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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-benzyl-4-(4-(3-(4-chlorophenyl)thioureido)phenylthio)picolinamide 1395063-25-8 C26H21ClN4OS2
    N-benzyl-4-(4-(3-(4-chlorophenyl)thioureido)phenylthio)picolinamide
    —— N-(2-fluoro-ethyl)-4-methylsulfanyl-pyridine-2,6-diamine 1158785-98-8 C8H12FN3S
    N-(2-fluoro-ethyl)-4-methylsulfanyl-pyridine-2,6-diamine
    —— 2-Phenyl-1,3-dithiolane-2-carboxylic acid 23118-19-6 C10H10O2S2
    2-Phenyl-1,3-dithiolane-2-carboxylic acid
    —— 2-(trifluoromethanesulfonyl)-1,3-cyclohexadiene 235746-99-3 C7H7F3O2S
    2-(trifluoromethanesulfonyl)-1,3-cyclohexadiene
    —— 7-Amino-5-benzylthio-pyrimido<5,4-e>as-triazine 31736-48-8 C12H10N6S
    7-Amino-5-benzylthio-pyrimido<5,4-e>as-triazine
    —— 4-chlorophenyl-(1-fluoroundec-1-yl)thioether 1245924-30-4 C17H26ClFS
    4-chlorophenyl-(1-fluoroundec-1-yl)thioether
    —— 4-Benzylsulfanyl-5-bromo-6-furan-2-yl-pyrimidin-2-yl-amine 357286-71-6 C15H12BrN3OS
    4-Benzylsulfanyl-5-bromo-6-furan-2-yl-pyrimidin-2-yl-amine
    —— 5-Bromo-4-ethylsulfanyl-6-furan-2-yl-pyrimidin-2-yl-amine 357286-72-7 C10H10BrN3OS
    5-Bromo-4-ethylsulfanyl-6-furan-2-yl-pyrimidin-2-yl-amine
    —— 2-Amino-4-benzo[1,3]dioxol-5-yl-6-phenylsulfanyl-pyrimidine-5-carbonitrile 357285-48-4 C18H12N4O2S
    2-Amino-4-benzo[1,3]dioxol-5-yl-6-phenylsulfanyl-pyrimidine-5-carbonitrile
    —— 1,2-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]ethane 390799-91-4 C16H12N6S4
    1,2-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]ethane
    —— 3-(2-(2-fluoroethoxy)ethylthio)-4-(1-methyl-1,2,5,6-tetrahydropyridin-3-yl)-1,2,5-thiadiazole 1262964-25-9 C12H18FN3OS2
    3-(2-(2-fluoroethoxy)ethylthio)-4-(1-methyl-1,2,5,6-tetrahydropyridin-3-yl)-1,2,5-thiadiazole
    —— 3-(3-butylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-52-8 C12H16N3S2*I
    3-(3-butylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-methylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-53-9 C9H10N3S2*I
    3-(3-methylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-(ethylthio)-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate salt 141064-33-7 C2H2O4*C10H15N3S2
    3-(3-(ethylthio)-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate salt
    —— 3-(3-Octylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridineoxalate 141064-40-6 C2H2O4*C16H27N3S2
    3-(3-Octylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridineoxalate
    —— Tazomeline oxalate 141064-37-1 C2H2O4*C14H23N3S2
    Tazomeline oxalate
    —— 3-(3-propylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-51-7 C11H14N3S2*I
    3-(3-propylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-octylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-58-4 C16H24N3S2*I
    3-(3-octylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-Butylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridineoxalate 141064-35-9 C2H2O4*C12H19N3S2
    3-(3-Butylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridineoxalate
    —— 3-(3-ethylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-59-5 C10H12N3S2*I
    3-(3-ethylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-Propylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate 141064-34-8 C2H2O4*C11H17N3S2
    3-(3-Propylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate
    —— 3-(3-methylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate 141064-32-6 C2H2O4*C9H13N3S2
    3-(3-methylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate
    —— 3-[4-(3-Phenyl-propylsulfanyl)-[1,2,5]thiadiazol-3-yl]-pyridine 169542-77-2 C16H15N3S2
    3-[4-(3-Phenyl-propylsulfanyl)-[1,2,5]thiadiazol-3-yl]-pyridine
