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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-Cyclohexylmethylcyclohexylisothiocyanat 38476-07-2 C14H23NS
    4-Cyclohexylmethylcyclohexylisothiocyanat
    —— N-[2-(5-butyl-6-methylthieno[2,3-c]pyrrol-4-yl)sulfanylethyl]acetamide 1431866-14-6 C15H22N2OS2
    N-[2-(5-butyl-6-methylthieno[2,3-c]pyrrol-4-yl)sulfanylethyl]acetamide
    —— 5,7a-Dihydro-4aH-cyclopenta[b][1,3]dithiolo[4,5-e][1,4]dithiine-2-thione 179009-97-3 C8H6S5
    5,7a-Dihydro-4aH-cyclopenta[b][1,3]dithiolo[4,5-e][1,4]dithiine-2-thione
    —— N-[2-(6-methyl-5-prop-2-enylthieno[2,3-c]pyrrol-4-yl)sulfanylethyl]acetamide 1431866-12-4 C14H18N2OS2
    N-[2-(6-methyl-5-prop-2-enylthieno[2,3-c]pyrrol-4-yl)sulfanylethyl]acetamide
    —— N-[2-[5-(2-hydroxyethyl)-6-methylthieno[2,3-c]pyrrol-4-yl]sulfanylethyl]acetamide 1431866-22-6 C13H18N2O2S2
    N-[2-[5-(2-hydroxyethyl)-6-methylthieno[2,3-c]pyrrol-4-yl]sulfanylethyl]acetamide
    —— 2-[4-(2-Hydroxyethylsulfanyl)-6-methylthieno[2,3-c]pyrrol-5-yl]ethanol 1431866-03-3 C11H15NO2S2
    2-[4-(2-Hydroxyethylsulfanyl)-6-methylthieno[2,3-c]pyrrol-5-yl]ethanol
    —— 3,4-dichloro-N-[5-(2-cyano-4-nitrophenylthio)-1,3,4-thiadiazol-2-yl]-benzamide 244125-89-1 C16H7Cl2N5O3S2
    3,4-dichloro-N-[5-(2-cyano-4-nitrophenylthio)-1,3,4-thiadiazol-2-yl]-benzamide
    —— 7,8,15,16-bisbenzo-10,13-diaza-1,6-dithia-cyclohexadecane 1228649-30-6 C20H26N2S2
    7,8,15,16-bisbenzo-10,13-diaza-1,6-dithia-cyclohexadecane
    —— rac-3-[2,2-bis(trifluoromethyl)-5-oxo-1,3-oxathiolan-4-yl]propionyl chloride 603961-01-9 C8H5ClF6O3S
    rac-3-[2,2-bis(trifluoromethyl)-5-oxo-1,3-oxathiolan-4-yl]propionyl chloride
    —— (5-Oxo-2,2-bis-trifluoromethyl-[1,3]oxathiolan-4-ylmethyl)-carbamic acid tert-butyl ester 184914-18-9 C11H13F6NO4S
    (5-Oxo-2,2-bis-trifluoromethyl-[1,3]oxathiolan-4-ylmethyl)-carbamic acid tert-butyl ester
    —— 4-(2,2,2-Trifluoro-ethyl)-2,2-bis-trifluoromethyl-[1,3]oxathiolan-5-one 291772-68-4 C7H3F9O2S
    4-(2,2,2-Trifluoro-ethyl)-2,2-bis-trifluoromethyl-[1,3]oxathiolan-5-one
    —— 2,2-bis(trifluoromethyl)-4-(2-oxopropyl)-1,3-oxathiolan-5-one 774603-35-9 C8H6F6O3S
    2,2-bis(trifluoromethyl)-4-(2-oxopropyl)-1,3-oxathiolan-5-one
    —— tert-butyl rac-3-[2,2-bis(trifluoromethyl)-5-oxo-1,3-oxathiolan-4-yl]propionate 603960-98-1 C12H14F6O4S
    tert-butyl rac-3-[2,2-bis(trifluoromethyl)-5-oxo-1,3-oxathiolan-4-yl]propionate
    —— (2-Chlorethyl)-heptyl-sulfon 24475-74-9 C9H19ClO2S
    (2-Chlorethyl)-heptyl-sulfon
    —— 2,2-Dimethylthietan-1,1-dioxid 31462-45-0 C5H10O2S
    2,2-Dimethylthietan-1,1-dioxid
    —— {2-[5-Fluoro-2-(1H-indol-3-ylsulfanyl)-phenyl]-ethyl}-methyl-carbamic acid tert-butyl ester 917390-02-4 C22H25FN2O2S
    {2-[5-Fluoro-2-(1H-indol-3-ylsulfanyl)-phenyl]-ethyl}-methyl-carbamic acid tert-butyl ester
