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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,3-dihydro-5-oxo-7-(2-thienyl)-5H-thiazolo<3,2-a>pyrimidine-6-carbonitrile 109552-70-7 C11H7N3OS2
    2,3-dihydro-5-oxo-7-(2-thienyl)-5H-thiazolo<3,2-a>pyrimidine-6-carbonitrile
    —— 2,2-Dimethyl-4-(3-oxo-butyl)-[1,3]oxathiolan-5-one 88802-53-3 C9H14O3S
    2,2-Dimethyl-4-(3-oxo-butyl)-[1,3]oxathiolan-5-one
    —— 5-Methyl-7-methylmercaptotetrazolo<1.5-a>pyrimidin 30152-89-7 C6H7N5S
    5-Methyl-7-methylmercaptotetrazolo<1.5-a>pyrimidin
    —— 1-Phenyl-4-(pyridin-2-ylsulfanyl)-pyrazolidin-3-one 133043-62-6 C14H13N3OS
    1-Phenyl-4-(pyridin-2-ylsulfanyl)-pyrazolidin-3-one
    —— 3-{[2-(4-amino-furazan-3-yl)-1-ethyl-1H-imidazo[4,5-c]pyridin-6-yl]thio}phenol 850663-88-6 C16H14N6O2S
    3-{[2-(4-amino-furazan-3-yl)-1-ethyl-1H-imidazo[4,5-c]pyridin-6-yl]thio}phenol
    —— 4-(1-Hydroxy-1-methyl-allyl)-2,2-dimethyl-[1,3]oxathiolan-5-one 344408-91-9 C9H14O3S
    4-(1-Hydroxy-1-methyl-allyl)-2,2-dimethyl-[1,3]oxathiolan-5-one
    —— 1-bromo-4-[2-(diphenylphophinothioyl)ethylsulfanyl]benzene 919992-20-4 C20H18BrPS2
    1-bromo-4-[2-(diphenylphophinothioyl)ethylsulfanyl]benzene
    —— 2-(Perfluorohexyl)ethanyl 2-chloroethanyl sulfone 93393-77-2 C10H8ClF13O2S
    2-(Perfluorohexyl)ethanyl 2-chloroethanyl sulfone
    —— 2-(4-Fluorophenyl)-3-(4-(methylthio)phenyl)-4H-thieno [2,3-c]furan-6-one 178614-55-6 C19H13FO2S2
    2-(4-Fluorophenyl)-3-(4-(methylthio)phenyl)-4H-thieno [2,3-c]furan-6-one
    —— 2-tert-butyl-3-methoxy-4-(phenylthio)-6-(trifluoromethyl)pyridine 1204777-20-7 C17H18F3NOS
    2-tert-butyl-3-methoxy-4-(phenylthio)-6-(trifluoromethyl)pyridine
    —— 2-diethylamino-4-oxo-4,5,6,7-tetrahydrothiazolo<1,2-a>-sym-triazine 65248-24-0 C9H14N4OS
    2-diethylamino-4-oxo-4,5,6,7-tetrahydrothiazolo<1,2-a>-sym-triazine
    —— (2-(p-tolylthio)ethyl)diphenylphosphine 1238380-97-6 C21H21PS
    (2-(p-tolylthio)ethyl)diphenylphosphine
    —— diphenyl(2-((4-fluorophenyl)thio)ethyl)phosphane 227174-97-2 C20H18FPS
    diphenyl(2-((4-fluorophenyl)thio)ethyl)phosphane
    —— 2-Dimethylamino-4-oxo-6,7-dihydro-4H-thiazolo[3,2-a][1,3,5]triazine-6-carbonitrile 334507-29-8 C8H9N5OS
    2-Dimethylamino-4-oxo-6,7-dihydro-4H-thiazolo[3,2-a][1,3,5]triazine-6-carbonitrile
    —— 2-Diethylamino-4-oxo-6,7-dihydro-4H-thiazolo[3,2-a][1,3,5]triazine-6-carbonitrile 81287-24-3 C10H13N5OS
    2-Diethylamino-4-oxo-6,7-dihydro-4H-thiazolo[3,2-a][1,3,5]triazine-6-carbonitrile
    —— 2-dimethylamino-4-oxo-4,5,6,7-tetrahydrothiazolo<1,2-a>-sym-triazine 65248-23-9 C7H10N4OS
