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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Dimethyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylamino)propyl]azanium;chloride —— C17H21ClN4OS
    Dimethyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylamino)propyl]azanium;chloride
    —— Diethyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethyl]azanium;chloride —— C18H22ClN3O2S
    Diethyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethyl]azanium;chloride
    —— 2-(dibutylamino)ethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;hydron;chloride —— C22H30ClN3O2S
    2-(dibutylamino)ethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;hydron;chloride
    —— Dimethyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethyl]azanium;chloride —— C16H18ClN3O2S
    Dimethyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethyl]azanium;chloride
    —— Di(propan-2-yl)-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethyl]azanium;chloride —— C20H26ClN3O2S
    Di(propan-2-yl)-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethyl]azanium;chloride
    —— Dipropyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethyl]azanium;chloride —— C20H26ClN3O2S
    Dipropyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethyl]azanium;chloride
    —— 3-[4-chloro-2-(4-chlorophenyl)sulfanylphenyl]-N,N-dimethylpropan-1-amine;hydron;chloride —— C17H20Cl3NS
    3-[4-chloro-2-(4-chlorophenyl)sulfanylphenyl]-N,N-dimethylpropan-1-amine;hydron;chloride
    —— 7a-methyl-2-methylthio-5,6,7,7a-tetrahydro-10-trifluoromethylpyrrolo<1,2-c>-1,2,4-triazolo<1,5-a>-1,3,5-benzotriazepin-5(8H)-one 120930-01-0 C15H14F3N5OS
    7a-methyl-2-methylthio-5,6,7,7a-tetrahydro-10-trifluoromethylpyrrolo<1,2-c>-1,2,4-triazolo<1,5-a>-1,3,5-benzotriazepin-5(8H)-one
    —— S-(3-pyrrolidin-1-ium-1-ylpropyl) pyrido[3,2-b][1,4]benzothiazine-10-carbothioate;chloride —— C19H22ClN3OS2
    S-(3-pyrrolidin-1-ium-1-ylpropyl) pyrido[3,2-b][1,4]benzothiazine-10-carbothioate;chloride
    —— (1-Ethylpiperidin-1-ium-4-yl) pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C19H22ClN3O2S
    (1-Ethylpiperidin-1-ium-4-yl) pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— Dipropyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)propyl]azanium;chloride —— C21H28ClN3OS2
    Dipropyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)propyl]azanium;chloride
    —— Dimethyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride —— C17H20ClN3O2S
    Dimethyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride
    —— N-ethyl-N-(4-methylpiperazin-1-yl)pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;hydron;chloride —— C19H24ClN5OS
    N-ethyl-N-(4-methylpiperazin-1-yl)pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;hydron;chloride
    —— 4-chloro-2-(4-chlorophenyl)sulfanyl-N-(3-piperidin-1-ylpropyl)aniline;hydron;chloride —— C20H25Cl3N2S
    4-chloro-2-(4-chlorophenyl)sulfanyl-N-(3-piperidin-1-ylpropyl)aniline;hydron;chloride
    —— hydron;3-(2-methylpiperidin-1-yl)propyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C21H26ClN3O2S
    hydron;3-(2-methylpiperidin-1-yl)propyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— hydron;(1-methylpiperidin-4-yl) pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C18H20ClN3O2S
    hydron;(1-methylpiperidin-4-yl) pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— N-(3-morpholin-4-ium-4-ylpropyl)pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;chloride —— C19H23ClN4O2S
    N-(3-morpholin-4-ium-4-ylpropyl)pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;chloride
    —— (3R,3aS,6aR)-3-(hydroxymethyl)-6a-(phenylthio)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one 909911-36-0 C14H14O3S
    (3R,3aS,6aR)-3-(hydroxymethyl)-6a-(phenylthio)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one
    —— hydron;2-(3-piperidin-1-ylpropoxy)ethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C22H28ClN3O3S
    hydron;2-(3-piperidin-1-ylpropoxy)ethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— hydron;(1-methylpiperidin-3-yl) pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C18H20ClN3O2S
    hydron;(1-methylpiperidin-3-yl) pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— Diethyl-[2-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethylsulfanyl]ethyl]azanium;chloride —— C20H26ClN3O2S2
    Diethyl-[2-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethylsulfanyl]ethyl]azanium;chloride
    —— tert-butyl (1R,2S)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylthio)cyclopent-3-ene-1-carboxylate 909911-35-9 C24H32O4S
    tert-butyl (1R,2S)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylthio)cyclopent-3-ene-1-carboxylate
    —— N-[3-(diethylamino)propyl]pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;hydron;chloride —— C19H25ClN4OS
    N-[3-(diethylamino)propyl]pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;hydron;chloride
    —— hydron;N-(2-piperazin-1-ylethyl)pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;chloride —— C18H22ClN5OS
