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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-<1-(phenylthio)ethyl>-3-sulfolene 122236-26-4 C12H14O2S2
    3-<1-(phenylthio)ethyl>-3-sulfolene
    —— 1.4-Dibutylmercapto-buta-1.3-dien 92039-05-9 C12H22S2
    1.4-Dibutylmercapto-buta-1.3-dien
    —— 1.4-Dibutylsulfonyl-buta-1c.3c-dien 4858-99-5 C12H22O4S2
    1.4-Dibutylsulfonyl-buta-1c.3c-dien
    —— 1.4-Dibutylsulfonyl-buta-1c.3t-dien 5799-63-3 C12H22O4S2
    1.4-Dibutylsulfonyl-buta-1c.3t-dien
    —— 6-acetyl-8-chloro-3,4,5,6-tetrahydro-5-phenyl-2h-1,6-benzothiazocine 87697-14-1 C18H18ClNOS
    6-acetyl-8-chloro-3,4,5,6-tetrahydro-5-phenyl-2h-1,6-benzothiazocine
    —— 3-(1,1-bis(phenylthio)ethyl)cyclohexanone 89969-02-8 C20H22OS2
    3-(1,1-bis(phenylthio)ethyl)cyclohexanone
    —— ethyl 2-(p-chlorophenylthio)-2-fluoroacetate 129600-91-5 C10H10ClFO2S
    ethyl 2-(p-chlorophenylthio)-2-fluoroacetate
    —— 2-hydroxy-2-methyl-3-phenylsulfenyl-4-(cyclohex-2-enyliden)-3-butene 154227-37-9 C17H20OS
    2-hydroxy-2-methyl-3-phenylsulfenyl-4-(cyclohex-2-enyliden)-3-butene
    —— 5-benzyl-2-[(4-chlorobenzyl)sulfanyl]-6-hydroxypyrimidin-4(3H)-one 415939-62-7 C18H15ClN2O2S
    5-benzyl-2-[(4-chlorobenzyl)sulfanyl]-6-hydroxypyrimidin-4(3H)-one
    —— 1,1-Dideuterio-1-ethylsulfanylpropane 139097-66-8 C5H12S
    1,1-Dideuterio-1-ethylsulfanylpropane
    —— 2-hydroxy-2-methyl-3-phenylsulfenyl-3,4,6-heptatriene 154227-27-7 C14H16OS
    2-hydroxy-2-methyl-3-phenylsulfenyl-3,4,6-heptatriene
    —— 1-phenylthiopent-4-en-1-yne 154227-20-0 C11H10S
    1-phenylthiopent-4-en-1-yne
    —— 1-Cyclohexyl-4-{1-[4-(4-methoxy-phenylsulfanyl)-phenyl]-vinyl}-piperidine 221459-04-7 C26H33NOS
    1-Cyclohexyl-4-{1-[4-(4-methoxy-phenylsulfanyl)-phenyl]-vinyl}-piperidine
    —— pyridine-4-carboxaldehyde (4-methylthiophenyl)imine 165806-92-8 C13H12N2S
    pyridine-4-carboxaldehyde (4-methylthiophenyl)imine
    —— 3-cyclopentyl-2-(4-methanesulfanyl-phenyl)propionic acid methyl ester 300356-41-6 C16H22O2S
    3-cyclopentyl-2-(4-methanesulfanyl-phenyl)propionic acid methyl ester
    —— 3-(phenylthioethynyl)cyclohexene 154227-21-1 C14H14S
    3-(phenylthioethynyl)cyclohexene
    —— 4,6-dichloro-5-(cyclohex-2-en-1-yl)-2-(methylthio)pyrimidine 1233493-48-5 C11H12Cl2N2S
    4,6-dichloro-5-(cyclohex-2-en-1-yl)-2-(methylthio)pyrimidine
    —— 2-Amino-4-(cyclohex-2-enylsulfanyl)-6-methylsulfanyl-pyrimidine-5-carbonitrile 114460-83-2 C12H14N4S2
    2-Amino-4-(cyclohex-2-enylsulfanyl)-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 5-methyl-4-thioxo-hexan-2-one 15578-81-1 C7H12OS
    5-methyl-4-thioxo-hexan-2-one
    —— 2-(4-Chlor-phenylmercapto)-1-dimethylamino-aethan 90945-21-4 C10H14ClNS
    2-(4-Chlor-phenylmercapto)-1-dimethylamino-aethan
    —— Propyl-thiocarbamic acid S-(4-chloro-phenyl) ester 14496-61-8 C10H12ClNOS
    Propyl-thiocarbamic acid S-(4-chloro-phenyl) ester
    —— N-methyl-2-(2'-amino-4'-hydroxymethylphenylthio)-5-bromobenzylamine 1005412-80-5 C15H17BrN2OS
    N-methyl-2-(2'-amino-4'-hydroxymethylphenylthio)-5-bromobenzylamine
    —— [3-amino-4-[4-iodo-2-[[methyl((111C)methyl)amino]methyl]phenyl]sulfanylphenyl]methanol 1005413-02-4 C16H19IN2OS
    [3-amino-4-[4-iodo-2-[[methyl((111C)methyl)amino]methyl]phenyl]sulfanylphenyl]methanol
    —— [3-amino-4-[4-bromo-2-[[methyl((111C)methyl)amino]methyl]phenyl]sulfanylphenyl]methanol 1005413-01-3 C16H19BrN2OS
    [3-amino-4-[4-bromo-2-[[methyl((111C)methyl)amino]methyl]phenyl]sulfanylphenyl]methanol
    —— [3-amino-4-[4-fluoro-2-[[methyl((111C)methyl)amino]methyl]phenyl]sulfanylphenyl]methanol 1005413-00-2 C16H19FN2OS
    [3-amino-4-[4-fluoro-2-[[methyl((111C)methyl)amino]methyl]phenyl]sulfanylphenyl]methanol