    —— 2-amino-6-methyl-5-[(5-chlorobenzimidazol-2-yl)sulfanyl]-3,4-dihydro-4-oxo-7H-pyrrolo[2,3-d]pyrimidine 1224513-98-7 C14H11ClN6OS
    2-amino-6-methyl-5-[(5-chlorobenzimidazol-2-yl)sulfanyl]-3,4-dihydro-4-oxo-7H-pyrrolo[2,3-d]pyrimidine
    —— 1,4-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]butane 390799-93-6 C18H16N6S4
    1,4-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]butane
    —— 1,3-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]propane 390799-92-5 C17H14N6S4
    1,3-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]propane
    —— 3-(3-methylthio-1,2,5-thiadiazol-4-yl)pyridine 131988-00-6 C8H7N3S2
    3-(3-methylthio-1,2,5-thiadiazol-4-yl)pyridine
    —— 3-(3-butylthio-1,2,5-thiadiazol-4-yl)pyridine 131987-99-0 C11H13N3S2
    3-(3-butylthio-1,2,5-thiadiazol-4-yl)pyridine
    —— 3-(3-octylthio-1,2,5-thiadiazol-4-yl)pyridine 131988-08-4 C15H21N3S2
    3-(3-octylthio-1,2,5-thiadiazol-4-yl)pyridine
    —— 3-(3-ethylthio-1,2,5-thiadiazol-4-yl)pyridine 131988-09-5 C9H9N3S2
    3-(3-ethylthio-1,2,5-thiadiazol-4-yl)pyridine
    —— 1,4-Bis-(N,N-dimethyl-thiocarbamoylmercapto)-2,3,5,6-tetramethyl-benzol 13512-07-7 C16H24N2O2S2
    1,4-Bis-(N,N-dimethyl-thiocarbamoylmercapto)-2,3,5,6-tetramethyl-benzol
    —— N-(2-Amino-ethyl)-N'-methyl-thioharnstoff 13528-11-5 C4H11N3S
    N-(2-Amino-ethyl)-N'-methyl-thioharnstoff
    —— Diethyl-thiocarbamic acid S-(4-diethylcarbamoylsulfanyl-phenyl) ester 13511-81-4 C16H24N2O2S2
    Diethyl-thiocarbamic acid S-(4-diethylcarbamoylsulfanyl-phenyl) ester
    —— (1,1-dimethyl-allyl)-methyl-thioketene 72807-41-1 C8H12S
    (1,1-dimethyl-allyl)-methyl-thioketene
    —— N,N-Dimethyl-thiocarbamidsaeure-O-(2-methylmercapto-pyrimidin-4-ylester) 13522-74-2 C8H11N3OS2
    N,N-Dimethyl-thiocarbamidsaeure-O-(2-methylmercapto-pyrimidin-4-ylester)
    —— 2-aminophenyl heptyl sulphide 111186-08-4 C13H21NS
    2-aminophenyl heptyl sulphide
    —— O-(3-methylbut-2-enyl) N,N-dimethylthiocarbamate 130893-43-5 C8H15NOS
    O-(3-methylbut-2-enyl) N,N-dimethylthiocarbamate
    —— n-heptyl mesylate 86602-40-6 C8H18O2S
    n-heptyl mesylate
    —— methyl 5-(3,4-dimethylphenylthio)-4-(N,N-dipentylcarbamoyl)pentanoate 136887-08-6 C25H41NO3S
    methyl 5-(3,4-dimethylphenylthio)-4-(N,N-dipentylcarbamoyl)pentanoate
    —— 2-phenylthio-3,5,6-trimethyl-4,7-benzofurandione 119048-35-0 C17H14O3S
    2-phenylthio-3,5,6-trimethyl-4,7-benzofurandione
    —— S-(1,1-dimethylallyl) N,N-dimethylthiocarbamate 130893-44-6 C8H15NOS
    S-(1,1-dimethylallyl) N,N-dimethylthiocarbamate
    —— n-heptyl methyl sulphoxide 24494-67-5 C8H18OS
    n-heptyl methyl sulphoxide
    —— 4,7-dimethoxy-2-phenylthio-3,5,6-trimethylbenzofuran 119048-18-9 C19H20O3S
    4,7-dimethoxy-2-phenylthio-3,5,6-trimethylbenzofuran
    —— cycloheptylmethylthiourea 117694-95-8 C9H18N2S
    cycloheptylmethylthiourea
    —— 2-(4,5-dihydro-1<i>H</i>-imidazol-2-yl)-benzo[<i>b</i>]thiophen-3-ol 57840-07-0 C11H10N2OS
    2-(4,5-dihydro-1<i>H</i>-imidazol-2-yl)-benzo[<i>b</i>]thiophen-3-ol
    —— thiourea hydrobromide 36666-93-0 BrH*CH4N2S
    thiourea hydrobromide
    —— 2-(2-(benzylthio)phenyl)ethanol 25866-40-4 C15H16OS
    2-(2-(benzylthio)phenyl)ethanol
    —— N-[2-(6-methyl-5-prop-2-ynylthieno[2,3-c]pyrrol-4-yl)sulfanylethyl]acetamide 1431866-13-5 C14H16N2OS2
    N-[2-(6-methyl-5-prop-2-ynylthieno[2,3-c]pyrrol-4-yl)sulfanylethyl]acetamide
    —— N-[2-[6-methyl-5-(2-phenylethyl)thieno[2,3-c]pyrrol-4-yl]sulfanylethyl]acetamide 1431866-17-9 C19H22N2OS2
    N-[2-[6-methyl-5-(2-phenylethyl)thieno[2,3-c]pyrrol-4-yl]sulfanylethyl]acetamide
    —— N-[2-(5-benzyl-6-methylthieno[2,3-c]pyrrol-4-yl)sulfanylethyl]acetamide 1431866-23-7 C18H20N2OS2
    N-[2-(5-benzyl-6-methylthieno[2,3-c]pyrrol-4-yl)sulfanylethyl]acetamide