    hydron;N-(2-piperazin-1-ylethyl)pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;chloride
    —— Bis(prop-2-enyl)-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride —— C21H24ClN3O2S
    Bis(prop-2-enyl)-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride
    —— hydron;N-(4-methylpiperazin-1-yl)pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;chloride —— C17H20ClN5OS
    hydron;N-(4-methylpiperazin-1-yl)pyrido[3,2-b][1,4]benzothiazine-10-carboxamide;chloride
    —— hydron;2-piperidin-1-ylethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C19H22ClN3O2S
    hydron;2-piperidin-1-ylethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— hydron;2-pyrrolidin-1-ylethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C18H20ClN3O2S
    hydron;2-pyrrolidin-1-ylethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— 10H-Pyrido(3,2-b)(1,4)benzothiazine-10-carbothioic acid, S-((2-diethylamino-1-methyl)ethyl) ester, hydrochloride 63906-27-4 C19H24ClN3OS2
    10H-Pyrido(3,2-b)(1,4)benzothiazine-10-carbothioic acid, S-((2-diethylamino-1-methyl)ethyl) ester, hydrochloride
    —— N-Methyl-4-(2-(phenylthio)ethyl)-pyridine methobromide 63906-19-4 C14H16BrNS
    N-Methyl-4-(2-(phenylthio)ethyl)-pyridine methobromide
    —— Dipropyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride —— C21H28ClN3O2S
    Dipropyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride
    —— 3-Piperidin-1-ium-1-ylpropyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C20H24ClN3O2S
    3-Piperidin-1-ium-1-ylpropyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— (E)-1-ethoxy-2-(methylthio)ethylene 53715-46-1 C5H10OS
    (E)-1-ethoxy-2-(methylthio)ethylene
    —— 2-Morpholin-4-ium-4-ylethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C18H20ClN3O3S
    2-Morpholin-4-ium-4-ylethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— 3-Pyrrolidin-1-ium-1-ylpropyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride —— C19H22ClN3O2S
    3-Pyrrolidin-1-ium-1-ylpropyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;chloride
    —— 5-bromo-4-(3-bromo-phenylsulfanyl)-thiophene-2-carbonitrile 911030-38-1 C11H5Br2NS2
    5-bromo-4-(3-bromo-phenylsulfanyl)-thiophene-2-carbonitrile
    —— 5-amino-4-(3-bromo-phenylsulfanyl)-thiophene-2-carbonitrile 911030-37-0 C11H7BrN2S2
    5-amino-4-(3-bromo-phenylsulfanyl)-thiophene-2-carbonitrile
    —— Dipropyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)ethyl]azanium;chloride —— C20H26ClN3OS2
    Dipropyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)ethyl]azanium;chloride
    —— (7aR)-7a-methyl-4-phenylsulfanyl-2,3,7,7a-tetrahydro-6H-indene-1,5-dione 244241-69-8 C16H16O2S
    (7aR)-7a-methyl-4-phenylsulfanyl-2,3,7,7a-tetrahydro-6H-indene-1,5-dione
    —— 4-(3-bromo-phenylsulfanyl)-5-nitro-thiophene-2-carbonitrile 631911-76-7 C11H5BrN2O2S2
    4-(3-bromo-phenylsulfanyl)-5-nitro-thiophene-2-carbonitrile
    —— Dibutyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)ethyl]azanium;chloride —— C22H30ClN3OS2
    Dibutyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)ethyl]azanium;chloride
    —— 3-[di(propan-2-yl)amino]propyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;hydron;chloride —— C21H28ClN3O2S
    3-[di(propan-2-yl)amino]propyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;hydron;chloride
    —— Diethyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)ethyl]azanium;chloride —— C18H22ClN3OS2
    Diethyl-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)ethyl]azanium;chloride
    —— S-tert-butyl (2R)-[(1R,2R)-3-oxo-2-(3-oxo-4-phenylthiobutyl)cyclopentyl]-4-[(4S)-2,2,5,5-tetramethyl-1,3-dioxolan-4-yl]butanethioate 203392-58-9 C31H46O5S2
    S-tert-butyl (2R)-[(1R,2R)-3-oxo-2-(3-oxo-4-phenylthiobutyl)cyclopentyl]-4-[(4S)-2,2,5,5-tetramethyl-1,3-dioxolan-4-yl]butanethioate
    —— (S)-2-((1S,7aS)-7a-Methyl-5-oxo-4-phenylsulfanyl-2,3,5,6,7,7a-hexahydro-1H-inden-1-yl)-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-thiopropionic acid S-tert-butyl ester 332950-57-9 C30H42O4S2
    (S)-2-((1S,7aS)-7a-Methyl-5-oxo-4-phenylsulfanyl-2,3,5,6,7,7a-hexahydro-1H-inden-1-yl)-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-thiopropionic acid S-tert-butyl ester
    —— (Z)-2-methoxy-1-(phenylthio)-1,3-butadiene 60466-66-2 C11H12OS
    (Z)-2-methoxy-1-(phenylthio)-1,3-butadiene
    —— Di(propan-2-yl)-[2-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethoxy]ethyl]azanium;chloride —— C22H30ClN3O3S
    Di(propan-2-yl)-[2-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)ethoxy]ethyl]azanium;chloride
    —— Di(propan-2-yl)-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)ethyl]azanium;chloride —— C20H26ClN3OS2
    Di(propan-2-yl)-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonylsulfanyl)ethyl]azanium;chloride
    —— 2-(Phenylthio)-1,3-dioxane 118418-20-5 C10H12O2S
    2-(Phenylthio)-1,3-dioxane
    —— S-[3-(dimethylamino)propyl] pyrido[3,2-b][1,4]benzothiazine-10-carbothioate;hydron;chloride —— C17H20ClN3OS2
    S-[3-(dimethylamino)propyl] pyrido[3,2-b][1,4]benzothiazine-10-carbothioate;hydron;chloride