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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— S-Methyl-thiosemicarbazono-cyclohexan 92383-84-1 C8H15N3S
    S-Methyl-thiosemicarbazono-cyclohexan
    —— 2-sec-Butoxy-6-(3,5-dimethyl-phenylsulfanyl)-3H-pyrimidin-4-one 284681-90-9 C16H20N2O2S
    2-sec-Butoxy-6-(3,5-dimethyl-phenylsulfanyl)-3H-pyrimidin-4-one
    —— 2-sec-Butoxy-6-m-tolylsulfanyl-3H-pyrimidin-4-one 284681-91-0 C15H18N2O2S
    2-sec-Butoxy-6-m-tolylsulfanyl-3H-pyrimidin-4-one
    —— 6-sec-Butoxy-2-p-tolylsulfanyl-pyrimidin-4-ylamine 284681-47-6 C15H19N3OS
    6-sec-Butoxy-2-p-tolylsulfanyl-pyrimidin-4-ylamine
    —— 4(1H)-Pyrimidinone, 2-(butylthio)-6-(2-naphthalenylthio)- 284682-04-8 C18H18N2OS2
    4(1H)-Pyrimidinone, 2-(butylthio)-6-(2-naphthalenylthio)-
    —— 6-sec-Butoxy-2-(4-methoxy-phenylsulfanyl)-pyrimidin-4-ylamine 284681-53-4 C15H19N3O2S
    6-sec-Butoxy-2-(4-methoxy-phenylsulfanyl)-pyrimidin-4-ylamine
    —— 2-(2-Amino-4-chloro-phenylsulfanyl)-6-sec-butoxy-pyrimidin-4-ylamine 284681-58-9 C14H17ClN4OS
    2-(2-Amino-4-chloro-phenylsulfanyl)-6-sec-butoxy-pyrimidin-4-ylamine
    —— 6-sec-Butoxy-2-(2-methoxy-phenylsulfanyl)-pyrimidin-4-ylamine 284681-51-2 C15H19N3O2S
    6-sec-Butoxy-2-(2-methoxy-phenylsulfanyl)-pyrimidin-4-ylamine
    —— 2-(2-Amino-phenylsulfanyl)-6-sec-butoxy-pyrimidin-4-ylamine 284681-55-6 C14H18N4OS
    2-(2-Amino-phenylsulfanyl)-6-sec-butoxy-pyrimidin-4-ylamine
    —— 2-sec-Butoxy-6-chloro-4-aminopyrimidine 284681-71-6 C15H18N2O2S
    2-sec-Butoxy-6-chloro-4-aminopyrimidine
    —— 2-sec-Butoxy-6-(3,5-dimethyl-phenylsulfanyl)-pyrimidin-4-ylamine 284681-84-1 C16H21N3OS
    2-sec-Butoxy-6-(3,5-dimethyl-phenylsulfanyl)-pyrimidin-4-ylamine
    —— 4-Pyrimidinamine, 2-((3,5-dimethylphenyl)thio)-6-(1-methylpropoxy)- 284681-59-0 C16H21N3OS
    4-Pyrimidinamine, 2-((3,5-dimethylphenyl)thio)-6-(1-methylpropoxy)-
    —— 4-Pyrimidinamine, 2-((2-chlorophenyl)thio)-6-(1-methylpropoxy)- 284681-48-7 C14H16ClN3OS
    4-Pyrimidinamine, 2-((2-chlorophenyl)thio)-6-(1-methylpropoxy)-
    —— 2-(4-Amino-phenylsulfanyl)-6-sec-butoxy-pyrimidin-4-ylamine 284681-57-8 C14H18N4OS
    2-(4-Amino-phenylsulfanyl)-6-sec-butoxy-pyrimidin-4-ylamine
    —— 2-(3-Amino-phenylsulfanyl)-6-sec-butoxy-pyrimidin-4-ylamine 284681-56-7 C14H18N4OS
    2-(3-Amino-phenylsulfanyl)-6-sec-butoxy-pyrimidin-4-ylamine
    —— 4-(Benzylsulfanyl)pyridine-2-carbonitrile 225112-43-6 C13H10N2S
    4-(Benzylsulfanyl)pyridine-2-carbonitrile
