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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-Phenyl-1-oxa-4-thiaspiro[4.5]decane 98204-53-6 C14H18OS
    3-Phenyl-1-oxa-4-thiaspiro[4.5]decane
    —— ethyl (1S,2S)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate 63012-13-5 C12H14O2S
    ethyl (1S,2S)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate
    —— ethyl 2-(phenylsulfanyl)cyclopropane-1-carboxylate 91496-20-7 C12H14O2S
    ethyl 2-(phenylsulfanyl)cyclopropane-1-carboxylate
    —— 1-bromo-4-[(2-methoxyethyl)thio]benzene 73655-43-3 C9H11BrOS
    1-bromo-4-[(2-methoxyethyl)thio]benzene
    —— 1189340-47-3 C8H9OS
    —— ethyl (1R,2R)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate —— C12H14O2S
    ethyl (1R,2R)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate
    —— {[1-(Phenylselanyl)ethenyl]sulfanyl}benzene 65034-50-6 C14H12SSe
    {[1-(Phenylselanyl)ethenyl]sulfanyl}benzene
    —— Diethylmethyl<2-(phenylthio)ethyl>silan 57787-84-5 C13H22SSi
    Diethylmethyl<2-(phenylthio)ethyl>silan
    —— 1-phenyl-1-phenylthio-1-trimethylsilyltridecane 77815-49-7 C28H44SSi
    1-phenyl-1-phenylthio-1-trimethylsilyltridecane
    —— 1-phenyl-1-phenylthio-1-trimethylsilylbutane 77815-46-4 C19H26SSi
    1-phenyl-1-phenylthio-1-trimethylsilylbutane
    —— 1-phenyl-1-phenylthio-1-trimethylsilylbut-3-ene 77815-50-0 C19H24SSi
    1-phenyl-1-phenylthio-1-trimethylsilylbut-3-ene
    —— (E)-2-oxo-4-phenylsulfanylbut-3-enoic acid 105633-41-8 C10H8O3S
    (E)-2-oxo-4-phenylsulfanylbut-3-enoic acid
    —— [Fluoro(phenyl)methyl]sulfanylbenzene 134988-42-4 C13H11FS
    [Fluoro(phenyl)methyl]sulfanylbenzene
    —— N-hydroxy-N-{1-[4-(benzylthio)phenyl]ethyl}acetamide 115513-97-8 C17H19NO2S
    N-hydroxy-N-{1-[4-(benzylthio)phenyl]ethyl}acetamide
    —— tert-butyl N-benzyl-N-[(Z)-2-phenylsulfanylbut-2-enyl]carbamate 192569-21-4 C22H27NO2S
    tert-butyl N-benzyl-N-[(Z)-2-phenylsulfanylbut-2-enyl]carbamate
    —— tert-butyl N-[(Z)-2-phenylsulfanylbut-2-enyl]carbamate 192569-29-2 C15H21NO2S
    tert-butyl N-[(Z)-2-phenylsulfanylbut-2-enyl]carbamate
    —— 2-[phenyl(phenylthio)methyl]cyclohexanone —— C19H20OS
    2-[phenyl(phenylthio)methyl]cyclohexanone
    —— 8-(2-Bromo-1-phenylsulfanylethylidene)-1,4-dioxaspiro[4.5]decane 474383-56-7 C16H19BrO2S
    8-(2-Bromo-1-phenylsulfanylethylidene)-1,4-dioxaspiro[4.5]decane
    —— 3-(phenyl(phenylthio)methyl)pentane-2,4-dione 51679-37-9 C18H18O2S
    3-(phenyl(phenylthio)methyl)pentane-2,4-dione
    —— 1-methyl-2β-(1-methylethyl)-4β-(phenylthio)pyrrolidine 138491-81-3 C14H21NS
    1-methyl-2β-(1-methylethyl)-4β-(phenylthio)pyrrolidine
    —— di-(μ-chloro)bis-{2-[(phenylthio)methyl]phenyl-C,S}dipalladium(II) 180332-56-3 C26H22Cl2Pd2S2
    di-(μ-chloro)bis-{2-[(phenylthio)methyl]phenyl-C,S}dipalladium(II)
    —— methyl (3R,4R,6R)-3-hydroxy-4-(2-methoxyethoxymethoxy)-6-phenylsulfanylcyclohexene-1-carboxylate 110474-29-8 C18H24O6S
    methyl (3R,4R,6R)-3-hydroxy-4-(2-methoxyethoxymethoxy)-6-phenylsulfanylcyclohexene-1-carboxylate
    —— (E)-4-(phenylthio)but-3-en-1-ol 112471-66-6 C10H12OS
    (E)-4-(phenylthio)but-3-en-1-ol
    —— [(1-ethylhexyl)thio]benzene 13921-17-0 C14H22S
    [(1-ethylhexyl)thio]benzene
    —— methyl (3R,4R,6R)-4-hydroxy-3-(2-methoxyethoxymethoxy)-6-phenylsulfanylcyclohexene-1-carboxylate 110474-30-1 C18H24O6S
    methyl (3R,4R,6R)-4-hydroxy-3-(2-methoxyethoxymethoxy)-6-phenylsulfanylcyclohexene-1-carboxylate
