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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(5-formylfuran-2-ylthio)-N-tert-butylbenzamide 1002759-93-4 C16H17NO3S
    2-(5-formylfuran-2-ylthio)-N-tert-butylbenzamide
    —— 2-trifluoromethylsulfonylethylamine hydrochloride 1275596-06-9 C3H6F3NO2S*ClH
    2-trifluoromethylsulfonylethylamine hydrochloride
    —— 2-(2,2,2-trifluoroethylsulfonyl)ethylammonium chloride 1275596-05-8 C4H8F3NO2S*ClH
    2-(2,2,2-trifluoroethylsulfonyl)ethylammonium chloride
    —— bis(o-tolylthio)methane 69984-33-4 C15H16S2
    bis(o-tolylthio)methane
    —— 4,5-(2'-methoxy-1',3'-dithiapropano)-1,3-dithiole-2-one 116341-68-5 C5H4OS5
    4,5-(2'-methoxy-1',3'-dithiapropano)-1,3-dithiole-2-one
    —— 2-Methyl-4-ethyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3 53265-24-0 C9H11N3OS
    2-Methyl-4-ethyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3
    —— 5-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methoxybenzene-1,2-diol 1174331-76-0 C15H12N2O4S
    5-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methoxybenzene-1,2-diol
    —— 4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methoxybenzene-1,2-diol 1174331-78-2 C15H12N2O4S
    4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methoxybenzene-1,2-diol
    —— Benzyl alcohol, 4-(methylthio)-alpha-(1-(octylamino)propyl)-, hydrochloride 54767-56-5 C19H34ClNOS
    Benzyl alcohol, 4-(methylthio)-alpha-(1-(octylamino)propyl)-, hydrochloride
    —— 2-[(3,4-dihydroxy-5-methoxyphenyl)thio]quinazolin-4(3H)-one 1134436-20-6 C15H12N2O4S
    2-[(3,4-dihydroxy-5-methoxyphenyl)thio]quinazolin-4(3H)-one
    —— 4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methylbenzene-1,2-diol 1174331-79-3 C15H12N2O3S
    4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methylbenzene-1,2-diol
    —— 4-(benzo[d]thiazol-2'-ylthio)-3-methylbenzene-1,2-diol 1521221-52-2 C14H11NO2S2
    4-(benzo[d]thiazol-2'-ylthio)-3-methylbenzene-1,2-diol
    —— 5-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methylbenzene-1,2-diol 1174331-77-1 C15H12N2O3S
    5-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methylbenzene-1,2-diol
    —— Benzyl alcohol, 4-(ethylthio)-alpha-(1-(octylamino)propyl)-, hydrochloride 54767-58-7 C20H36ClNOS
    Benzyl alcohol, 4-(ethylthio)-alpha-(1-(octylamino)propyl)-, hydrochloride
    —— Acetic acid (4R,5R,6S)-2,2,5-trimethyl-6-phenylsulfanylmethyl-[1,3]dioxan-4-ylmethyl ester 193890-11-8 C17H24O4S
    Acetic acid (4R,5R,6S)-2,2,5-trimethyl-6-phenylsulfanylmethyl-[1,3]dioxan-4-ylmethyl ester
    —— ((4R,5R,6S)-2,2,5-Trimethyl-6-phenylsulfanylmethyl-[1,3]dioxan-4-yl)-methanol 193890-12-9 C15H22O3S
    ((4R,5R,6S)-2,2,5-Trimethyl-6-phenylsulfanylmethyl-[1,3]dioxan-4-yl)-methanol
    —— 2-Amino-4-(4-bromo-pyrazol-1-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile 357289-63-5 C9H7BrN6S
    2-Amino-4-(4-bromo-pyrazol-1-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 4-(cyclopropylthio)-1H-pyrazole 1196875-57-6 C6H8N2S
    4-(cyclopropylthio)-1H-pyrazole
    —— 7,7-dimethoxy-5-(phenylthio)heptan-2-one 444168-98-3 C15H22O3S
    7,7-dimethoxy-5-(phenylthio)heptan-2-one
    —— Benzyl alcohol, alpha-(1-(butylamino)propyl)-4-(ethylthio)-, hydrochloride 54767-57-6 C16H28ClNOS
    Benzyl alcohol, alpha-(1-(butylamino)propyl)-4-(ethylthio)-, hydrochloride
    —— [4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid 150535-98-1 C10H12N4O3S
    [4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid
    —— 5-(2,4,6-Trimethyl-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester 823219-91-6 C16H19NO3S
    5-(2,4,6-Trimethyl-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester
    —— 5-(4-toluenesulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide 823220-02-6 C12H12N2O3S
    5-(4-toluenesulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide
    —— [4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid methyl ester 150535-85-6 C11H14N4O3S