    2-dimethylamino-4-oxo-4,5,6,7-tetrahydrothiazolo<1,2-a>-sym-triazine
    —— 2-dimethylamino-4-thioxo-4,5,6,7-tetrahydrothiazolo<1,2-a>-sym-triazine 79923-87-8 C7H10N4S2
    2-dimethylamino-4-thioxo-4,5,6,7-tetrahydrothiazolo<1,2-a>-sym-triazine
    —— 2-diethylamino-4-thioxo-4,5,6,7-tetrahydrothiazolo<1,2-a>-sym-triazine 79923-88-9 C9H14N4S2
    2-diethylamino-4-thioxo-4,5,6,7-tetrahydrothiazolo<1,2-a>-sym-triazine
    —— 3-Phenylmercapto-milchsaeure-amid 128677-42-9 C9H11NO2S
    3-Phenylmercapto-milchsaeure-amid
    —— 3-nitro-4-(2,4,6-trimethyl-benzylsulfanyl)-pyridine-2,6-diamine 60282-78-2 C15H18N4O2S
    3-nitro-4-(2,4,6-trimethyl-benzylsulfanyl)-pyridine-2,6-diamine
    —— 4-(2,4,6-trimethyl-benzylsulfanyl)-pyridine-2,3,6-triamine 60282-81-7 C15H20N4S
    4-(2,4,6-trimethyl-benzylsulfanyl)-pyridine-2,3,6-triamine
    —— Bis-<2-(N-isopropylcarbamoyl)phenyl>sulfid 65838-69-9 C20H24N2O2S
    Bis-<2-(N-isopropylcarbamoyl)phenyl>sulfid
    —— 2,2'-sulfanediyl-di-benzoic acid bis-butylamide 34145-26-1 C22H28N2O2S
    2,2'-sulfanediyl-di-benzoic acid bis-butylamide
    —— N-methyl-2-(phenylthio)benzamide 31913-93-6 C14H13NOS
    N-methyl-2-(phenylthio)benzamide
    —— [4-Methyl-2-(2,2,2-trifluoro-1-hydroxy-1-trifluoromethyl-ethyl)-phenylsulfanyl]-acetic acid ethyl ester 63780-80-3 C14H14F6O3S
    [4-Methyl-2-(2,2,2-trifluoro-1-hydroxy-1-trifluoromethyl-ethyl)-phenylsulfanyl]-acetic acid ethyl ester
    —— 2-(5-Chloro-2-phenylsulfanyl-phenyl)-propan-2-ol 57302-42-8 C15H15ClOS
    2-(5-Chloro-2-phenylsulfanyl-phenyl)-propan-2-ol
    —— (3,5-bis(phenylthiomethyl)phenyl)trimethylsilane 1332700-23-8 C23H26S2Si
    (3,5-bis(phenylthiomethyl)phenyl)trimethylsilane
    —— Di-<2-decylamino-ethyl>-disulfid 45298-59-7 C24H52N2S2
    Di-<2-decylamino-ethyl>-disulfid
    —— 2-Phenylthio-N-isopropylbenzamid 65838-73-5 C16H17NOS
    2-Phenylthio-N-isopropylbenzamid
    —— 2-(butylthio)-4,6-dichloro-pyrimidine 883870-63-1 C8H10Cl2N2S
    2-(butylthio)-4,6-dichloro-pyrimidine
    —— N'-isopropylidene-hydrazinecarbothioic acid S-propyl ester 222625-75-4 C7H14N2OS
    N'-isopropylidene-hydrazinecarbothioic acid S-propyl ester
    —— 3-[2-[(2-Hydroxyphenyl)methylideneamino]phenyl]sulfanylpropanenitrile 82654-94-2 C16H14N2OS
    3-[2-[(2-Hydroxyphenyl)methylideneamino]phenyl]sulfanylpropanenitrile
    —— [2-Methyl-1,3-bis(phenylsulfanyl)propyl]sulfanylbenzene 69519-82-0 C22H22S3
    [2-Methyl-1,3-bis(phenylsulfanyl)propyl]sulfanylbenzene
