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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Hydroxy (methyl)-methylenesulfane —— C2H6OS
    Hydroxy (methyl)-methylenesulfane
    —— methanesulfinyl-acetaldehyde 51840-12-1 C3H6O2S
    methanesulfinyl-acetaldehyde
    —— 5-Amino-3-methylthio-1,2,4-triazine 7632-30-6 C4H6N4S
    5-Amino-3-methylthio-1,2,4-triazine
    —— WEHI-0059743 68943-85-1 C8H8N6OS
    WEHI-0059743
    —— N,N-dimethyl-2-((3′-(methylthio)-[5,5′-bi(1,2,4-triazin)]-3-yl)-thio)ethan-1-amine 1255789-70-8 C11H15N7S2
    N,N-dimethyl-2-((3′-(methylthio)-[5,5′-bi(1,2,4-triazin)]-3-yl)-thio)ethan-1-amine
    —— 2-[[5-[3-(2-dimethylaminoethylsulfanyl)-1,2,4-triazin-5-yl]-1,2,4-triazin-3-yl]sulfanyl]-N,N-dimethyl-ethanamine 1255789-71-9 C14H22N8S2
    2-[[5-[3-(2-dimethylaminoethylsulfanyl)-1,2,4-triazin-5-yl]-1,2,4-triazin-3-yl]sulfanyl]-N,N-dimethyl-ethanamine
    —— 2-(5-(3-methylthio-1,2,4-triazin-5-yl)-1,2,4-triazin-3-ylthio)-N,N-diethylethanamine 1255789-72-0 C13H19N7S2
    2-(5-(3-methylthio-1,2,4-triazin-5-yl)-1,2,4-triazin-3-ylthio)-N,N-diethylethanamine
    —— 3,4-dihydro-6-methylthio-2-p-methylphenyl-4-oxopyrimidine-5-carbonitrile 87693-98-9 C13H11N3OS
    3,4-dihydro-6-methylthio-2-p-methylphenyl-4-oxopyrimidine-5-carbonitrile
    —— N,N-dimethyl-2-[[5-(3-methylsulfanyl-1,2,4-triazin-5-yl)-1,2,4-triazin-3-yl]oxy]ethanamine 1255789-69-5 C11H15N7OS
    N,N-dimethyl-2-[[5-(3-methylsulfanyl-1,2,4-triazin-5-yl)-1,2,4-triazin-3-yl]oxy]ethanamine
    —— 3-(4-Methoxyphenyl)-4-(4-methoxyphenyl)sulfanylcyclobut-3-ene-1,2-dione 956110-81-9 C18H14O4S
    3-(4-Methoxyphenyl)-4-(4-methoxyphenyl)sulfanylcyclobut-3-ene-1,2-dione
    —— 2,4-bis(methylthio)imidazo[1,2-f][1,2,4]triazine-7-carboxylic acid 1062135-88-9 C8H8N4O2S2
    2,4-bis(methylthio)imidazo[1,2-f][1,2,4]triazine-7-carboxylic acid
    —— Methyl 3<2-(1,3-dioxolanyl)>furan-2-yl mercaptoacetate 122321-34-0 C10H12O5S
    Methyl 3<2-(1,3-dioxolanyl)>furan-2-yl mercaptoacetate
    —— 3-amino-4,4-dicyano-3-butenethioamide 676655-98-4 C6H6N4S
    3-amino-4,4-dicyano-3-butenethioamide
    —— 2,4-diamino-6-methylsulfanylnicotinnitrile 676656-05-6 C7H8N4S
    2,4-diamino-6-methylsulfanylnicotinnitrile
    —— 1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(2,4-difluorophenyl)urea 417715-68-5 C24H18F2N4O3S2
    1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(2,4-difluorophenyl)urea
    —— N-(2,4-Difluorophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea 417715-36-7 C21H16F2N4O3S2
    N-(2,4-Difluorophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea
    —— (2,6-dichloro-5-methylsulfanylpyrimidin-4-yl)acetic acid methyl ester 1313720-79-4 C8H8Cl2N2O2S
    (2,6-dichloro-5-methylsulfanylpyrimidin-4-yl)acetic acid methyl ester
    —— (2,6-dihydroxy-5-methylsulfanylpyrimidin-4-yl)acetic acid methyl ester 1313720-78-3 C8H10N2O4S
    (2,6-dihydroxy-5-methylsulfanylpyrimidin-4-yl)acetic acid methyl ester
