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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4,4,4-trifluoro-3-methylthio-1-butanol 1086277-27-1 C5H9F3OS
    4,4,4-trifluoro-3-methylthio-1-butanol
    —— (R)-ethyl 4,4,4-trifluoro-3-(phenylthio)butanoate 115630-73-4 C12H13F3O2S
    (R)-ethyl 4,4,4-trifluoro-3-(phenylthio)butanoate
    —— (S)-ethyl 4,4,4-trifluoro-3-(phenylthio)butanoate 1318254-44-2 C12H13F3O2S
    (S)-ethyl 4,4,4-trifluoro-3-(phenylthio)butanoate
    —— 8-Fluor-1-azaphenothiazin 117326-41-7 C11H7FN2S
    8-Fluor-1-azaphenothiazin
    —— 8-Trifluormethyl-1-azaphenothiazin 112723-37-2 C12H7F3N2S
    8-Trifluormethyl-1-azaphenothiazin
    —— N-(tert-butoxycarbonyl)-3-aminomethyl-6-[(2,2-dimethylpropane)thio]-pyridine 928650-38-8 C16H26N2O2S
    N-(tert-butoxycarbonyl)-3-aminomethyl-6-[(2,2-dimethylpropane)thio]-pyridine
    —— (Z)-2,2-dimethylpropanethial S-oxide 74635-31-7 C5H10OS
    (Z)-2,2-dimethylpropanethial S-oxide
    —— 3-Bromo-5-[(2,2-dimethylpropyl)thio]pyridine 1159826-33-1 C10H14BrNS
    3-Bromo-5-[(2,2-dimethylpropyl)thio]pyridine
    —— dineopentyl sulfide 51616-83-2 C10H22S
    dineopentyl sulfide
    —— 4-(5-(benzylthio)-1,3,4-oxadiazol-2-yl)pyridin-2-amine 1357083-14-7 C14H12N4OS
    4-(5-(benzylthio)-1,3,4-oxadiazol-2-yl)pyridin-2-amine
    —— N-β-Methoxy-cyclohexyl)-S-methyl-thiourethan 23850-19-3 C9H17NO2S
    N-β-Methoxy-cyclohexyl)-S-methyl-thiourethan
    —— 4-tert.-Butyl-2-(2-oxo-propylmercapto)-thiazol 22997-34-8 C10H15NOS2
    4-tert.-Butyl-2-(2-oxo-propylmercapto)-thiazol
    —— 4-tert.-Butyl-2-(3-oxo-butylmercapto)-thiazol 22997-29-1 C11H17NOS2
    4-tert.-Butyl-2-(3-oxo-butylmercapto)-thiazol
    —— allyl butyl sulfoxide 16841-62-6 C7H14OS
    allyl butyl sulfoxide
    —— 2-(2-Cyan-ethylmercapto)-4-tert.-butylthiazol 22997-30-4 C10H14N2S2
    2-(2-Cyan-ethylmercapto)-4-tert.-butylthiazol
    —— 2-(2-Cyan-ethylmercapto)-4-phenyl-thiazol 18711-80-3 C12H10N2S2
    2-(2-Cyan-ethylmercapto)-4-phenyl-thiazol
    —— 6-(4-chlorophenyl)-3-methylmercapto-as-triazin-5-one 99074-40-5 C10H8ClN3OS
    6-(4-chlorophenyl)-3-methylmercapto-as-triazin-5-one
    —— bis-(2-acetylamino-4-phenyl-thiazol-5-yl)-sulfide 122352-17-4 C22H18N4O2S3
    bis-(2-acetylamino-4-phenyl-thiazol-5-yl)-sulfide
    —— 2-(4'-Acetylaminophenylthio)-3-cyano-4,6-dimethylpyridine 142531-61-1 C16H15N3OS
    2-(4'-Acetylaminophenylthio)-3-cyano-4,6-dimethylpyridine
    —— 2-(4'-Aminophenylthio)-3-cyano-4,6-dimethylpyridine 112955-01-8 C14H13N3S
    2-(4'-Aminophenylthio)-3-cyano-4,6-dimethylpyridine
    —— 2-(tert-butylthio)-4,6-dimethyl-3-pyridinecarbonitrile 96853-12-2 C12H16N2S
    2-(tert-butylthio)-4,6-dimethyl-3-pyridinecarbonitrile
    —— 2-(4'-Succinamidophenylthio)-3-cyano-4,6-dimethylpyridine 142531-72-4 C18H17N3O3S
    2-(4'-Succinamidophenylthio)-3-cyano-4,6-dimethylpyridine
    —— 2-(2-aminophenylthio)-3-cyano-4,6-dimethylpyridine 285985-67-3 C14H13N3S
    2-(2-aminophenylthio)-3-cyano-4,6-dimethylpyridine
    —— 1-(methanesulfonyl)-7-azido-2-heptyl chloroformate 1346434-41-0 C9H16ClN3O4S
    1-(methanesulfonyl)-7-azido-2-heptyl chloroformate
    —— 1-(methylsulfonyl)-7-azido-2-heptanol 1346434-30-7 C8H17N3O3S
    1-(methylsulfonyl)-7-azido-2-heptanol
    —— 5-[(5-amino-4H-1,2,4-triazol-3-yl)thio]-2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl] amino]-4-pyrimidinol 666752-79-0 C16H17F2N7O2S2
    5-[(5-amino-4H-1,2,4-triazol-3-yl)thio]-2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl] amino]-4-pyrimidinol
    —— S-Ethyl-N-propyl-isothioharnstoff 100319-27-5 C6H14N2S
    S-Ethyl-N-propyl-isothioharnstoff
    —— 5-(prop-2-yn-1-ylthio)-4H-1,2,4-triazol-3-amine 53918-44-8 C5H6N4S