    —— 1-[Bromo(1,1,2,2,3,3,4,4,4-nonafluorobutylsulfonyl)methyl]sulfonyl-1,1,2,2,3,3,4,4,4-nonafluorobutane 30416-81-0 C9HBrF18O4S2
    1-[Bromo(1,1,2,2,3,3,4,4,4-nonafluorobutylsulfonyl)methyl]sulfonyl-1,1,2,2,3,3,4,4,4-nonafluorobutane
    —— 2-(2,3-dihydro-2-benzothiophene-yl)-2-imidazoline 89197-29-5 C11H12N2S
    2-(2,3-dihydro-2-benzothiophene-yl)-2-imidazoline
    —— 2-Methanesulfonyl-2-methylpropanoyl chloride 1017540-45-2 C5H9ClO3S
    2-Methanesulfonyl-2-methylpropanoyl chloride
    —— 2-Ethyl-[1,3]dithiane-2-carboxylic acid 344325-97-9 C7H12O2S2
    2-Ethyl-[1,3]dithiane-2-carboxylic acid
    —— 5,5-Dimethyl-2-(phenylsulfanylmethyl)cyclohexane-1,3-dione 23853-46-5 C15H18O2S
    5,5-Dimethyl-2-(phenylsulfanylmethyl)cyclohexane-1,3-dione
    —— 1-(4-Chloro-benzyloxymethyl)-5-ethyl-6-phenylsulfanyl-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one 136160-43-5 C20H19ClN2O2S2
    1-(4-Chloro-benzyloxymethyl)-5-ethyl-6-phenylsulfanyl-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one
    —— 3-Chloro-4-phenylsulfanylmethyl-phenylamine 87740-23-6 C13H12ClNS
    3-Chloro-4-phenylsulfanylmethyl-phenylamine
    —— (R/S)-4-(2-phenylpropylthio)aniline 1415902-51-0 C15H17NS
    (R/S)-4-(2-phenylpropylthio)aniline
    —— (R/S)-2-(2-phenylpropylthio)aniline 1415902-50-9 C15H17NS
    (R/S)-2-(2-phenylpropylthio)aniline
    —— 4-(2-phenyl-[1,3]dithian-2-yl)-dihydro-furan-2-one 62096-76-8 C14H16O2S2
    4-(2-phenyl-[1,3]dithian-2-yl)-dihydro-furan-2-one
    —— (R/S)-3-(2-phenylpropylthio)aniline 1206795-93-8 C15H17NS
    (R/S)-3-(2-phenylpropylthio)aniline
    —— benzo<f>pyrido<4,3-b><1,4>thiazepin-10(11H)-one 106515-32-6 C12H8N2OS
    benzo<f>pyrido<4,3-b><1,4>thiazepin-10(11H)-one
    —— 2-(1-hydroxy-1-phenyl-5,6,7,8-tetrahydro-2H-[1,3]thiazolo[3,2-a]benzimidazol-2-yl)acetic acid 66077-80-3 C17H18N2O3S
    2-(1-hydroxy-1-phenyl-5,6,7,8-tetrahydro-2H-[1,3]thiazolo[3,2-a]benzimidazol-2-yl)acetic acid
    —— 5-fluoro-N1-(2-(methylthio)phenyl)benzene-1,2-diamine 1338482-18-0 C13H13FN2S
    5-fluoro-N1-(2-(methylthio)phenyl)benzene-1,2-diamine
    —— 6-(4-Methoxyphenyl)sulfanylpteridine-2,4-diamine 77900-97-1 C13H12N6OS
    6-(4-Methoxyphenyl)sulfanylpteridine-2,4-diamine
    —— [3-(5-nitro-pyridin-2-ylamino)-pyridin-2-ylsulfanyl]-acetic acid 60780-94-1 C12H10N4O4S
    [3-(5-nitro-pyridin-2-ylamino)-pyridin-2-ylsulfanyl]-acetic acid
    —— 1,2,3,4,5,6-hexahydro-2-methylspiro[7H-cyclopenta[c]pyridine-7,2'-[1,3]dithiolane] 436849-39-7 C11H17NS2
    1,2,3,4,5,6-hexahydro-2-methylspiro[7H-cyclopenta[c]pyridine-7,2'-[1,3]dithiolane]