloride 52548-66-0 C13H10ClFS
    3-fluoro-6-(phenylthio)-benzyl chloride
    —— (5-chloro-2-(4-fluorophenylthio)phenyl)acetonitrile 54435-37-9 C14H9ClFNS
    (5-chloro-2-(4-fluorophenylthio)phenyl)acetonitrile
    —— Ammonium reineckate hydrate 19441-09-9 C12H34Cr3N21O2S12
    Ammonium reineckate hydrate
    —— 3-fluoro-6-(phenylthio)-benzyl alcohol 52548-65-9 C13H11FOS
    3-fluoro-6-(phenylthio)-benzyl alcohol
    —— 3-fluoro-6-(phenylthio)-phenylacetic acid 52548-68-2 C14H11FO2S
    3-fluoro-6-(phenylthio)-phenylacetic acid
    —— 5-Fluoro-2-(phenylthio)-phenylacetonitrile 52548-67-1 C14H10FNS
    5-Fluoro-2-(phenylthio)-phenylacetonitrile
    —— butyl propyl sulfoxide 2977-02-8 C7H16OS
    butyl propyl sulfoxide
    —— 1,5-Bis-decylsulfon-pentan 73771-53-6 C25H52O4S2
    1,5-Bis-decylsulfon-pentan
    —— N-(3,5-difluoro-4-(3-(6-(methylthio)pyrimidin-4-yl)pyrazin-2-ylamino)pyridin-2-yl)propane-1-sulfonamide 1325215-15-3 C17H17F2N7O2S2
    N-(3,5-difluoro-4-(3-(6-(methylthio)pyrimidin-4-yl)pyrazin-2-ylamino)pyridin-2-yl)propane-1-sulfonamide
    —— 5-Acetamino-5-desoxy-L-arabinose-diethyl-dithioacetal 55955-63-0 C11H23NO4S2
    5-Acetamino-5-desoxy-L-arabinose-diethyl-dithioacetal
    —— [(15)N2]-mono(boc)-S-methylisothiourea 1185762-92-8 C7H14N2O2S
    [(15)N2]-mono(boc)-S-methylisothiourea
    —— [(15)N2]-N(boc)-N'(propionyl)-S-methylisothiourea 1185762-93-9 C10H18N2O3S
    [(15)N2]-N(boc)-N'(propionyl)-S-methylisothiourea
    —— (E)-5-butyl-6-(methylthio)-5-hexenenitrile 134629-15-5 C11H19NS
    (E)-5-butyl-6-(methylthio)-5-hexenenitrile
    —— (E)-1-allyl-2-cyclohexyl-1-hexenyl methyl sulfide 134629-16-6 C16H28S
    (E)-1-allyl-2-cyclohexyl-1-hexenyl methyl sulfide
    —— (E)-2-butyl-6-chloro-1-hexenyl methyl sulfide 134653-25-1 C11H21ClS
    (E)-2-butyl-6-chloro-1-hexenyl methyl sulfide
    —— (Z)-1-allyl-2-ethyl-1-hexenyl methyl sulfide 134629-05-3 C12H22S
    (Z)-1-allyl-2-ethyl-1-hexenyl methyl sulfide
    —— (Z)-2-ethyl-1-hexenyl methyl sulfide 134629-04-2 C9H18S
    (Z)-2-ethyl-1-hexenyl methyl sulfide
    —— 1,3,5,8-tetrathiacyclodecane 144681-17-4 C6H12S4
    1,3,5,8-tetrathiacyclodecane
    —— 1,2,4,5-tetrakis(benzylthio)benzene 91900-07-1 C34H30S4
    1,2,4,5-tetrakis(benzylthio)benzene
    —— bis-(carbamimidoylmercapto-methyl)-sulfide 107662-49-7 C4H10N4S3
    bis-(carbamimidoylmercapto-methyl)-sulfide
    —— bis-(phenylsulfanyl-methyl)-sulfide 66694-02-8 C14H14S3
    bis-(phenylsulfanyl-methyl)-sulfide
    —— Bis-acetylmercaptomethyl-sulfid 2242-70-8 C6H10O2S3
    Bis-acetylmercaptomethyl-sulfid
    —— ethyl-dimethyl-sulfonium 24509-90-8 C4H11S
    ethyl-dimethyl-sulfonium