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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-ethoxy-5-cyano-2-methylthio-4-thiomorpholino-pyrimidine 56035-96-2 C12H16N4OS2
    6-ethoxy-5-cyano-2-methylthio-4-thiomorpholino-pyrimidine
    —— 4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 56032-59-8 C13H20N4O3S2
    4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine
    —— 2-(2-benzyl-1,3-dithian-2-yl)acetaldehyde 1258948-52-5 C13H16OS2
    2-(2-benzyl-1,3-dithian-2-yl)acetaldehyde
    —— 4,8-Dithia-spiro[2.5]octan-1-ol 78633-19-9 C6H10OS2
    4,8-Dithia-spiro[2.5]octan-1-ol
    —— 5-cyano-2-methylthio-6-(n-propoxy)-4-thiomorpholino-pyrimidine 56036-00-1 C13H18N4OS2
    5-cyano-2-methylthio-6-(n-propoxy)-4-thiomorpholino-pyrimidine
    —— <2>Thienylmercapto-essigsaeure-amid 14725-29-2 C6H7NOS2
    <2>Thienylmercapto-essigsaeure-amid
    —— 6-methyl-2-methylthio-3-cyanomethyl-4-pyrimidone 148291-50-3 C8H9N3OS
    6-methyl-2-methylthio-3-cyanomethyl-4-pyrimidone
    —— 4-(6-isopropoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 56032-55-4 C12H18N4O3S2
    4-(6-isopropoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine
    —— 4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-morpholine 56032-60-1 C13H20N4O4S
    4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-morpholine
    —— 5-cyano-2-methylthio-4-morpholino-6-(n-propoxy)-pyrimidine 56035-99-5 C13H18N4O2S
    5-cyano-2-methylthio-4-morpholino-6-(n-propoxy)-pyrimidine
    —— 2-chloro-8-phenethylthio-4-thiomorpholino-pyrimido-[5,4-d]-pyrimidine 77748-97-1 C18H18ClN5S2
    2-chloro-8-phenethylthio-4-thiomorpholino-pyrimido-[5,4-d]-pyrimidine
    —— 4,6-dichloro-5-dichloromethyl-2-methylsulfanyl-pyrimidine 56032-82-7 C6H4Cl4N2S
    4,6-dichloro-5-dichloromethyl-2-methylsulfanyl-pyrimidine
    —— 2-chloro-4-morpholino-8-propylthio-pyrimido-[5,4-d]-pyrimidine 77748-85-7 C13H16ClN5OS
    2-chloro-4-morpholino-8-propylthio-pyrimido-[5,4-d]-pyrimidine
    —— 6-ethoxy-5-cyano-2-methylthio-4-morpholino-pyrimidine 56035-95-1 C12H16N4O2S
    6-ethoxy-5-cyano-2-methylthio-4-morpholino-pyrimidine
    —— 4-(6-isopropoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-morpholine 56032-56-5 C12H18N4O4S
    4-(6-isopropoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-morpholine
    —— 6-methyl-2-methylthio-4-cyanomethoxypyrimidine 148291-49-0 C8H9N3OS
    6-methyl-2-methylthio-4-cyanomethoxypyrimidine
    —— 6-ethoxy-5-cyano-2-methylthio-4-(1,1-dioxido-thiomorpholino)-pyrimidine 56035-94-0 C12H16N4O3S2
    6-ethoxy-5-cyano-2-methylthio-4-(1,1-dioxido-thiomorpholino)-pyrimidine
    —— methylthioketene 67730-68-1 C3H4S
    methylthioketene
    —— 2-chloro-8-cyclohexylthio-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77748-90-4 C16H20ClN5OS
    2-chloro-8-cyclohexylthio-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 4-ethoxy-2-methylsulfanyl-6-(1-oxo-1λ<sup>4</sup>-thiomorpholin-4-yl)-pyrimidine-5-carbaldehyde 56032-84-9 C12H17N3O3S2
    4-ethoxy-2-methylsulfanyl-6-(1-oxo-1λ<sup>4</sup>-thiomorpholin-4-yl)-pyrimidine-5-carbaldehyde
    —— 4-(6-<i>sec</i>-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 56032-63-4 C13H20N4O3S2
    4-(6-<i>sec</i>-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine
    —— 4-(6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1,1-dioxide 56032-44-1 C11H16N4O5S2
    4-(6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1,1-dioxide
    —— 4-ethoxy-2-methylsulfanyl-6-thiomorpholin-4-yl-pyrimidine-5-carbaldehyde 56032-83-8 C12H17N3O2S2
    4-ethoxy-2-methylsulfanyl-6-thiomorpholin-4-yl-pyrimidine-5-carbaldehyde
    —— 4-(2-methylsulfanyl-5-nitro-6-propoxy-pyrimidin-4-yl)-morpholine 56032-52-1 C12H18N4O4S
    4-(2-methylsulfanyl-5-nitro-6-propoxy-pyrimidin-4-yl)-morpholine
    —— 2-chloro-4-morpholino-8-octylthio-pyrimido-[5,4-d]-pyrimidine 77748-89-1 C18H26ClN5OS
    2-chloro-4-morpholino-8-octylthio-pyrimido-[5,4-d]-pyrimidine
    —— 8-benzylthio-2-chloro-4-(2-methylmorpholino)-pyrimido-[5,4-d]-pyrimidine 77749-00-9 C18H18ClN5OS
    8-benzylthio-2-chloro-4-(2-methylmorpholino)-pyrimido-[5,4-d]-pyrimidine
