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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(N-benzylamino)-6-chloro-2-methylthio-5-nitropyrimidine 1097966-93-2 C12H11ClN4O2S
    4-(N-benzylamino)-6-chloro-2-methylthio-5-nitropyrimidine
    —— allyldimethyl[1-octyl-3,3-bis(phenylthio)propoxy]silane 332188-32-6 C28H42OS2Si
    allyldimethyl[1-octyl-3,3-bis(phenylthio)propoxy]silane
    —— 1,1-bis(phenylthio)-3-undecanol 332188-27-9 C23H32OS2
    1,1-bis(phenylthio)-3-undecanol
    —— 1-(4-Methylsulfanylphenyl)but-3-en-1-ol 219788-93-9 C11H14OS
    1-(4-Methylsulfanylphenyl)but-3-en-1-ol
    —— [(E)-4-[dimethyl(phenyl)silyl]but-1-enyl]-dimethyl-(1-phenylsulfanylcyclopropyl)silane 273212-28-5 C23H32SSi2
    [(E)-4-[dimethyl(phenyl)silyl]but-1-enyl]-dimethyl-(1-phenylsulfanylcyclopropyl)silane
    —— allyldimethyl[1-phenethyl-3,3-bis(phenylthio)propoxy]silane 332188-30-4 C28H34OS2Si
    allyldimethyl[1-phenethyl-3,3-bis(phenylthio)propoxy]silane
    —— allyldimethyl[1-phenyl-3,3-bis(phenylthio)propoxy]silane 332188-28-0 C26H30OS2Si
    allyldimethyl[1-phenyl-3,3-bis(phenylthio)propoxy]silane
    —— 4-Benzyl-5-ethylthio-3H-1,2-dithiole-3-thione 176324-59-7 C12H12S4
    4-Benzyl-5-ethylthio-3H-1,2-dithiole-3-thione
    —— 2-(2-Phenylthioethyl)-1-methylpyrrolidine 90238-65-6 C13H19NS
    2-(2-Phenylthioethyl)-1-methylpyrrolidine
    —— Diethylmalonsaeure-bis-thioamid 118897-69-1 C7H14N2S2
    Diethylmalonsaeure-bis-thioamid
    —— N-Methyl-N-(2-dimethylaminoethyl)-2-(3-methoxyphenylthio)benzylamine 127906-92-7 C19H26N2OS
    N-Methyl-N-(2-dimethylaminoethyl)-2-(3-methoxyphenylthio)benzylamine
    —— N-(2-Dimethylaminoethyl)-2-(3-methoxyphenylthio)benzylamine 129162-36-3 C18H24N2OS
    N-(2-Dimethylaminoethyl)-2-(3-methoxyphenylthio)benzylamine
    —— 3,5-dichloro-2-(phenylthio)benzoic acid 79332-30-2 C13H8Cl2O2S
    3,5-dichloro-2-(phenylthio)benzoic acid
    —— 6,7-epoxy-3,7-dimethyl-oct-2-enyl phenyl sulfide 95851-64-2 C16H22OS
    6,7-epoxy-3,7-dimethyl-oct-2-enyl phenyl sulfide
    —— (2R,4E)-4-methyl-1-(2-methyl-1,3-dithian-2-yl)octa-4,7-dien-2-ol 1262763-89-2 C14H24OS2
    (2R,4E)-4-methyl-1-(2-methyl-1,3-dithian-2-yl)octa-4,7-dien-2-ol
    —— 2-(4-bromophenylthio)-2-phenylacetyl chloride 1262226-96-9 C14H10BrClOS
    2-(4-bromophenylthio)-2-phenylacetyl chloride
    —— 2,2,2-tris(phenylthio)acetaldehyde 96014-41-4 C20H16OS3
    2,2,2-tris(phenylthio)acetaldehyde
    —— 5-bromo-2-(3-tolylsulfenyl)methyloxypyrimidine 83768-14-3 C12H11BrN2OS