    [4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid methyl ester
    —— 2-[4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-propionic acid 150535-99-2 C11H14N4O3S
    2-[4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-propionic acid
    —— 5-(4-fluoro-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide 823220-13-9 C11H9FN2O3S
    5-(4-fluoro-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide
    —— 5-(4-chloro-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide 823220-04-8 C11H9ClN2O3S
    5-(4-chloro-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide
    —— 5-(2-bromo-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide 823220-11-7 C11H9BrN2O3S
    5-(2-bromo-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide
    —— 2-[4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-propionic acid methyl ester 150535-86-7 C12H16N4O3S
    2-[4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-propionic acid methyl ester
    —— 5-(4-Fluoro-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester 823219-96-1 C13H12FNO3S
    5-(4-Fluoro-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester
    —— 5-(3-bromo-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide 823220-12-8 C11H9BrN2O3S
    5-(3-bromo-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide
    —— 5-(2-Bromo-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester 823219-94-9 C13H12BrNO3S
    5-(2-Bromo-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester
    —— 5-(3-Bromo-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester 823219-95-0 C13H12BrNO3S
    5-(3-Bromo-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester
    —— 5-(4-Chloro-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester 823219-87-0 C13H12ClNO3S
    5-(4-Chloro-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester
    —— 1-[((E)-2-Propenyl)-[1,3]dithian-2-yl]-cyclopentanol 106501-01-3 C12H20OS2
    1-[((E)-2-Propenyl)-[1,3]dithian-2-yl]-cyclopentanol
    —— 2-Methyl-3-[(prop-2-en-1-yl)sulfanyl]furan 61720-51-2 C8H10OS
    2-Methyl-3-[(prop-2-en-1-yl)sulfanyl]furan
    —— 4,5-Dihydro-N-(2-(methylthio)phenyl)-1H-imidazol-2-amine monohydriodide 59083-47-5 C10H14IN3S
    4,5-Dihydro-N-(2-(methylthio)phenyl)-1H-imidazol-2-amine monohydriodide
    —— 3-(4-nitro-phenylsulfanyl)-isonicotinic acid 855636-32-7 C12H8N2O4S
    3-(4-nitro-phenylsulfanyl)-isonicotinic acid
    —— 3-(2-nitro-5-chlorothiophenoxy)isonicotinic acid 187658-76-0 C12H7ClN2O4S
    3-(2-nitro-5-chlorothiophenoxy)isonicotinic acid
    —— 2-Methyl-2-(4-methyl-pent-3-enyl)-[1,3]dithiane 112776-67-7 C11H20S2
    2-Methyl-2-(4-methyl-pent-3-enyl)-[1,3]dithiane
    —— 2-((Z)-Hexa-3,5-dienyl)-2-methyl-[1,3]dithiane 112776-74-6 C11H18S2
    2-((Z)-Hexa-3,5-dienyl)-2-methyl-[1,3]dithiane
    —— 2-((E)-Hex-3-enyl)-2-methyl-[1,3]dithiane 112776-59-7 C11H20S2
    2-((E)-Hex-3-enyl)-2-methyl-[1,3]dithiane
    —— 2-((Z)-Hex-3-enyl)-2-methyl-[1,3]dithiane 112776-58-6 C11H20S2
    2-((Z)-Hex-3-enyl)-2-methyl-[1,3]dithiane
    —— Benzyl alcohol, alpha-(1-(butylamino)propyl)-4-(methylthio)-, hydrochloride 54767-55-4 C15H26ClNOS
    Benzyl alcohol, alpha-(1-(butylamino)propyl)-4-(methylthio)-, hydrochloride
    —— 2-[((E)-2-Propenyl)-[1,3]dithian-2-yl]-heptan-2-ol 106501-24-0 C14H26OS2
    2-[((E)-2-Propenyl)-[1,3]dithian-2-yl]-heptan-2-ol
    —— 1-[((E)-2-Propenyl)-[1,3]dithian-2-yl]-cyclohex-2-enol 106501-34-2 C13H20OS2
    1-[((E)-2-Propenyl)-[1,3]dithian-2-yl]-cyclohex-2-enol
    —— 1-(3-Phenylthiopropyl)-5-methylbicyclo<3.2.1>oct-3-en-2-on 67316-21-6 C18H22OS
    1-(3-Phenylthiopropyl)-5-methylbicyclo<3.2.1>oct-3-en-2-on
    —— prop-2-yn-1-yl(o-tolyl)sulfane 5651-85-4 C10H10S
    prop-2-yn-1-yl(o-tolyl)sulfane
    —— Cyclopropanon-diethylthioketal 27482-16-2 C7H14S2
    Cyclopropanon-diethylthioketal
    —— 1-[((E)-2-Propenyl)-[1,3]dithian-2-yl]-cycloheptanol 106501-19-3 C14H24OS2
    1-[((E)-2-Propenyl)-[1,3]dithian-2-yl]-cycloheptanol