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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[2-Nitro-4-(trifluoromethyl)phenyl]sulfanylthiophene-2-carboxylic acid 104636-61-5 C12H6F3NO4S2
    3-[2-Nitro-4-(trifluoromethyl)phenyl]sulfanylthiophene-2-carboxylic acid
    —— Propanal S,S-diethylacetal S-oxide 49585-39-9 C7H16OS2
    Propanal S,S-diethylacetal S-oxide
    —— 1-(4-(benzylthio)phenyl)ethanol 1344980-59-1 C15H16OS
    1-(4-(benzylthio)phenyl)ethanol
    —— N.N-Dimethyl-O-isopropyl-thiocarbaminsaeureester 24060-02-4 C6H13NOS
    N.N-Dimethyl-O-isopropyl-thiocarbaminsaeureester
    —— N-Methyl-N-cyclohexyl-thiocarbamoyl-chlorid 24053-58-5 C8H14ClNS
    N-Methyl-N-cyclohexyl-thiocarbamoyl-chlorid
    —— methyl 3-oxo-2-<(phenylthio)trimethylsilylmethyl>butyrate 123315-27-5 C15H22O3SSi
    methyl 3-oxo-2-<(phenylthio)trimethylsilylmethyl>butyrate
    —— 4-[[3-(Phenylsulfanylmethyl)-5-propylsulfanyl-1,2,4-triazol-4-yl]methyl]aniline 1027660-97-4 C19H22N4S2
    4-[[3-(Phenylsulfanylmethyl)-5-propylsulfanyl-1,2,4-triazol-4-yl]methyl]aniline
    —— 4-[(3-Benzyl-5-ethylsulfanyl-1,2,4-triazol-4-yl)methyl]aniline 1028279-52-8 C18H20N4S
    4-[(3-Benzyl-5-ethylsulfanyl-1,2,4-triazol-4-yl)methyl]aniline
    —— 4-[[3-(2-Phenylethyl)-5-propylsulfanyl-1,2,4-triazol-4-yl]methyl]aniline 1027060-33-8 C20H24N4S
    4-[[3-(2-Phenylethyl)-5-propylsulfanyl-1,2,4-triazol-4-yl]methyl]aniline
    —— 4-[[3-(3-Phenylpropyl)-5-propylsulfanyl-1,2,4-triazol-4-yl]methyl]aniline 1027051-67-7 C21H26N4S
    4-[[3-(3-Phenylpropyl)-5-propylsulfanyl-1,2,4-triazol-4-yl]methyl]aniline
    —— 4-[(3-Benzyl-5-propylsulfanyl-1,2,4-triazol-4-yl)methyl]aniline 1026371-96-9 C19H22N4S
    4-[(3-Benzyl-5-propylsulfanyl-1,2,4-triazol-4-yl)methyl]aniline
    —— 4-(4-aminobenzyl)-3-ethylthio-5-methoxymethyl-4H-1,2,4-triazole 134402-71-4 C13H18N4OS
    4-(4-aminobenzyl)-3-ethylthio-5-methoxymethyl-4H-1,2,4-triazole
    —— 4-(4-aminobenzyl)-3-ethylthio-5-trifluoromethyl-4H-1,2,4-triazole 134402-68-9 C12H13F3N4S
    4-(4-aminobenzyl)-3-ethylthio-5-trifluoromethyl-4H-1,2,4-triazole
    —— 2-Bromo-5-(pentylthio)thiazolo[4,5-d]pyrimidin-7(4H)-one 259100-49-7 C10H12BrN3OS2
    2-Bromo-5-(pentylthio)thiazolo[4,5-d]pyrimidin-7(4H)-one
    —— 7-chloro-5-(pentylthio)thiazolo[4,5-d]pyrimidin-2-amine 259103-39-4 C10H13ClN4S2
    7-chloro-5-(pentylthio)thiazolo[4,5-d]pyrimidin-2-amine