    —— N-methyl-2-(2'-amino-4'-hydroxymethylphenylthio)-5-fluorobenzylamine 1005412-79-2 C15H17FN2OS
    N-methyl-2-(2'-amino-4'-hydroxymethylphenylthio)-5-fluorobenzylamine
    —— Hexakis(p-aminophenylthiomethyl)benzol 72031-82-4 C48H48N6S6
    Hexakis(p-aminophenylthiomethyl)benzol
    —— hexakis[(2-pyridylsulfanyl)methyl]benzene 53403-86-4 C42H36N6S6
    hexakis[(2-pyridylsulfanyl)methyl]benzene
    —— 6-methoxy-3-(phenylthio)-1H-indole 92552-56-2 C15H13NOS
    6-methoxy-3-(phenylthio)-1H-indole
    —— 5,6-dihydropyrido[2,3-b][1,4]benzothiazepine 169878-94-8 C12H10N2S
    5,6-dihydropyrido[2,3-b][1,4]benzothiazepine
    —— 1,6-dithio-2,5-dithia-adipic acid <i>O</i>,<i>O</i>'-bis-dimethylaminomethyl ester 119210-25-2 C10H20N2O2S4
    1,6-dithio-2,5-dithia-adipic acid <i>O</i>,<i>O</i>'-bis-dimethylaminomethyl ester
    —— Hexakis(phenylthiomethyl)benzol 53370-13-1 C48H42S6
    Hexakis(phenylthiomethyl)benzol
    —— 1-(phenylthio)cyclopropanecarboxylic acid 36638-57-0 C10H10O2S
    1-(phenylthio)cyclopropanecarboxylic acid
    —— 4-Aza-phenothiazin-10-carbonsaeure-1-dimethylamino-propylester-3 98344-49-1 C17H19N3O2S
    4-Aza-phenothiazin-10-carbonsaeure-1-dimethylamino-propylester-3
    —— 2-(4-phenyl-butylsulfanyl)-pyrimidin-4-ylamine 60722-72-7 C14H17N3S
    2-(4-phenyl-butylsulfanyl)-pyrimidin-4-ylamine
    —— 2-{3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}-N-(2,5-difluorobenzyl)acetamide 745837-72-3 C32H37F2N3O2S
    2-{3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}-N-(2,5-difluorobenzyl)acetamide
    —— {3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}acetic acid 735274-10-9 C25H32N2O3S
    {3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}acetic acid
    —— 1-ethylsulfanyl(113C)propane 140155-09-5 C5H12S
    1-ethylsulfanyl(113C)propane
    —— 4-[3-(N-dodecyl-N-trifluoroacetylamino)propylthio]pyridine 155966-35-1 C22H35F3N2OS
    4-[3-(N-dodecyl-N-trifluoroacetylamino)propylthio]pyridine
    —— 2-Methyl-4-phenylthio-benzofuro<3,2-d>pyrimidin 68217-87-8 C17H12N2OS
    2-Methyl-4-phenylthio-benzofuro<3,2-d>pyrimidin
    —— butyl trans-2-butenyl sulfone 73687-62-4 C8H16O2S
    butyl trans-2-butenyl sulfone
    —— <2-(6-Ethoxy-5,6-dihydro-6-methylthiazolo<3,2-b><1,2,4>triazol-5-yliden)ethyl>phosphonsaeure-diethylester 113250-13-8 C13H22N3O4PS
    <2-(6-Ethoxy-5,6-dihydro-6-methylthiazolo<3,2-b><1,2,4>triazol-5-yliden)ethyl>phosphonsaeure-diethylester
    —— p-Bromphenyl-2-pentylsulfid 29182-85-2 C11H15BrS
    p-Bromphenyl-2-pentylsulfid
    —— 2-methyl-5-phenylsulfanyl-oxazole-4-carbonitrile 60957-16-6 C11H8N2OS
    2-methyl-5-phenylsulfanyl-oxazole-4-carbonitrile
    —— 2-ethyl-5-phenylsulfanyl-oxazole-4-carbonitrile 60957-19-9 C12H10N2OS
    2-ethyl-5-phenylsulfanyl-oxazole-4-carbonitrile
    —— <<2,3-Dihydro-2-(2-methyl-1-oxopropyl)imidazo<2,1-b>thiazol-3-yl>methyl>phosphonsaeure-diethylester 113250-37-6 C14H23N2O4PS
    <<2,3-Dihydro-2-(2-methyl-1-oxopropyl)imidazo<2,1-b>thiazol-3-yl>methyl>phosphonsaeure-diethylester
    —— 5-Phenylthiooxazol-4-carbonitril 60957-13-3 C10H6N2OS
    5-Phenylthiooxazol-4-carbonitril
    —— 5-cyclopropyl-3-(methylthio)-1,2,4-triazine 69466-76-8 C7H9N3S
    5-cyclopropyl-3-(methylthio)-1,2,4-triazine
    —— 4-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-3-methyl-5-phenylsulfanylmethyl-isoxazole 132611-27-9 C16H18N2O2S
    4-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-3-methyl-5-phenylsulfanylmethyl-isoxazole
    —— (2R)-2-[{2-amino-5-[(4-bromo-2-fluorobenzyl)thio][1,3]thiazolo[4,5-d]pyrimidin-7-yl}(methyl)amino]-4-methylpentan-1-ol 849942-85-4 C19H23BrFN5OS2
    (2R)-2-[{2-amino-5-[(4-bromo-2-fluorobenzyl)thio][1,3]thiazolo[4,5-d]pyrimidin-7-yl}(methyl)amino]-4-methylpentan-1-ol