    —— 2-(1-methyl-1H-tetrazol-5-ylthio)-N-phenethylacetamide 140406-25-3 C12H15N5OS
    2-(1-methyl-1H-tetrazol-5-ylthio)-N-phenethylacetamide
    —— (1E)-3,3-dimethyl-1-[2-(methylsulfanyl)phenyl]triaz-1-ene 52416-13-4 C9H13N3S
    (1E)-3,3-dimethyl-1-[2-(methylsulfanyl)phenyl]triaz-1-ene
    —— <i>meso</i>-2,3-dimercapto-butane-1,4-diol 122844-69-3 C4H10O2S2
    <i>meso</i>-2,3-dimercapto-butane-1,4-diol
    —— 2-methylthio-1,4,5,6,7,8-hexahydro-1,3-diazocine hydroiodide 62829-45-2 C7H14N2S*HI
    2-methylthio-1,4,5,6,7,8-hexahydro-1,3-diazocine hydroiodide
    —— 2-(Benzofuran-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-76-4 C14H10N4OS
    2-(Benzofuran-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine
    —— N-(2-chloro-5-(S-2-[18F]fluoromethyl)thiophenyl)-N'-(3-methylthiophenyl)-N'-methyl-guanidine 917894-10-1 C16H17ClFN3S2
    N-(2-chloro-5-(S-2-[18F]fluoromethyl)thiophenyl)-N'-(3-methylthiophenyl)-N'-methyl-guanidine
    —— 2-(2,3-Dihydrobenzofuran-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-71-9 C14H12N4OS
    2-(2,3-Dihydrobenzofuran-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine
    —— N-(2-chloro-5-(S-benzyl)thiophenyl)-N'-(3-thiomethylphenyl)-N'-methyl guanidine 917894-22-5 C22H22ClN3S2
    N-(2-chloro-5-(S-benzyl)thiophenyl)-N'-(3-thiomethylphenyl)-N'-methyl guanidine
    —— 2-(benzofuran-5-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-73-1 C19H16N4OS
    2-(benzofuran-5-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2-(2,3-dihydrobenzofuran-5-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-69-5 C19H18N4OS
    2-(2,3-dihydrobenzofuran-5-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2-(benzylsulfanyl)-5-hydroxy-6-(trifluoromethyl)pyrimidin-4(3H)-one 1417817-41-4 C12H9F3N2O2S
    2-(benzylsulfanyl)-5-hydroxy-6-(trifluoromethyl)pyrimidin-4(3H)-one
    —— 5-Propylamino-3-benzylmercapto-1,2,4-thiadiazol 93042-65-0 C12H15N3S2
    5-Propylamino-3-benzylmercapto-1,2,4-thiadiazol
    —— 2,3-Dihydro-[1,4]dithiino[2,3-d]pyridazine-5,8-diamine 57310-92-6 C6H8N4S2
    2,3-Dihydro-[1,4]dithiino[2,3-d]pyridazine-5,8-diamine
    —— 1-(4,4-Difluorobuta-1,3-dien-2-ylsulfanyl)-4-methylbenzene 1147999-77-6 C11H10F2S
    1-(4,4-Difluorobuta-1,3-dien-2-ylsulfanyl)-4-methylbenzene
    —— 3-Propylmercapto-anilin 27122-81-2 C9H13NS
    3-Propylmercapto-anilin
    —— 2-amino-5-chloro-4-propylthiopyridine 263276-18-2 C8H11ClN2S
    2-amino-5-chloro-4-propylthiopyridine
    —— (E)-3,3,3-trifluoro-1-methylsulfanyl-1-methylsulfinylprop-1-ene 1603829-00-0 C5H7F3OS2
    (E)-3,3,3-trifluoro-1-methylsulfanyl-1-methylsulfinylprop-1-ene
    —— 5-(Methylsulfonyl)-1-pentanol 558466-07-2 C6H14O3S
    5-(Methylsulfonyl)-1-pentanol