    5-(prop-2-yn-1-ylthio)-4H-1,2,4-triazol-3-amine
    —— S-Methyl-N-propyl-isothioharnstoff 925-59-7 C5H12N2S
    S-Methyl-N-propyl-isothioharnstoff
    —— 6-ethylsulfanyl-5-methyl-3-oxo-2-phenyl-2,3-dihydro-pyridazine-4-carbonitrile 160146-42-9 C14H13N3OS
    6-ethylsulfanyl-5-methyl-3-oxo-2-phenyl-2,3-dihydro-pyridazine-4-carbonitrile
    —— 3-Ethylsulfanyl-5-phenyl-isothiazole-4-carbonitrile 223440-06-0 C12H10N2S2
    3-Ethylsulfanyl-5-phenyl-isothiazole-4-carbonitrile
    —— 3,3'-methylenebis(sulfanediyl)bis(5-phenylisothiazole-4-carbonitrile) 915395-64-1 C21H12N4S4
    3,3'-methylenebis(sulfanediyl)bis(5-phenylisothiazole-4-carbonitrile)
    —— 5-Ethyl-1-((cyclohexyloxy)methyl)-6-(phenylthio)-2-thiouracil 136160-41-3 C19H24N2O2S2
    5-Ethyl-1-((cyclohexyloxy)methyl)-6-(phenylthio)-2-thiouracil
    —— 5-Ethyl-1-(cyclohexyloxy)methyl)-6-(phenylthio)uracil 136160-40-2 C19H24N2O3S
    5-Ethyl-1-(cyclohexyloxy)methyl)-6-(phenylthio)uracil
    —— 5-amino-2-[(6-bromo-1,3-benzodioxol-5-yl)thio]-1-methyl-1H-imidazole-4-carboxamide 1102466-92-1 C12H11BrN4O3S
    5-amino-2-[(6-bromo-1,3-benzodioxol-5-yl)thio]-1-methyl-1H-imidazole-4-carboxamide
    —— 4,4-Bis(ethylsulfonyl)pimelonitril 62943-41-3 C11H18N2O4S2
    4,4-Bis(ethylsulfonyl)pimelonitril
    —— 6-[(6-amino-9H-purin-8-yl)thio]-1,3-benzodioxole-5-carbonitrile 958026-14-7 C13H8N6O2S
    6-[(6-amino-9H-purin-8-yl)thio]-1,3-benzodioxole-5-carbonitrile
    —— tert-butyl 4-(2-{6-amino-8-[(6-bromo-2,2-d<sub>2</sub>-benzo[d][1,3]dioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidine-1-carboxylate 1425565-36-1 C24H29BrN6O4S
    tert-butyl 4-(2-{6-amino-8-[(6-bromo-2,2-d<sub>2</sub>-benzo[d][1,3]dioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidine-1-carboxylate
    —— 8-(6-iodo-benzo[1,3]dioxol-5-ylsulfanyl)-9-(pent-4-ynyl)adenine 873436-90-9 C17H14IN5O2S
    8-(6-iodo-benzo[1,3]dioxol-5-ylsulfanyl)-9-(pent-4-ynyl)adenine
    —— 8-[(6-bromo-2,2-difluoro-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-6-amine 958026-17-0 C12H6BrF2N5O2S
    8-[(6-bromo-2,2-difluoro-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-6-amine
    —— 8-(6-amino-2,3-dihydrobenzofuran-5-ylthio)-9H-purin-6-amine 1289544-20-2 C13H12N6OS
    8-(6-amino-2,3-dihydrobenzofuran-5-ylthio)-9H-purin-6-amine
    —— 8-[(7-nitro-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-6-amine 1156467-97-8 C13H10N6O4S
    8-[(7-nitro-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-6-amine
    —— 8-(2,3-dihydrobenzofuran-6-ylthio)-9H-purin-6-amine 1289544-14-4 C13H11N5OS
    8-(2,3-dihydrobenzofuran-6-ylthio)-9H-purin-6-amine
    —— 2-(4-methyl-2-phenylsulfanylthiazol-5-yl)ethanol 477533-78-1 C12H13NOS2
    2-(4-methyl-2-phenylsulfanylthiazol-5-yl)ethanol
    —— methyl (4-methyl-2-phenylsulfanylthiazol-5-yl)acetate 477533-77-0 C13H13NO2S2
    methyl (4-methyl-2-phenylsulfanylthiazol-5-yl)acetate
    —— 2-Bromo-7-chloro-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidine 333743-68-3 C12H5BrClF2N3S2
    2-Bromo-7-chloro-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidine
    —— 7-chloro-5-(2,3-difluoro-benzylsulfanyl)-3H-thiazolo[4,5-d]pyrimidin-2-one 333743-70-7 C12H6ClF2N3OS2
    7-chloro-5-(2,3-difluoro-benzylsulfanyl)-3H-thiazolo[4,5-d]pyrimidin-2-one
    —— 7-chloro-5-[(2,3-difluorophenylmethyl)thio]-2-methoxythiazolo[4,5-d]pyrimidine 333743-69-4 C13H8ClF2N3OS2
    7-chloro-5-[(2,3-difluorophenylmethyl)thio]-2-methoxythiazolo[4,5-d]pyrimidine
    —— 1,3,5-Oxadiazinane-4-thione 23375-59-9 C3H6N2OS
    1,3,5-Oxadiazinane-4-thione
    —— methyl [(2-bromo-4-chlorophenyl)thio]acetate 882689-77-2 C9H8BrClO2S
    methyl [(2-bromo-4-chlorophenyl)thio]acetate