    —— methyl 4-(methylsulfanyl)butyl sulfoxide 67463-86-9 C6H14OS2
    methyl 4-(methylsulfanyl)butyl sulfoxide
    —— 4-(4-Chloro-benzylsulfanyl)-pyridine-2-carbonitrile 225112-49-2 C13H9ClN2S
    4-(4-Chloro-benzylsulfanyl)-pyridine-2-carbonitrile
    —— 4-phenylsulfanyl-benzo[4,5]furo[3,2-<i>d</i>]pyrimidine 65023-97-4 C16H10N2OS
    4-phenylsulfanyl-benzo[4,5]furo[3,2-<i>d</i>]pyrimidine
    —— 4-amino-2-benzylthio-5-cyano-6-methylthiopyrimidine 647832-49-3 C13H12N4S2
    4-amino-2-benzylthio-5-cyano-6-methylthiopyrimidine
    —— Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-butylamide 1187397-90-5 C11H18N4OS
    Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-butylamide
    —— (3<i>E</i>,5<i>E</i>,7<i>Z</i>)-7-methylsulfanyl-trideca-1,3,5,7-tetraene-9,11-diyne 51042-84-3 C14H14S
    (3<i>E</i>,5<i>E</i>,7<i>Z</i>)-7-methylsulfanyl-trideca-1,3,5,7-tetraene-9,11-diyne
    —— Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-benzylamide 1187397-93-8 C14H16N4OS
    Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-benzylamide
    —— Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-cyclohexylamide 1187397-92-7 C13H20N4OS
    Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-cyclohexylamide
    —— Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-isopentylamide 1187397-91-6 C12H20N4OS
    Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-isopentylamide
    —— Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-(2-phenylethyl)amide 1187397-94-9 C15H18N4OS
    Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-(2-phenylethyl)amide
    —— Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-propylamide 1187397-89-2 C10H16N4OS
    Z-3-(3-ethylthio-1,2,4-triazol-5-yl)propenoic acid N-propylamide
    —— 4-(2-Chloro-6-fluoro-benzylsulfanyl)-pyridine-2-carbonitrile 225112-77-6 C13H8ClFN2S
    4-(2-Chloro-6-fluoro-benzylsulfanyl)-pyridine-2-carbonitrile
    —— ((1E,3E)-4-tert-Butylsulfanyl-buta-1,3-dienyl)-cyclohexane 95061-56-6 C14H24S
    ((1E,3E)-4-tert-Butylsulfanyl-buta-1,3-dienyl)-cyclohexane
    —— ethyl (Z)-3-ethoxy-3-((2-(methylthio)phenyl)imino)propanoate 872496-83-8 C14H19NO3S
    ethyl (Z)-3-ethoxy-3-((2-(methylthio)phenyl)imino)propanoate
    —— 1-(3-ethyl-2-p-toluylsulfanyl-pyridin-4-yl)-ethylamine 1110734-87-6 C16H20N2S
    1-(3-ethyl-2-p-toluylsulfanyl-pyridin-4-yl)-ethylamine
    —— 2-Propen-1-one, 1-(5-((4-fluorophenyl)thio)-2-furanyl)-3-hydroxy-3-(1H-1,2,4-triazol-3-yl)- 280571-60-0 C15H10FN3O3S