    —— Acetic acid (5R,6S,7S,8aR,10aR)-6-acetoxy-1,3,7-trimethyl-2,4-dioxo-1,2,3,4,6,7,8a,10a-octahydro-5H-8,9-dioxa-10-thia-1,3-diaza-anthracen-5-yl ester —— C16H20N2O8S
    Acetic acid (5R,6S,7S,8aR,10aR)-6-acetoxy-1,3,7-trimethyl-2,4-dioxo-1,2,3,4,6,7,8a,10a-octahydro-5H-8,9-dioxa-10-thia-1,3-diaza-anthracen-5-yl ester
    —— p-tolyl 3-azido-2,3,6-trideoxy-1-thio-β-L-arabino-hexopyranoside —— C13H17N3O2S
    p-tolyl 3-azido-2,3,6-trideoxy-1-thio-β-L-arabino-hexopyranoside
    —— (5-chloro-7-nitro-benzoxazol-2-yl)-[4-(pyridin-4-ylsulfanyl)-phenyl]-amine —— C18H11ClN4O3S
    (5-chloro-7-nitro-benzoxazol-2-yl)-[4-(pyridin-4-ylsulfanyl)-phenyl]-amine
    —— 4-Isopropylsulfanyl-5-methyl-3-oxo-3H-isoxazole-2-carbonyl chloride —— C8H10ClNO3S
    4-Isopropylsulfanyl-5-methyl-3-oxo-3H-isoxazole-2-carbonyl chloride
    —— p-tolyl 3-azido-2,3,6-trideoxy-1-thio-β-L-ribo-hexopyranoside —— C13H17N3O2S
    p-tolyl 3-azido-2,3,6-trideoxy-1-thio-β-L-ribo-hexopyranoside
    —— p-tolyl 3-azido-2,3,6-trideoxy-1-thio-α-L-ribo-hexopyranoside —— C13H17N3O2S
    p-tolyl 3-azido-2,3,6-trideoxy-1-thio-α-L-ribo-hexopyranoside
    —— {[3-(tert-butyl)pyrazol-5-yl]amino}-N-(3-(4-pyridylthio)phenyl)carboxamide —— C19H21N5OS
    {[3-(tert-butyl)pyrazol-5-yl]amino}-N-(3-(4-pyridylthio)phenyl)carboxamide
    —— N-(4-dimethylaminophenyl)bis[1]benzothieno[2,3-b:2′,3′-e][1,4]thiazine —— C24H18N2S3
    N-(4-dimethylaminophenyl)bis[1]benzothieno[2,3-b:2′,3′-e][1,4]thiazine
    —— N-(4-methoxyphenyl)bis[1]benzothieno[2,3b:2′,3′-e][1,4]thiazine —— C23H15NOS3
    N-(4-methoxyphenyl)bis[1]benzothieno[2,3b:2′,3′-e][1,4]thiazine
    —— N-(4-chlorophenyl)bis[1]benzothieno[2,3-b:2′,3′-e][1,4]thiazine —— C22H12ClNS3
    N-(4-chlorophenyl)bis[1]benzothieno[2,3-b:2′,3′-e][1,4]thiazine
    —— (1Z,3E)-1-phenyl-2-phenylthio-5-methoxy-1,3-pentadiene —— C18H18OS
    (1Z,3E)-1-phenyl-2-phenylthio-5-methoxy-1,3-pentadiene
    —— 3,4-di-O-acetyl-2-thio-1-O,2-S-(1,2,3,6-tetrahydro-2,6-dioxo-4,5-pyrimidinediyl)-β-L-rhamnopyranose —— C14H16N2O8S
    3,4-di-O-acetyl-2-thio-1-O,2-S-(1,2,3,6-tetrahydro-2,6-dioxo-4,5-pyrimidinediyl)-β-L-rhamnopyranose
    —— (Z)-1-phenyl-2-phenylsulfanyl-4-trimethylsilyl-but-1-en-3-yne —— C19H20SSi
    (Z)-1-phenyl-2-phenylsulfanyl-4-trimethylsilyl-but-1-en-3-yne
    —— (2-hydrazino-7-methylthiazolo[4,5-d]pyrimidin-5-ylsulfanyl)acetic acid hydrazide —— C8H11N7OS2
    (2-hydrazino-7-methylthiazolo[4,5-d]pyrimidin-5-ylsulfanyl)acetic acid hydrazide
    —— [7-methyl-2-(morpholin-4-yl)thiazolo[4,5-d]pyrimidin-5-ylsulfanyl]acetic acid ethyl ester —— C14H18N4O3S2
    [7-methyl-2-(morpholin-4-yl)thiazolo[4,5-d]pyrimidin-5-ylsulfanyl]acetic acid ethyl ester
    —— Diethyl-thiocarbamic acid S-(2,4,5-trichloro-phenyl) ester 22857-77-8 C11H12Cl3NOS
    Diethyl-thiocarbamic acid S-(2,4,5-trichloro-phenyl) ester