    —— (3,4-dihydro-6-methyl-2-methylthio-4-oxo-3-pyrimidinyl)acetic acid amide 54069-04-4 C8H11N3O2S
    (3,4-dihydro-6-methyl-2-methylthio-4-oxo-3-pyrimidinyl)acetic acid amide
    —— 8-(2-aminophenyl-thio)-2-chloro-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-19-0 C16H15ClN6OS
    8-(2-aminophenyl-thio)-2-chloro-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— N-(3-ethyl-2-(methylsulfanyl)-5,6-dihydro-4H-furo[2,3-b]pyridin-7-yl)but-3-enamide 438045-27-3 C14H19NO2S
    N-(3-ethyl-2-(methylsulfanyl)-5,6-dihydro-4H-furo[2,3-b]pyridin-7-yl)but-3-enamide
    —— 4-[6-(2,2-dimethyl-propoxy)-2-methylsulfanyl-5-nitro-pyrimidin-4-yl]-thiomorpholine 56032-65-6 C14H22N4O3S2
    4-[6-(2,2-dimethyl-propoxy)-2-methylsulfanyl-5-nitro-pyrimidin-4-yl]-thiomorpholine
    —— 4-(6-allyloxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1,1-dioxide 56032-48-5 C12H16N4O5S2
    4-(6-allyloxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1,1-dioxide
    —— 4-(2-methylsulfanyl-5-nitro-6-propoxy-pyrimidin-4-yl)-thiomorpholine 56032-51-0 C12H18N4O3S2
    4-(2-methylsulfanyl-5-nitro-6-propoxy-pyrimidin-4-yl)-thiomorpholine
    —— 2-Methyl-2H-pyrazino(2,3-b)-1,4-thiazin-3(4H)-one 34057-33-5 C7H7N3OS
    2-Methyl-2H-pyrazino(2,3-b)-1,4-thiazin-3(4H)-one
    —— 4-(6-allyloxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 56032-47-4 C12H16N4O3S2
    4-(6-allyloxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine
    —— 2-chloro-4-morpholino-8-(4-tolylthio)-pyrimido-[5,4-d]-pyrimidine 77749-17-8 C17H16ClN5OS
    2-chloro-4-morpholino-8-(4-tolylthio)-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-4-morpholino-8-pentylthio-pyrimido-[5,4-d]-pyrimidine 77748-88-0 C15H20ClN5OS
    2-chloro-4-morpholino-8-pentylthio-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-4-morpholino-8-phenylthio-pyrimido-[5,4-d]-pyrimidine 77748-91-5 C16H14ClN5OS
    2-chloro-4-morpholino-8-phenylthio-pyrimido-[5,4-d]-pyrimidine
    —— 2'-(2,4-difluorophenylthio)-4'-formylmethanesulfonanilide 119983-76-5 C14H11F2NO3S2
    2'-(2,4-difluorophenylthio)-4'-formylmethanesulfonanilide
    —— 2-chloro-8-methylthio-4-thiomorpholino-pyrimido-[5,4-d]-pyrimidine 77776-77-3 C11H12ClN5S2
    2-chloro-8-methylthio-4-thiomorpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-isopropylthio-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77748-86-8 C13H16ClN5OS
    2-chloro-8-isopropylthio-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-phenylthio-4-thiomorpholino-pyrimido-[5,4-d]-pyrimidine 77776-81-9 C16H14ClN5S2
    2-chloro-8-phenylthio-4-thiomorpholino-pyrimido-[5,4-d]-pyrimidine
    —— 8-butylthio-2-chloro-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77748-87-9 C14H18ClN5OS
    8-butylthio-2-chloro-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-4-morpholino-8-(3-phenylpropyl-thio)-pyrimido-[5,4-d]-pyrimidine 77748-99-3 C19H20ClN5OS
    2-chloro-4-morpholino-8-(3-phenylpropyl-thio)-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(methoxycarbonyl-methylthio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-02-1 C13H14ClN5O3S
    2-chloro-8-(methoxycarbonyl-methylthio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— Z-2-phenyl-3-phenylthiobut-2-ene-1-ol 119044-25-6 C16H16OS
    Z-2-phenyl-3-phenylthiobut-2-ene-1-ol
    —— (E)-2-phenyl-3-phenylthio-but-2-ene-1-ol 119044-24-5 C16H16OS
    (E)-2-phenyl-3-phenylthio-but-2-ene-1-ol
    —— 2-chloro-8-(4-methylbenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-08-7 C18H18ClN5OS
    2-chloro-8-(4-methylbenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(4-fluorophenyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-21-4 C16H13ClFN5OS
    2-chloro-8-(4-fluorophenyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(4-chlorobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-10-1 C17H15Cl2N5OS
    2-chloro-8-(4-chlorobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(2-diethylamino-ethylthio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-03-2 C16H23ClN6OS
    2-chloro-8-(2-diethylamino-ethylthio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine