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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-methyl-3-(phenylthio)-9-oxobicyclo<3.3.1>non-2-ene 90838-33-8 C16H18OS
    1-methyl-3-(phenylthio)-9-oxobicyclo<3.3.1>non-2-ene
    —— 8-bromo-1-octanethiol 202824-07-5 C8H17BrS
    8-bromo-1-octanethiol
    —— 3-(2-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-10-2 C27H31N2S*I
    3-(2-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 4-(6-methoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1-oxide 56032-46-3 C10H14N4O4S2
    4-(6-methoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1-oxide
    —— 4-(6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 56032-43-0 C11H16N4O3S2
    4-(6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine
    —— 7H-6-(p-Chlorphenyl)-s-triazolo<3,4-b><1,3,4>thiadiazin 62467-76-9 C10H7ClN4S
    7H-6-(p-Chlorphenyl)-s-triazolo<3,4-b><1,3,4>thiadiazin
    —— bis(2-methyl-1-cyclohexene) sulfide 82998-29-6 C14H22S
    bis(2-methyl-1-cyclohexene) sulfide
    —— 1,1-dioxo-3-piperidino-1λ<sup>6</sup>-[1,2,4]triazolo[4,3-b][1,4,2,6]dithiadiazine 1121614-75-2 C8H11N5O2S2
    1,1-dioxo-3-piperidino-1λ<sup>6</sup>-[1,2,4]triazolo[4,3-b][1,4,2,6]dithiadiazine
    —— (2S)-1-ethoxy-2-isothiocyanato-propane 1380094-36-9 C6H11NOS
    (2S)-1-ethoxy-2-isothiocyanato-propane
    —— 2-Ethylthio-5-methylthiothiophen 61809-22-1 C7H10S3
    2-Ethylthio-5-methylthiothiophen
    —— 4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1-oxide 56032-58-7 C13H20N4O4S2
    4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1-oxide
    —— (R)-4-[(phenylthio)methyl]-2-spirocyclohexyl-1,3-dioxolane 675956-62-4 C15H20O2S
    (R)-4-[(phenylthio)methyl]-2-spirocyclohexyl-1,3-dioxolane
    —— N-hydroxythiosemicarbazide 54393-56-5 CH5N3OS
    N-hydroxythiosemicarbazide
    —— 2,2'-Thiobis-<4,6-di-tert.-butylresorcinol> 35455-62-0 C28H42O4S
    2,2'-Thiobis-<4,6-di-tert.-butylresorcinol>
    —— 2-(Diethylamino)ethyl ((4-methylphenyl)thio)acetate hydrochloride 35859-34-8 C15H24ClNO2S
    2-(Diethylamino)ethyl ((4-methylphenyl)thio)acetate hydrochloride
    —— <i>N</i>-cyclohexyl-<i>N'</i>-(3-diethylamino-propyl)-thiourea 106476-26-0 C14H29N3S
    <i>N</i>-cyclohexyl-<i>N'</i>-(3-diethylamino-propyl)-thiourea
    —— 2-(1-Piperidinyl)ethyl (phenylthio)acetate hydrochloride 35859-24-6 C15H22ClNO2S
    2-(1-Piperidinyl)ethyl (phenylthio)acetate hydrochloride
    —— N-(2-(Dimethylamino)ethyl)-2-(phenylthio)acetamide monohydrochloride 35859-28-0 C12H19ClN2OS
    N-(2-(Dimethylamino)ethyl)-2-(phenylthio)acetamide monohydrochloride
    —— 4-allylsulfanyl-imidazo[1,5-<i>d</i>][1,2,4]triazine 69195-42-2 C8H8N4S
    4-allylsulfanyl-imidazo[1,5-<i>d</i>][1,2,4]triazine
    —— Carbamic acid 1,4-dithia-spiro[4.6]undec-2-ylmethyl ester 35801-65-1 C11H19NO2S2
    Carbamic acid 1,4-dithia-spiro[4.6]undec-2-ylmethyl ester
    —— 4,5-(2-methylene-1,2-ethanediyldithio)-1,3-dithiole-2-thione 111016-04-7 C6H4S5
    4,5-(2-methylene-1,2-ethanediyldithio)-1,3-dithiole-2-thione
    —— Carbamic acid 1,4-dithia-spiro[4.11]hexadec-2-ylmethyl ester 35801-66-2 C16H29NO2S2
    Carbamic acid 1,4-dithia-spiro[4.11]hexadec-2-ylmethyl ester
    —— 2-(Diethylamino)ethyl (phenylthio)acetate hydrochloride 35859-20-2 C14H22ClNO2S
    2-(Diethylamino)ethyl (phenylthio)acetate hydrochloride
    —— 4-Cyclohexylsulfonyl-butylbromid 5755-84-0 C10H19BrO2S
    4-Cyclohexylsulfonyl-butylbromid
    —— 2-(4-Morpholinyl)ethyl (phenylthio)acetate hydrochloride 35859-26-8 C14H20ClNO3S
