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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-2-Methyl-3-phenylsulfanyl-prop-2-en-1-ol 401893-43-4 C10H12OS
    (E)-2-Methyl-3-phenylsulfanyl-prop-2-en-1-ol
    —— N-[4,4-bis(phenylsulfanyl)but-1-yl]-N-[1(R)-phenylethyl]amine 920512-69-2 C24H27NS2
    N-[4,4-bis(phenylsulfanyl)but-1-yl]-N-[1(R)-phenylethyl]amine
    —— 5-ethylthio-5-methyl-4-(pyrrolidin-1-yl)furan-2(5H)-one 134294-95-4 C11H17NO2S
    5-ethylthio-5-methyl-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 5-ethylthio-5-(1-hydroxyprop-1-yl)-4-(pyrrolidin-1-yl)furan-2(5H)-one 134295-08-2 C13H21NO3S
    5-ethylthio-5-(1-hydroxyprop-1-yl)-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— N-[4,4-bis(phenylsulfanyl)but-1-yl]-N-[1(S)-phenylethyl]amine 920512-70-5 C24H27NS2
    N-[4,4-bis(phenylsulfanyl)but-1-yl]-N-[1(S)-phenylethyl]amine
    —— 5-benzyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one 134294-99-8 C17H21NO2S
    5-benzyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 5-acetyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one 134295-16-2 C12H17NO3S
    5-acetyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 2-<Chlorfluor(trifluormethylthio)methylthio>pyrrol 62665-32-1 C6H4ClF4NS2
    2-<Chlorfluor(trifluormethylthio)methylthio>pyrrol
    —— 5-phenylthiothiophene-2-carboxylic acid 79504-97-5 C11H8O2S2
    5-phenylthiothiophene-2-carboxylic acid
    —— methyl ethylsulfonylacetate 42271-27-2 C5H10O4S
    methyl ethylsulfonylacetate
    —— (Z)-3-Fluoro-4-phenylsulfanyl-but-3-en-2-one 167965-53-9 C10H9FOS
    (Z)-3-Fluoro-4-phenylsulfanyl-but-3-en-2-one
    —— 2-(hexylthio)pyrimidine-4,5,6-triamine 1260177-43-2 C10H19N5S
    2-(hexylthio)pyrimidine-4,5,6-triamine
    —— 5-Nitroso-4,6-diamino-2-benzylmercapto-pyrimidin 52222-45-4 C11H11N5OS
    5-Nitroso-4,6-diamino-2-benzylmercapto-pyrimidin
    —— 2-Isopropylsulfonyl-ethylbromid 5755-75-9 C5H11BrO2S
    2-Isopropylsulfonyl-ethylbromid
    —— 2-n-Butylthio-5-nitroso-4,6-diaminopyrimidin 73000-29-0 C8H13N5OS
    2-n-Butylthio-5-nitroso-4,6-diaminopyrimidin
    —— 2-(isopropylsulfonyl)ethanol 98288-49-4 C5H12O3S
    2-(isopropylsulfonyl)ethanol
    —— 2-Isopropylmercapto-ethylbromid 5755-62-4 C5H11BrS
    2-Isopropylmercapto-ethylbromid
    —— 2,4-Bis-(2-methyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole 147089-57-4 C20H17NS4
    2,4-Bis-(2-methyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole
    —— 1-[4-(2-Methyl-benzo[1,3]dithiol-2-yl)-1H-pyrrol-2-yl]-ethanone 147089-46-1 C14H13NOS2
    1-[4-(2-Methyl-benzo[1,3]dithiol-2-yl)-1H-pyrrol-2-yl]-ethanone
    —— 4-Benzylsulfanyl-5-(4-methyl-oxazol-2-yl)-2-thiophen-2-yl-pyrimidine 212621-49-3 C19H15N3OS2
    4-Benzylsulfanyl-5-(4-methyl-oxazol-2-yl)-2-thiophen-2-yl-pyrimidine
    —— 5-(4-chlorophenyl)-3-(methylthio)isoxazole 120803-16-9 C10H8ClNOS
    5-(4-chlorophenyl)-3-(methylthio)isoxazole
    —— 2,2'-Dimesyloxy-N-methyldipropylamine picrylsulfonate 3545-54-8 C15H24N4O13S3
    2,2'-Dimesyloxy-N-methyldipropylamine picrylsulfonate
    —— 4-Benzylsulfanyl-5-(2H-tetrazol-5-yl)-2-thiophen-2-yl-pyrimidine 212621-45-9 C16H12N6S2
    4-Benzylsulfanyl-5-(2H-tetrazol-5-yl)-2-thiophen-2-yl-pyrimidine
    —— dimethyl-thiocarbamic acid S-(4-bromo-3,5-dimethyl-phenyl) ester 872254-86-9 C11H14BrNOS
    dimethyl-thiocarbamic acid S-(4-bromo-3,5-dimethyl-phenyl) ester
    —— 4-(benzylthio)-5-cyano-2-(2'-thienyl)pyrimidine 212621-35-7 C16H11N3S2
    4-(benzylthio)-5-cyano-2-(2'-thienyl)pyrimidine
    —— 4-Benzylsulfanyl-5-(4,5-dihydro-oxazol-2-yl)-2-thiophen-2-yl-pyrimidine 212621-55-1 C18H15N3OS2
    4-Benzylsulfanyl-5-(4,5-dihydro-oxazol-2-yl)-2-thiophen-2-yl-pyrimidine
    —— 5-ethylthio-5-(methoxycarbonylmethyl)-4-(pyrrolidin-1-yl)furan-2(5H)-one 134295-02-6 C13H19NO4S
    5-ethylthio-5-(methoxycarbonylmethyl)-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 2-ethoxycarbonylmethylsulfanyl-5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-1,3,4-oxadiazole 445467-17-4 C12H14N4O5S
    2-ethoxycarbonylmethylsulfanyl-5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-1,3,4-oxadiazole
    —— 2-methoxycarbonylmethylsulfanyl-5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-1,3,4-oxadiazole 445467-16-3 C11H12N4O5S
    2-methoxycarbonylmethylsulfanyl-5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-1,3,4-oxadiazole
    —— 2-amino-3,4-dimethylphenyl-3-nitro-4-pyridinylsulfide 239791-57-2 C13H13N3O2S
    2-amino-3,4-dimethylphenyl-3-nitro-4-pyridinylsulfide
    —— 2-(methylthio)phenylphosphonic N,N,N',N'-tetramethyldiamidate 133617-49-9 C11H19N2OPS
    2-(methylthio)phenylphosphonic N,N,N',N'-tetramethyldiamidate
    —— Morpholine, 4-(3-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)propyl)- 3562-89-8 C21H27ClN2OS
    Morpholine, 4-(3-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)propyl)-
    —— 2,2'-(Methylimino)diethanol bismethanesulfonate picrylsulfonate 3545-53-7 C13H20N4O13S3
    2,2'-(Methylimino)diethanol bismethanesulfonate picrylsulfonate
    —— Pseudourea, 2,2',2''-(nitrilotriethylene)tris(2-thio-, tetrahydrobromide 3810-31-9 C9H25Br4N7S3
    Pseudourea, 2,2',2''-(nitrilotriethylene)tris(2-thio-, tetrahydrobromide
    —— 2-[4,5-dimethoxy-1,3-dithiol-2-ylidene]-5-(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene 1313432-70-0 C12H8O2S8
    2-[4,5-dimethoxy-1,3-dithiol-2-ylidene]-5-(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene
    —— (3-Cyano-4-furan-2-yl-5,6-dimethyl-pyridin-2-ylsulfanyl)-acetic acid ethyl ester 94639-44-8 C16H16N2O3S
    (3-Cyano-4-furan-2-yl-5,6-dimethyl-pyridin-2-ylsulfanyl)-acetic acid ethyl ester
    —— 2-phenoxycarbonylamino-5-phenylsulphanyl-1H-indole-3-carbonitrile 378236-69-2 C22H15N3O2S
    2-phenoxycarbonylamino-5-phenylsulphanyl-1H-indole-3-carbonitrile
    —— Benzimidazole, 2-(p-cumenylthio)-1-(2-(diethylamino)ethyl)-, dipicrate 4929-62-8 C34H35N9O14S
    Benzimidazole, 2-(p-cumenylthio)-1-(2-(diethylamino)ethyl)-, dipicrate
    —— 1-phenylsulfonyl-2-(2,4-dimethoxybenzyl)-3-(phenylthio)-1H-indole 1150111-65-1 C29H25NO4S2
    1-phenylsulfonyl-2-(2,4-dimethoxybenzyl)-3-(phenylthio)-1H-indole
    —— Piperidine, 1-(3-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)propyl)- 3626-70-8 C22H29ClN2S
    Piperidine, 1-(3-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)propyl)-
    —— 1-phenylsulfonyl-2-(3,4-dimethoxybenzyl)-3-(phenylthio)-1H-indole 144465-23-6 C29H25NO4S2
    1-phenylsulfonyl-2-(3,4-dimethoxybenzyl)-3-(phenylthio)-1H-indole
    —— (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-(4-methoxy-phenyl)-amine 171618-49-8 C28H24N2O3S2
    (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-(4-methoxy-phenyl)-amine
    —— (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-p-tolyl-amine 171618-48-7 C28H24N2O2S2
    (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-p-tolyl-amine
    —— 2-(3-bromo-3-phenylallyl)-1-(phenylsulfonyl)-3-(phenylthio)-1H-indole 1372674-47-9 C29H22BrNO2S2
    2-(3-bromo-3-phenylallyl)-1-(phenylsulfonyl)-3-(phenylthio)-1H-indole
    —— 1-phenylsulfonyl-2-(3,4-dimethylbenzyl)-3-(phenylthio)-1H-indole 1150111-63-9 C29H25NO2S2
    1-phenylsulfonyl-2-(3,4-dimethylbenzyl)-3-(phenylthio)-1H-indole
    —— (3-Phenylsulfanyl-1H-indol-2-ylmethyl)-p-tolyl-amine 171618-51-2 C22H20N2S
    (3-Phenylsulfanyl-1H-indol-2-ylmethyl)-p-tolyl-amine
    —— 1-phenylsulfonyl-3-(phenylthio)-2-((thiophen-2-yl)methyl)-1H-indole 1150111-68-4 C25H19NO2S3
    1-phenylsulfonyl-3-(phenylthio)-2-((thiophen-2-yl)methyl)-1H-indole
    —— (4-Methoxy-phenyl)-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine 171618-52-3 C22H20N2OS
    (4-Methoxy-phenyl)-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine
    —— N-(3-Phenylsulfanyl-1H-indol-2-ylmethyl)-N-p-tolyl-acetamide 171618-55-6 C24H22N2OS
    N-(3-Phenylsulfanyl-1H-indol-2-ylmethyl)-N-p-tolyl-acetamide
    —— N-[(1-(phenylsulfonyl)-3-(phenylthio)-1H-indol-2-yl)methyl]acetamide 1227373-10-5 C23H20N2O3S2
    N-[(1-(phenylsulfonyl)-3-(phenylthio)-1H-indol-2-yl)methyl]acetamide