    5-bromo-2-(3-tolylsulfenyl)methyloxypyrimidine
    —— ethyl {3-[4-(1,3-diphenethylureido)phenylsulphanyl]phenyl}acetate 735273-72-0 C33H34N2O3S
    ethyl {3-[4-(1,3-diphenethylureido)phenylsulphanyl]phenyl}acetate
    —— (2,4,6-Trichlor-phenylmercapto)-essigsaeure 16928-88-4 C8H5Cl3O2S
    (2,4,6-Trichlor-phenylmercapto)-essigsaeure
    —— [(2R,3R,4R,6R)-4-azido-3-hydroxy-6-phenylsulfanyloxan-2-yl]methyl 3-methylbutanoate 1239701-21-3 C17H23N3O4S
    [(2R,3R,4R,6R)-4-azido-3-hydroxy-6-phenylsulfanyloxan-2-yl]methyl 3-methylbutanoate
    —— 5-bromo-1-(3-tolylsulfenyl)methyl-2(1H)-pyrimidinone 83768-13-2 C12H11BrN2OS
    5-bromo-1-(3-tolylsulfenyl)methyl-2(1H)-pyrimidinone
    —— 1,4-bis(3-cyclopentenylsulfonyl)butane 78652-09-2 C14H22O4S2
    1,4-bis(3-cyclopentenylsulfonyl)butane
    —— (Z)-2-ethylnon-2-en-4-yne-1-thiol 260543-73-5 C11H18S
    (Z)-2-ethylnon-2-en-4-yne-1-thiol
    —— methyl 4-[(4-methylphenyl)thio]butanoate 29193-78-0 C12H16O2S
    methyl 4-[(4-methylphenyl)thio]butanoate
    —— 3-isobutyl-4-(phenylthio)-1H-pyrazol-5(4H)-one 1188445-12-6 C13H16N2OS
    3-isobutyl-4-(phenylthio)-1H-pyrazol-5(4H)-one
    —— (2R,3R,4R,6R)-4-azido-2-(hydroxymethyl)-6-phenylsulfanyloxan-3-ol 1239701-19-9 C12H15N3O3S
    (2R,3R,4R,6R)-4-azido-2-(hydroxymethyl)-6-phenylsulfanyloxan-3-ol
    —— 1-(4-fluorophenyl)-3-isobutyl-4-(phenylthio)-1H-pyrazol-5(4H)-one 1188445-21-7 C19H19FN2OS
    1-(4-fluorophenyl)-3-isobutyl-4-(phenylthio)-1H-pyrazol-5(4H)-one
    —— 3-isobutyl-4-(4-chlorophenylthio)-1H-pyrazol-5(4H)-one 1188445-14-8 C13H15ClN2OS
    3-isobutyl-4-(4-chlorophenylthio)-1H-pyrazol-5(4H)-one
    —— O-(2-phenylsulfanylethyl) N-phenylcarbamothioate 1033617-81-0 C15H15NOS2
    O-(2-phenylsulfanylethyl) N-phenylcarbamothioate
    —— 4-amino-1-[(2R,3R,5S,9R)-9-[tert-butyl(dimethyl)silyl]oxy-3-phenylsulfanyl-1-oxaspiro[4.4]nonan-2-yl]pyrimidin-2-one 629666-46-2 C24H35N3O3SSi
    4-amino-1-[(2R,3R,5S,9R)-9-[tert-butyl(dimethyl)silyl]oxy-3-phenylsulfanyl-1-oxaspiro[4.4]nonan-2-yl]pyrimidin-2-one
    —— ethyl [(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetate 476211-49-1 C7H11N3O2S
    ethyl [(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetate
    —— 3-[Tert-butyl(dimethyl)silyl]oxy-4-methyl-5-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpentanoyl chloride 1612831-43-2 C18H27ClF3NO2SSi
    3-[Tert-butyl(dimethyl)silyl]oxy-4-methyl-5-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpentanoyl chloride