    —— 6-amino-2-pentylsulfanyl-3H-pyrimidin-4-one —— C9H15N3OS
    6-amino-2-pentylsulfanyl-3H-pyrimidin-4-one
    —— 2,4-dimethyl-4-(phenylthio)-2-pentanol 132102-27-3 C13H20OS
    2,4-dimethyl-4-(phenylthio)-2-pentanol
    —— 4-methyl-pent-3-ene-2-thione 73501-31-2 C6H10S
    4-methyl-pent-3-ene-2-thione
    —— 2,2'-Isopropylidenedithiobis(1-propylamine) 91485-90-4 C9H22N2S2
    2,2'-Isopropylidenedithiobis(1-propylamine)
    —— (R,E)-11-methyl-10-oxa-1,5-dithiaspiro[5.11]heptadec-7-en-9-one 147378-96-9 C15H24O2S2
    (R,E)-11-methyl-10-oxa-1,5-dithiaspiro[5.11]heptadec-7-en-9-one
    —— N,2-dimethyl-2-(methyldisulfanyl)propan-1-amine 1239587-72-4 C6H15NS2
    N,2-dimethyl-2-(methyldisulfanyl)propan-1-amine
    —— 5-isopropyl-5-methoxy-2-(tricyclo[3.3.1.1-3,7-]decan-1-ylamino)-thiazol-4-one 870708-60-4 C17H26N2O2S
    5-isopropyl-5-methoxy-2-(tricyclo[3.3.1.1-3,7-]decan-1-ylamino)-thiazol-4-one
    —— Bicyclo[2.2.1]hept-2-ene-2-carbonyl isothiocyanate 1134541-29-9 C9H9NOS
    Bicyclo[2.2.1]hept-2-ene-2-carbonyl isothiocyanate
    —— 2-ethylmercapto-5-fluoro-6-trifluoromethyl-3<i>H</i>-pyrimidin-4-one 1513-21-9 C7H6F4N2OS
    2-ethylmercapto-5-fluoro-6-trifluoromethyl-3<i>H</i>-pyrimidin-4-one
    —— 5-Vinyl-[1,3]oxathiole 3-oxide 114274-81-6 C5H6O2S
    5-Vinyl-[1,3]oxathiole 3-oxide
    —— 5-methylsulfanyl-3,6-dihydro-2H-pyrazine-1-carboxylic acid tert-butyl ester 1182359-41-6 C10H18N2O2S
    5-methylsulfanyl-3,6-dihydro-2H-pyrazine-1-carboxylic acid tert-butyl ester
    —— 2,2-dimethyl-1-(1'-methyl-5'-nitro-1'H-pyrrol-2'-yl)propyl p-tolyl sulfide 115975-81-0 C17H22N2O2S
    2,2-dimethyl-1-(1'-methyl-5'-nitro-1'H-pyrrol-2'-yl)propyl p-tolyl sulfide
    —— {3-[5-(3,5-dichloro-phenylsulfanyl)-4-isopropyl-1-pyridin-4-ylmethyl-1H-imidazol-2-ylmethoxycarbonylamino]-propyl}-phosphonic acid 620969-29-1 C23H27Cl2N4O5PS
    {3-[5-(3,5-dichloro-phenylsulfanyl)-4-isopropyl-1-pyridin-4-ylmethyl-1H-imidazol-2-ylmethoxycarbonylamino]-propyl}-phosphonic acid
    —— 14,14-dimethyl-7-methylsulfanyl-3-phenyl-2,13,15-trioxa-8-azatricyclo[9.4.0.04,8]pentadeca-1(11),4,6-trien-12-one 225502-94-3 C20H21NO4S
    14,14-dimethyl-7-methylsulfanyl-3-phenyl-2,13,15-trioxa-8-azatricyclo[9.4.0.04,8]pentadeca-1(11),4,6-trien-12-one
    —— 5-Isopropenyl-[1,3]oxathiole 3-oxide 114274-84-9 C6H8O2S
    5-Isopropenyl-[1,3]oxathiole 3-oxide
    —— Phenyl-2.3-xylyl-sulfid 105336-67-2 C14H14S