    —— 5-methoxy-2-(thiophen-2-yl)-3-[(3,4,5-trimethoxyphenyl)thio]-1H-indole 1337932-61-2 C22H21NO4S2
    5-methoxy-2-(thiophen-2-yl)-3-[(3,4,5-trimethoxyphenyl)thio]-1H-indole
    —— 1-benzylideneamino-4-ethoxycarbonyl-5-methylmercapto-1,2,3-triazole 127045-29-8 C13H14N4O2S
    1-benzylideneamino-4-ethoxycarbonyl-5-methylmercapto-1,2,3-triazole
    —— 5-(1H-Imidazol-2-ylsulfanyl)-pentanoic acid heptylamide 1027514-75-5 C15H27N3OS
    5-(1H-Imidazol-2-ylsulfanyl)-pentanoic acid heptylamide
    —— Benzyl-(4-chloro-5-methylsulfanyl-pyrimidin-2-yl)-amine 115581-37-8 C12H12ClN3S
    Benzyl-(4-chloro-5-methylsulfanyl-pyrimidin-2-yl)-amine
    —— N-<5-(1H-imidazol-2-ylthio)pentyl>-1-heptanamine 161669-64-3 C15H29N3S
    N-<5-(1H-imidazol-2-ylthio)pentyl>-1-heptanamine
    —— 4-benzilamino-2-metossi-5-metiltiopirimidina 115581-40-3 C13H15N3OS
    4-benzilamino-2-metossi-5-metiltiopirimidina
    —— 5-methylthio-2,4,6-trimethoxypyrimidine 87756-55-6 C8H12N2O3S
    5-methylthio-2,4,6-trimethoxypyrimidine
    —— 2-methyl-5-phenylthio-2-pentene 203632-83-1 C12H16S
    2-methyl-5-phenylthio-2-pentene
    —— 1-(6-Methyl-4-methylsulfanyl-1-phenyl-2-thioxo-1,2-dihydro-pyridin-3-yl)-ethanone 90097-27-1 C15H15NOS2
    1-(6-Methyl-4-methylsulfanyl-1-phenyl-2-thioxo-1,2-dihydro-pyridin-3-yl)-ethanone
    —— methyl [(2-amino-4-chloro-5-formyl-6-pyrimidinyl)thio]ethanoate 873544-78-6 C8H8ClN3O3S
    methyl [(2-amino-4-chloro-5-formyl-6-pyrimidinyl)thio]ethanoate
    —— octakis-2,3,7,8,12,13,17,18-(2-methyl-2-pentenyl)porphyrazine 1331773-85-3 C64H90N8S8
    octakis-2,3,7,8,12,13,17,18-(2-methyl-2-pentenyl)porphyrazine
    —— 1-[1-(4-Chloro-phenyl)-6-methyl-4-methylsulfanyl-2-thioxo-1,2-dihydro-pyridin-3-yl]-ethanone 90097-32-8 C15H14ClNOS2
    1-[1-(4-Chloro-phenyl)-6-methyl-4-methylsulfanyl-2-thioxo-1,2-dihydro-pyridin-3-yl]-ethanone
    —— 3-(O-tert-butyldimethylsilyl)-5-chloro-1,2-O-isopropylidene-5-S-phenyl-5-thio-α-D-xylofuranose 124502-76-7 C20H31ClO4SSi
    3-(O-tert-butyldimethylsilyl)-5-chloro-1,2-O-isopropylidene-5-S-phenyl-5-thio-α-D-xylofuranose
    —— 6,10-anhydro-3-O-(tert-butyldimethylsilyl)-8,9-dideoxy-1,2-O-isopropylidene-5-S-phenyl-5-thio-α-D-glycero-L-ido-decofuranos-7-ulose 124502-84-7 C25H38O6SSi
    6,10-anhydro-3-O-(tert-butyldimethylsilyl)-8,9-dideoxy-1,2-O-isopropylidene-5-S-phenyl-5-thio-α-D-glycero-L-ido-decofuranos-7-ulose
    —— (1Z,3R)-3-tert-butyldimethylsilyloxy-4-methyl-1-(4'-methylphenylthio)-1-nitropent-1-ene 228716-84-5 C19H31NO3SSi
    (1Z,3R)-3-tert-butyldimethylsilyloxy-4-methyl-1-(4'-methylphenylthio)-1-nitropent-1-ene
    —— (4,7-dihydroxy-benzo[1,3]dithiol-2-ylidene)-malononitrile 24059-12-9 C10H4N2O2S2
    (4,7-dihydroxy-benzo[1,3]dithiol-2-ylidene)-malononitrile
    —— 1-Benzyl-3-phenyl-5-phenylthio-1H-1,2,4-triazole 108223-03-6 C21H17N3S
    1-Benzyl-3-phenyl-5-phenylthio-1H-1,2,4-triazole
    —— 2-[(1-methyl-4-nitro-5-imidazolyl)thio]-5-acetamido-1,3,4-thiadiazole 1070980-44-7 C8H8N6O3S2