    —— (2S,5R)-3,6-dimethoxy-2-(2-phenylsulfanylprop-2-enyl)-5-propan-2-yl-2,5-dihydropyrazine 203920-11-0 C18H24N2O2S
    (2S,5R)-3,6-dimethoxy-2-(2-phenylsulfanylprop-2-enyl)-5-propan-2-yl-2,5-dihydropyrazine
    —— 1-Chlor-2-phenylthio-2-propen 15893-06-8 C9H9ClS
    1-Chlor-2-phenylthio-2-propen
    —— ethyl 2-((4-chlorophenyl)thio)-2-phenylacetate 101282-63-7 C16H15ClO2S
    ethyl 2-((4-chlorophenyl)thio)-2-phenylacetate
    —— ethyl 2-phenyl-2-(phenylthio)penta-3,4-dienoate 1150634-47-1 C19H18O2S
    ethyl 2-phenyl-2-(phenylthio)penta-3,4-dienoate
    —— 1-(4-methylsulfanyl-phenyl)-ethanone semicarbazone 40028-95-3 C10H13N3OS
    1-(4-methylsulfanyl-phenyl)-ethanone semicarbazone
    —— ethyl 2-phenyl-2-(2-bromophenylthio)-4-pentenoate 1150634-41-5 C19H19BrO2S
    ethyl 2-phenyl-2-(2-bromophenylthio)-4-pentenoate
    —— 1-(4-(methylsulfanyl)phenyl)ethylamine 150012-25-2 C9H13NS
    1-(4-(methylsulfanyl)phenyl)ethylamine
    —— 3-amino-4-(4'-metiltiofenil)furazano 89992-06-3 C9H9N3OS
    3-amino-4-(4'-metiltiofenil)furazano
    —— Ethyl 1-phenyl-2-(phenylsulfanylmethyl)-3-(2,2,2-trifluoroethyl)cycloprop-2-ene-1-carboxylate 1394290-93-7 C21H19F3O2S
    Ethyl 1-phenyl-2-(phenylsulfanylmethyl)-3-(2,2,2-trifluoroethyl)cycloprop-2-ene-1-carboxylate
    —— phenyl(5,5,5-trifluoropent-2-ynyl)sulfane 1394290-79-9 C11H9F3S
    phenyl(5,5,5-trifluoropent-2-ynyl)sulfane
    —— ethyl 2-phenyl-2-(phenylthio)pent-4-enoate 1150634-38-0 C19H20O2S
    ethyl 2-phenyl-2-(phenylthio)pent-4-enoate
    —— 3-(4-methylmercaptophenyl)-5-(2-thienyl)-pyrazoline 1097965-34-8 C14H14N2S2
    3-(4-methylmercaptophenyl)-5-(2-thienyl)-pyrazoline
    —— ethyl 2-phenyl-2-(4-bromophenylthio)-4-pentenoate 1150634-40-4 C19H19BrO2S
    ethyl 2-phenyl-2-(4-bromophenylthio)-4-pentenoate
    —— N-(4-chlorophenyl)-5-(4-(methylmercapto)phenyl)-1,3,4-oxadiazol-2-amine 1257256-84-0 C15H12ClN3OS
    N-(4-chlorophenyl)-5-(4-(methylmercapto)phenyl)-1,3,4-oxadiazol-2-amine
    —— N-((5-(4-(methylthio)phenyl)isoxazol-3-yl)methyl)adamantan-1-amine 1443123-64-5 C21H26N2OS
    N-((5-(4-(methylthio)phenyl)isoxazol-3-yl)methyl)adamantan-1-amine
    —— ethyl 2-phenyl-2-(phenylthio)-4-bromo-4-pentenoate 1150634-46-0 C19H19BrO2S
    ethyl 2-phenyl-2-(phenylthio)-4-bromo-4-pentenoate
    —— 5-(4-(methylmercapto)phenyl)-N-phenyl-1,3,4-oxadiazol-2-amine 1257256-66-8 C15H13N3OS
    5-(4-(methylmercapto)phenyl)-N-phenyl-1,3,4-oxadiazol-2-amine