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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2H-Pyridazino(3,4-e)thiazin-7(6H)-one, 3-methyl- 82608-24-0 C7H7N3OS
    2H-Pyridazino(3,4-e)thiazin-7(6H)-one, 3-methyl-
    —— 5-hydroxymethyl-6-diethoxymethyl-1,3-dithiolo[4,5-b]1,4-dithiine-2-thione 338461-43-1 C11H14O3S5
    5-hydroxymethyl-6-diethoxymethyl-1,3-dithiolo[4,5-b]1,4-dithiine-2-thione
    —— 4-Diethoxymethyl-2-hexylsulfanyl-pyrimidine 863672-54-2 C15H26N2O2S
    4-Diethoxymethyl-2-hexylsulfanyl-pyrimidine
    —— 1,1,2,5,6,6-hexakis(phenylthio)-1,5-diene-3-yne 585527-20-4 C42H30S6
    1,1,2,5,6,6-hexakis(phenylthio)-1,5-diene-3-yne
    —— 3,3,4-trimethyl-4-<<(phenylthio)carbonyloxy>methyl>-1,2-dioxetane 109123-70-8 C13H16O4S
    3,3,4-trimethyl-4-<<(phenylthio)carbonyloxy>methyl>-1,2-dioxetane
    —— N,N-Dimethyl-11H-dibenzo(b,e)(1,4)dithiepin-11-ethanamine oxalate 81890-71-3 C19H21NO4S2
    N,N-Dimethyl-11H-dibenzo(b,e)(1,4)dithiepin-11-ethanamine oxalate
    —— [2-(1,3-benzodithiol-2-ylidene)-1,3-dithiol-4-yl]methyl N-(3-triethoxysilylpropyl)carbamate 1323394-57-5 C21H29NO5S4Si
    [2-(1,3-benzodithiol-2-ylidene)-1,3-dithiol-4-yl]methyl N-(3-triethoxysilylpropyl)carbamate
    —— N2-[4-(3,4-dichlorophenyl)thiazol-2-yl]-N4,N4-diethyl-6-phenylsulfanyl-1,3,5-triazine-2,4-diamine 1366099-29-7 C22H20Cl2N6S2
    N2-[4-(3,4-dichlorophenyl)thiazol-2-yl]-N4,N4-diethyl-6-phenylsulfanyl-1,3,5-triazine-2,4-diamine
    —— 2-(3,3,4,4-tetrafluoro-4-heptafluoropropyloxy-butylsulfanyl)-ethylamine 1158091-30-5 C9H10F11NOS
    2-(3,3,4,4-tetrafluoro-4-heptafluoropropyloxy-butylsulfanyl)-ethylamine
    —— 2,7,7-trimethyl-6-(phenylthio)-3-aza-7-silaoct-3-ene 96787-42-7 C15H25NSSi
    2,7,7-trimethyl-6-(phenylthio)-3-aza-7-silaoct-3-ene
    —— 2-Dimethylamino-N-methyl-N-(4-phenylsulfanyl-phenyl)-acetamide 77711-40-1 C17H20N2OS
    2-Dimethylamino-N-methyl-N-(4-phenylsulfanyl-phenyl)-acetamide
    —— 5-Chloro-3-methylsulfenylpyridine 98627-01-1 C6H6ClNS
    5-Chloro-3-methylsulfenylpyridine
    —— 4-(4-Chloro-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid 1027893-52-2 C14H8ClNO2S2
    4-(4-Chloro-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid
    —— N-Methyl-N-(4-phenylsulfanyl-phenyl)-2-piperidin-1-yl-acetamide 77711-46-7 C20H24N2OS
    N-Methyl-N-(4-phenylsulfanyl-phenyl)-2-piperidin-1-yl-acetamide
    —— 2-Chlor-4'-hydroxy-diphenyl-sulfid 20200-92-4 C12H9ClOS
    2-Chlor-4'-hydroxy-diphenyl-sulfid
    —— p-(o-Aminophenylthio)phenol 23621-49-0 C12H11NOS
    p-(o-Aminophenylthio)phenol
    —— N,N-Dimethyl-2-(methylthio)thioacetamid 65131-19-3 C5H11NS2
    N,N-Dimethyl-2-(methylthio)thioacetamid
    —— 2-Chloro-N-methyl-N-(4-phenylsulfanyl-phenyl)-acetamide 77711-38-7 C15H14ClNOS
    2-Chloro-N-methyl-N-(4-phenylsulfanyl-phenyl)-acetamide
    —— N-Methyl-2-(4-methyl-piperazin-1-yl)-N-(4-phenylsulfanyl-phenyl)-acetamide 77711-50-3 C20H25N3OS
    N-Methyl-2-(4-methyl-piperazin-1-yl)-N-(4-phenylsulfanyl-phenyl)-acetamide
    —— N-Methyl-N-(4-phenylsulfanyl-phenyl)-2-pyrrolidin-1-yl-acetamide 77711-44-5 C19H22N2OS
    N-Methyl-N-(4-phenylsulfanyl-phenyl)-2-pyrrolidin-1-yl-acetamide
    —— 2-Diethylamino-N-methyl-N-(4-phenylsulfanyl-phenyl)-acetamide 77711-42-3 C19H24N2OS
    2-Diethylamino-N-methyl-N-(4-phenylsulfanyl-phenyl)-acetamide
    —— N-Methyl-2-morpholin-4-yl-N-(4-phenylsulfanyl-phenyl)-acetamide 77711-48-9 C19H22N2O2S
    N-Methyl-2-morpholin-4-yl-N-(4-phenylsulfanyl-phenyl)-acetamide
    —— 4-(4-Bromo-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid 1026974-42-4 C14H8BrNO2S2
    4-(4-Bromo-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 4-o-Tolylsulfanyl-thieno[2,3-c]pyridine-2-carboxylic acid 1026851-99-9 C15H11NO2S2
    4-o-Tolylsulfanyl-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 4-(4-Trifluoromethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid 1026260-04-7 C15H8F3NO2S2
    4-(4-Trifluoromethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 4-Phenylsulfanyl-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester 1026182-43-3 C15H11NO2S2