    —— Phenyl 2-deoxy-1-thio-α-L-threo-pentofuranoside 134614-93-0 C11H14O3S
    Phenyl 2-deoxy-1-thio-α-L-threo-pentofuranoside
    —— 5-(phenylthio)-3-o-tolyl-2-isoxazoline 1258507-20-8 C16H15NOS
    5-(phenylthio)-3-o-tolyl-2-isoxazoline
    —— (Z)-8-phenyl-5-(phenylthio)oct-5-en-2-one 1334484-20-6 C20H22OS
    (Z)-8-phenyl-5-(phenylthio)oct-5-en-2-one
    —— 4(R,S)-(Phenylthio)-6(S)-isopropenyl-1(9)-octalin 118575-88-5 C19H24S
    4(R,S)-(Phenylthio)-6(S)-isopropenyl-1(9)-octalin
    —— phenyl 1-(methyldiphenylsilyl)ethenyl sulfide 120395-08-6 C21H20SSi
    phenyl 1-(methyldiphenylsilyl)ethenyl sulfide
    —— 5-(phenylthio)norbornene 91911-07-8 C13H14S
    5-(phenylthio)norbornene
    —— 2-methyl-6-phenylthio-4H-5,6,-dihydropyran 75697-55-1 C12H14OS
    2-methyl-6-phenylthio-4H-5,6,-dihydropyran
    —— (Z)-3-amino-3-cyclohexylprop-2-enethioamide 95882-45-4 C9H16N2S
    (Z)-3-amino-3-cyclohexylprop-2-enethioamide
    —— 2-[2-(1,3,2-Benzodioxaborol-2-yl)-1-phenylsulfanylethyl]-1,3,2-benzodioxaborole 345921-80-4 C20H16B2O4S
    2-[2-(1,3,2-Benzodioxaborol-2-yl)-1-phenylsulfanylethyl]-1,3,2-benzodioxaborole
    —— 1-t-butyldimethylsilyl-1-phenylthioethylene 120395-09-7 C14H22SSi
    1-t-butyldimethylsilyl-1-phenylthioethylene
    —— bicyclo[2.2.1]hept-5-en-2-yl(phenyl)sulfane —— C13H14S
    bicyclo[2.2.1]hept-5-en-2-yl(phenyl)sulfane
    —— methyl (1R,4R,8R)-3-oxo-8-phenylsulfanyl-2-oxabicyclo[2.2.2]oct-5-ene-4-carboxylate 156899-11-5 C15H14O4S
    methyl (1R,4R,8R)-3-oxo-8-phenylsulfanyl-2-oxabicyclo[2.2.2]oct-5-ene-4-carboxylate
    —— 4-ethylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-thiaselenole-2-selone 444603-47-8 C12H18O2S2Se3
    4-ethylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-thiaselenole-2-selone
    —— 4-ethylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-diselenole-2-selone 444603-46-7 C12H18O2SSe4
    4-ethylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-diselenole-2-selone
    —— 3-(phenylsulfanyl)but-3-ene-1,2-diol 432502-72-2 C10H12O2S
    3-(phenylsulfanyl)but-3-ene-1,2-diol
    —— 4-ethylthio-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-thiaselenole-2-one 444603-72-9 C12H18O3S3Se
    4-ethylthio-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-thiaselenole-2-one
    —— (Z)-1-nitro-2-phenylthioethene 130521-15-2 C8H7NO2S
    (Z)-1-nitro-2-phenylthioethene
    —— cis-/trans-1,3-Bis(mercaptomethyl)cyclohexane 4396-95-6 C8H16S2
    cis-/trans-1,3-Bis(mercaptomethyl)cyclohexane
    —— 4-chloro-2-methyl-butane-2-thiol 98137-31-6 C5H11ClS
    4-chloro-2-methyl-butane-2-thiol
    —— 2-chloro-3-methylthio-2-propenenitrile 127729-12-8 C4H4ClNS
    2-chloro-3-methylthio-2-propenenitrile
    —— acetone(6-chloropyridin-2-yl)[5-iodo-2-(methylthio)pyrimidin-4-yl]hydrazone 955369-81-0 C13H13ClIN5S
    acetone(6-chloropyridin-2-yl)[5-iodo-2-(methylthio)pyrimidin-4-yl]hydrazone
    —— 5-(Phenylthio)-3H-pyrrolizin 81927-41-5 C13H11NS
    5-(Phenylthio)-3H-pyrrolizin
    —— (2,3-Dihydro-5-oxo-5H-thiazolo(3,2-a)pyrimidin-6-yl)carbamic acid ethyl ester 93501-14-5 C9H11N3O3S
    (2,3-Dihydro-5-oxo-5H-thiazolo(3,2-a)pyrimidin-6-yl)carbamic acid ethyl ester
    —— methyl 2,3-dihydro-5H-oxothiazolo<3,2-a>pyrimidine-6-carbamate 93501-13-4 C8H9N3O3S
    methyl 2,3-dihydro-5H-oxothiazolo<3,2-a>pyrimidine-6-carbamate
    —— Benzene, [(1-chloro-2,2-difluoroethenyl)thio]- 102688-06-2 C8H5ClF2S
    Benzene, [(1-chloro-2,2-difluoroethenyl)thio]-