    2-(4-Morpholinyl)ethyl (phenylthio)acetate hydrochloride
    —— 6-Cyano-5-oxothiazolidino<3,2-a>pyrimidin 32084-54-1 C7H5N3OS
    6-Cyano-5-oxothiazolidino<3,2-a>pyrimidin
    —— (2-Aminoaethyl)-octyl-disulfid 105532-69-2 C10H23NS2
    (2-Aminoaethyl)-octyl-disulfid
    —— 4-methoxy-6-[(4'-methylthio-phenyl)-thio]-phenylacetonitrile 54413-88-6 C16H15NOS2
    4-methoxy-6-[(4'-methylthio-phenyl)-thio]-phenylacetonitrile
    —— 4-methoxy-6-{[4'-(methylthio)-phenyl]-thio}-benzyl chloride 54413-87-5 C15H15ClOS2
    4-methoxy-6-{[4'-(methylthio)-phenyl]-thio}-benzyl chloride
    —— (2-Aminoaethyl)-butyl-disulfid 95056-38-5 C6H15NS2
    (2-Aminoaethyl)-butyl-disulfid
    —— 4-methoxy-6-[(4'-methylthio-phenyl)-thio]-phenylacetic acid 54413-89-7 C16H16O3S2
    4-methoxy-6-[(4'-methylthio-phenyl)-thio]-phenylacetic acid
    —— 3-Cyclohexylsulfonyl-propylbromid 5755-73-7 C9H17BrO2S
    3-Cyclohexylsulfonyl-propylbromid
    —— 2-p-Tolyl-6,7-dihydro-thiazolo[3,2-a][1,3,5]triazin-4-one 82256-17-5 C12H11N3OS
    2-p-Tolyl-6,7-dihydro-thiazolo[3,2-a][1,3,5]triazin-4-one
    —— 6-(2-hydroxy-ethyl)-5-methyl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-7-one 53750-92-8 C9H12N2O2S
    6-(2-hydroxy-ethyl)-5-methyl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-7-one
    —— N-(2-Mercaptoaethyl)-thioharnstoff 15267-06-8 C3H8N2S2
    N-(2-Mercaptoaethyl)-thioharnstoff
    —— 2-(Cyclopropyl)-2-thiazolin 55089-25-3 C6H9NS
    2-(Cyclopropyl)-2-thiazolin
    —— 2-(dimethylamino)ethyl 2-phenylsulfanylacetate;hydron;chloride —— C12H18ClNO2S
    2-(dimethylamino)ethyl 2-phenylsulfanylacetate;hydron;chloride
    —— 1-bromo-4-[1,2,2,2-tetradeuterio-1-(trideuteriomethyl)ethyl]sulfanyl-benzene 1428935-50-5 C9H11BrS
    1-bromo-4-[1,2,2,2-tetradeuterio-1-(trideuteriomethyl)ethyl]sulfanyl-benzene
    —— 2-(4-Morpholinyl)ethyl ((4-methylphenyl)thio)acetate hydrochloride 35859-40-6 C15H22ClNO3S
    2-(4-Morpholinyl)ethyl ((4-methylphenyl)thio)acetate hydrochloride
    —— Carbamic acid 2,2-dimethyl-[1,3]dithiolan-4-ylmethyl ester 35801-62-8 C7H13NO2S2
    Carbamic acid 2,2-dimethyl-[1,3]dithiolan-4-ylmethyl ester
    —— 2-(Dimethylamino)ethyl ((4-methylphenyl)thio)acetate hydrochloride 35859-32-6 C13H20ClNO2S
    2-(Dimethylamino)ethyl ((4-methylphenyl)thio)acetate hydrochloride
    —— hydron;2-piperidin-1-ylethyl 2-(4-methylphenyl)sulfanylacetate;chloride —— C16H24ClNO2S
    hydron;2-piperidin-1-ylethyl 2-(4-methylphenyl)sulfanylacetate;chloride
    —— 2-carbamoyloxymethyl-1,4-dithia-spiro[4.5]decane 35877-41-9 C10H17NO2S2
    2-carbamoyloxymethyl-1,4-dithia-spiro[4.5]decane
    —— 1-(phenylsulfonyl)-3-(phenylthio)-1H-indole-2-carbaldehyde 643001-32-5 C21H15NO3S2
    1-(phenylsulfonyl)-3-(phenylthio)-1H-indole-2-carbaldehyde
    —— Dimethyl-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine 85678-47-3 C17H18N2S
    Dimethyl-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine
    —— 2-(β-hydroxyethylthio)-5-aminophenol 146310-38-5 C8H11NO2S
    2-(β-hydroxyethylthio)-5-aminophenol
    —— 2-(4-Morpholinyl)ethyl ((4-chlorophenyl)thio)acetate hydrochloride 35859-48-4 C14H19Cl2NO3S
    2-(4-Morpholinyl)ethyl ((4-chlorophenyl)thio)acetate hydrochloride
    —— (Z)-4-ethyl-5-(phenylthio)-1,4-nonadiene 217803-24-2 C17H24S
    (Z)-4-ethyl-5-(phenylthio)-1,4-nonadiene
    —— phenyl tris(trimethylsilyl)tetrahedranyl sulfide 1313728-12-9 C19H32SSi3
    phenyl tris(trimethylsilyl)tetrahedranyl sulfide
    —— dicyclopropyl sulfide 45468-25-5 C6H10S
    dicyclopropyl sulfide