    2-[(1-methyl-4-nitro-5-imidazolyl)thio]-5-acetamido-1,3,4-thiadiazole
    —— (1Z,3R)-3-hydroxy-4-methyl-1-(4'-methylphenylthio)-1-nitropent-1-ene 228716-86-7 C13H17NO3S
    (1Z,3R)-3-hydroxy-4-methyl-1-(4'-methylphenylthio)-1-nitropent-1-ene
    —— (1'S,2R,3R)-3-(1'-tert-butoxydimethylsilyloxy-2'-methylpropyl)-2-(4''-methylphenylthio)-2-nitrooxirane 228716-90-3 C19H31NO4SSi
    (1'S,2R,3R)-3-(1'-tert-butoxydimethylsilyloxy-2'-methylpropyl)-2-(4''-methylphenylthio)-2-nitrooxirane
    —— (1'S,2R,3R)-3-(1'-hydroxy-2'-methylpropyl)-2-(4''-methylphenylthio)-2-nitrooxirane 228716-88-9 C13H17NO4S
    (1'S,2R,3R)-3-(1'-hydroxy-2'-methylpropyl)-2-(4''-methylphenylthio)-2-nitrooxirane
    —— N-{5-[6,7-bis(2-methoxyethoxy)quinazolin-4-ylthio][1,3,4]thiadiazol-2-yl}acetamide 1370256-69-1 C18H21N5O5S2
    N-{5-[6,7-bis(2-methoxyethoxy)quinazolin-4-ylthio][1,3,4]thiadiazol-2-yl}acetamide
    —— 3.5-Dihydroxy-6-<2-amino-1.3.4-thiadiazolyl-(5)-mercapto>-1.2.4-triazin 4956-10-9 C5H4N6O2S2
    3.5-Dihydroxy-6-<2-amino-1.3.4-thiadiazolyl-(5)-mercapto>-1.2.4-triazin
    —— (4-Chloro-1-phenylsulfanylbutyl)sulfanylbenzene 89593-91-9 C16H17ClS2
    (4-Chloro-1-phenylsulfanylbutyl)sulfanylbenzene
    —— N-(2-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)-'-(3-fluorophenyl)urea 417715-34-5 C21H17FN4O3S2
    N-(2-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)-'-(3-fluorophenyl)urea
    —— 2-Acetylamino-5-phenylsulfanyl-thiazole-4-carboxylic acid ethyl ester 175603-84-6 C14H14N2O3S2
    2-Acetylamino-5-phenylsulfanyl-thiazole-4-carboxylic acid ethyl ester
    —— 1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(3-fluorophenyl)urea 417715-63-0 C24H19FN4O3S2
    1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(3-fluorophenyl)urea
    —— Ethyl 2-amino-5-(3-benzyl-6,7-dimethoxy-4-oxoquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate 1443205-18-2 C23H22N4O5S2
    Ethyl 2-amino-5-(3-benzyl-6,7-dimethoxy-4-oxoquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate
    —— Ethyl 2-amino-5-(6-chloro-4-oxo-3-phenylquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate 1443205-15-9 C20H15ClN4O3S2
    Ethyl 2-amino-5-(6-chloro-4-oxo-3-phenylquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate
    —— Ethyl 2-amino-5-(3-benzyl-6-chloro-4-oxoquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate 1443205-16-0 C21H17ClN4O3S2
    Ethyl 2-amino-5-(3-benzyl-6-chloro-4-oxoquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate
    —— 2-Amino-5-phenylsulfanyl-thiazole-4-carboxylic acid ethyl ester 175603-81-3 C12H12N2O2S2
    2-Amino-5-phenylsulfanyl-thiazole-4-carboxylic acid ethyl ester
    —— N-(6-(6-bromo-[1,2,4]triazolo[4,3-a]pyridin-3-ylthio)imidazo[1,2-b]pyridazin-2-yl)cyclopropanecarboxamide 1208247-67-9 C16H12BrN7OS
    N-(6-(6-bromo-[1,2,4]triazolo[4,3-a]pyridin-3-ylthio)imidazo[1,2-b]pyridazin-2-yl)cyclopropanecarboxamide