    Phenyl-2.3-xylyl-sulfid
    —— 3,4-Dimethylphenyl ethyl sulfide 105336-64-9 C10H14S
    3,4-Dimethylphenyl ethyl sulfide
    —— 2,2'thiobis(6-t-butyl-4-bromophenol) 39769-79-4 C20H24Br2O2S
    2,2'thiobis(6-t-butyl-4-bromophenol)
    —— Di-tert-butyl vic-disulfone 98248-42-1 C8H18O4S2
    Di-tert-butyl vic-disulfone
    —— di-tert-butylsulfonyl dithioanhydride 163362-42-3 C8H18O4S4
    di-tert-butylsulfonyl dithioanhydride
    —— Di-tert-butyl vic-disulfoxide 79599-55-6 C8H18O2S2
    Di-tert-butyl vic-disulfoxide
    —— tert-butylsulfonic tert-butylsulfinic thioanhydride 161151-73-1 C8H18O3S3
    tert-butylsulfonic tert-butylsulfinic thioanhydride
    —— 2,2'thiobis(6-t-butyl-4-chlorophenol) 6012-78-8 C20H24Cl2O2S
    2,2'thiobis(6-t-butyl-4-chlorophenol)
    —— S-Methyl-N-butyl-isothioharnstoff 100319-25-3 C6H14N2S
    S-Methyl-N-butyl-isothioharnstoff
    —— 5-(2-fluorophenyl)-4-(phenylthio)furan-2-carbaldehyde 1138035-95-6 C17H11FO2S
    5-(2-fluorophenyl)-4-(phenylthio)furan-2-carbaldehyde
    —— 2-methyl-4-phenyl-1-(phenylthiol)-3-butyn-2-ol 150587-38-5 C17H16OS
    2-methyl-4-phenyl-1-(phenylthiol)-3-butyn-2-ol
    —— 2-(1-dihydroxyboranyl-1-methyl-ethyl)-isothiourea; hydrobromide 5271-88-5 BrH*C4H11BN2O2S
    2-(1-dihydroxyboranyl-1-methyl-ethyl)-isothiourea; hydrobromide
    —— Methylen-bis-thioharnstoff 20939-13-3 C3H8N4S2
    Methylen-bis-thioharnstoff
    —— [(3,7-Dimethylocta-1,2,6-trien-1-YL)sulfanyl]benzene 69358-72-1 C16H20S
    [(3,7-Dimethylocta-1,2,6-trien-1-YL)sulfanyl]benzene
    —— 3,6-dihydro-3,6-diphenyl-5-phenylthio-1,2,3-triazolo[4,5-d]pyrimidine-7-one 1364422-19-4 C22H15N5OS
    3,6-dihydro-3,6-diphenyl-5-phenylthio-1,2,3-triazolo[4,5-d]pyrimidine-7-one
    —— 6-isothiocyanatohexyl isocyanate 118685-44-2 C8H12N2OS
    6-isothiocyanatohexyl isocyanate
    —— 5-[(4-chlorophenyl)thio]-3,6-dihydro-3,6-diphenyl-1,2,3-triazolo[4,5-d]pyrimidine-7-one 1364422-22-9 C22H14ClN5OS
    5-[(4-chlorophenyl)thio]-3,6-dihydro-3,6-diphenyl-1,2,3-triazolo[4,5-d]pyrimidine-7-one
    —— bis[3-(cyclohept-1-enyl)propargyl] sulfoxide 432546-16-2 C20H26OS
    bis[3-(cyclohept-1-enyl)propargyl] sulfoxide
    —— bis[3-(cyclohept-1-enyl)propargyl] sulfide 432546-11-7 C20H26S
    bis[3-(cyclohept-1-enyl)propargyl] sulfide
    —— 2,2-dimethyl-[1,3]dithiane-1,1,3,3-tetraoxide 69489-99-2 C6H12O4S2
    2,2-dimethyl-[1,3]dithiane-1,1,3,3-tetraoxide