    2-Propen-1-one, 1-(5-((4-fluorophenyl)thio)-2-furanyl)-3-hydroxy-3-(1H-1,2,4-triazol-3-yl)-
    —— (Z)-t-butyl 1-propenyl sulfide 61865-96-1 C7H14S
    (Z)-t-butyl 1-propenyl sulfide
    —— 2-Amino-6-(2-chloro-phenylsulfanyl)-benzonitrile 168910-78-9 C13H9ClN2S
    2-Amino-6-(2-chloro-phenylsulfanyl)-benzonitrile
    —— bis-(1-ethyl-propyl)-disulfide 99868-42-5 C10H22S2
    bis-(1-ethyl-propyl)-disulfide
    —— 2,3-dihydrobenzo[b]thiophene-5-carboxaldehyde 55745-98-7 C9H8OS
    2,3-dihydrobenzo[b]thiophene-5-carboxaldehyde
    —— 1-(thiophen-2-ylsulfanyl)-dodecan-2-one 877221-88-0 C16H26OS2
    1-(thiophen-2-ylsulfanyl)-dodecan-2-one
    —— 1-(4-methylthiophenyl)-2-butanone oxime 1204749-69-8 C11H15NOS
    1-(4-methylthiophenyl)-2-butanone oxime
    —— N-[2-[6-methyl-5-(2-pyridin-4-ylethyl)thieno[2,3-c]pyrrol-4-yl]sulfanylethyl]acetamide 1431866-18-0 C18H21N3OS2
    N-[2-[6-methyl-5-(2-pyridin-4-ylethyl)thieno[2,3-c]pyrrol-4-yl]sulfanylethyl]acetamide
    —— 1-Methyl-sulfinyl-2-hydroxy-undecan 22204-26-8 C12H26O2S
    1-Methyl-sulfinyl-2-hydroxy-undecan
    —— 4-Amino-6-chloro-2-(1-(4-(1-methylethyl)-2-pyridyl)ethyl)thio-pyrimidine 185219-29-8 C14H17ClN4S
    4-Amino-6-chloro-2-(1-(4-(1-methylethyl)-2-pyridyl)ethyl)thio-pyrimidine
    —— 3,5-Bis(methylthio)-4-phenyl-1lambda(4),2-dithiole 18260-42-9 C11H11S4+
    3,5-Bis(methylthio)-4-phenyl-1lambda(4),2-dithiole
    —— 4-Amino-6-chloro-2-(1-(4-(1-methylethenyl)-pyridin-2-yl)ethyl)thio-pyrimidine 185219-28-7 C14H15ClN4S
    4-Amino-6-chloro-2-(1-(4-(1-methylethenyl)-pyridin-2-yl)ethyl)thio-pyrimidine
    —— 1,2-Dimethylethylenepisulfoxid 10306-89-5 C4H8OS
    1,2-Dimethylethylenepisulfoxid
    —— 2,4-diamino-6-[2-(diisopropylphosphonylmethoxy)ethylsulfanyl]pyrimidine 429676-32-4 C13H25N4O4PS
    2,4-diamino-6-[2-(diisopropylphosphonylmethoxy)ethylsulfanyl]pyrimidine
    —— S(CH2CH2NHPiPr2)2 1360139-95-2 C16H38N2P2S
    S(CH2CH2NHPiPr2)2
    —— (4,4-Dipropyl-cyclobut-1-enylsulfanyl)-benzene 63048-80-6 C16H22S
    (4,4-Dipropyl-cyclobut-1-enylsulfanyl)-benzene
    —— 3-Phenylthio-4-n-propyl-hepta-1,3-dien 63049-22-9 C16H22S
    3-Phenylthio-4-n-propyl-hepta-1,3-dien
    —— 2,5-dibenzylthiopyrazine 1-oxide 136743-06-1 C18H16N2OS2
    2,5-dibenzylthiopyrazine 1-oxide
    —— Bis(4-(diphenylsulfonio)phenyl)sulfide bis(hexafluorophosphate) 74227-35-3 C36H28F12P2S3
    Bis(4-(diphenylsulfonio)phenyl)sulfide bis(hexafluorophosphate)