    4-Phenylsulfanyl-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester
    —— 4-(phenylthio)thieno[2,3-c]pyridine-2-carboxamide 251992-93-5 C14H10N2OS2
    4-(phenylthio)thieno[2,3-c]pyridine-2-carboxamide
    —— 2-[[[4-[(4-methylphenyl)thio]thieno[2,3-c]pyridin-2-ylmethylene]amino]oxy]acetic acid 251992-75-3 C17H14N2O3S2
    2-[[[4-[(4-methylphenyl)thio]thieno[2,3-c]pyridin-2-ylmethylene]amino]oxy]acetic acid
    —— phenyl 3,4,6-tri-O-(t-butyldimethylsilyl)-2-deoxy-1-thio-α-D-lyxo-pyranoside 125211-44-1 C30H58O4SSi3
    phenyl 3,4,6-tri-O-(t-butyldimethylsilyl)-2-deoxy-1-thio-α-D-lyxo-pyranoside
    —— 4-(4-Trifluoromethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester 1028291-59-9 C16H10F3NO2S2
    4-(4-Trifluoromethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester
    —— 5-Methoxy-3-methylsulfenylpyridine 98627-13-5 C7H9NOS
    5-Methoxy-3-methylsulfenylpyridine
    —— 4-(3,4-Dichloro-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid 1025959-65-2 C14H7Cl2NO2S2
    4-(3,4-Dichloro-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 4-(4-Methoxy-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid 1026928-32-4 C15H11NO3S2
    4-(4-Methoxy-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 4-(5-Methyl-[1,3,4]thiadiazol-2-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester 1026941-80-9 C12H9N3O2S3
    4-(5-Methyl-[1,3,4]thiadiazol-2-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester
    —— 4-(3,5-Dimethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester 1028256-17-8 C17H15NO2S2
    4-(3,5-Dimethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester
    —— 4-(3,4-Dimethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid 1026811-03-9 C16H13NO2S2
    4-(3,4-Dimethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 4-(2,4-Dimethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester 1027525-11-6 C17H15NO2S2
    4-(2,4-Dimethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester
    —— 4-(4-Chloro-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester 1026974-60-6 C15H10ClNO2S2
    4-(4-Chloro-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester
    —— 4-(3,5-Dimethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid 1025963-69-2 C16H13NO2S2
    4-(3,5-Dimethyl-phenylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 4-[(4-bromophenyl)thio]thieno[2,3-c]pyridine-2-carboxamide 251992-92-4 C14H9BrN2OS2
    4-[(4-bromophenyl)thio]thieno[2,3-c]pyridine-2-carboxamide
    —— 4-(2-Methyl-furan-3-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester 1026239-52-0 C14H11NO3S2
    4-(2-Methyl-furan-3-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester
    —— 4-(2-Methyl-furan-3-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid 1027193-53-8 C13H9NO3S2
    4-(2-Methyl-furan-3-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 4-(5-Methyl-[1,3,4]thiadiazol-2-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid 1028295-70-6 C11H7N3O2S3
    4-(5-Methyl-[1,3,4]thiadiazol-2-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 1-[4-[(4-methylphenyl)thio]thieno[2,3-c]pyridin-2-yl]ethanone 251992-80-0 C16H13NOS2
    1-[4-[(4-methylphenyl)thio]thieno[2,3-c]pyridin-2-yl]ethanone
    —— 4-Phenylsulfanyl-thieno[2,3-c]pyridine-2-carboxylic acid 1026226-44-7 C14H9NO2S2
    4-Phenylsulfanyl-thieno[2,3-c]pyridine-2-carboxylic acid
    —— 4-(Pyridin-2-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester 1026513-60-9 C14H10N2O2S2
    4-(Pyridin-2-ylsulfanyl)-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester
    —— methyl 4-[(4-bromophenyl)thio]thieno[2,3-c]pyridine-2-carboxylate 402582-08-5 C15H10BrNO2S2
    methyl 4-[(4-bromophenyl)thio]thieno[2,3-c]pyridine-2-carboxylate
    —— 4-o-Tolylsulfanyl-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester 1026955-80-5 C16H13NO2S2
    4-o-Tolylsulfanyl-thieno[2,3-c]pyridine-2-carboxylic acid methyl ester
    —— 3-Chloro-5-o-tolylsulfanyl-pyridine-4-carbaldehyde 1025981-67-2 C13H10ClNOS
    3-Chloro-5-o-tolylsulfanyl-pyridine-4-carbaldehyde
    —— dimethyl sulfoxide oxygen 393782-06-4 C2H6O2S
    dimethyl sulfoxide oxygen