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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-<Bis-(phenylthio)-methyl>-cyclopentanol 57768-29-3 C18H20OS2
    1-<Bis-(phenylthio)-methyl>-cyclopentanol
    —— ((E)-(R)-4-Bromo-2-methyl-pent-3-enylsulfanyl)-benzene 143619-02-7 C12H15BrS
    ((E)-(R)-4-Bromo-2-methyl-pent-3-enylsulfanyl)-benzene
    —— (3S,4S)-3-(Bis-phenylsulfanyl-methyl)-4-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopentanone 167260-19-7 C26H36O2S2Si
    (3S,4S)-3-(Bis-phenylsulfanyl-methyl)-4-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopentanone
    —— 1-[(2-ethyl-2-hydroxy-1-phenylsulfanyl)butyl]cyclohexanol 253797-53-4 C18H28O2S
    1-[(2-ethyl-2-hydroxy-1-phenylsulfanyl)butyl]cyclohexanol
    —— Dichloro-acetic acid phenylsulfanylmethyl ester 59231-04-8 C9H8Cl2O2S
    Dichloro-acetic acid phenylsulfanylmethyl ester
    —— (+)-(R)-2-(bis(phenylthio)methyl)butane-1,4-diol 1353547-44-0 C17H20O2S2
    (+)-(R)-2-(bis(phenylthio)methyl)butane-1,4-diol
    —— 4-benzyl-6,6-bis(phenylsulfanyl)hex-1-ene 222547-33-3 C25H26S2
    4-benzyl-6,6-bis(phenylsulfanyl)hex-1-ene
    —— ((E)-(S)-3-Bromo-2-methyl-pent-3-enylsulfanyl)-benzene 143619-21-0 C12H15BrS
    ((E)-(S)-3-Bromo-2-methyl-pent-3-enylsulfanyl)-benzene
    —— 5-[2,2-bis(phenylsulfanyl)ethyl]-2-methyl-8-phenyloct-1-ene 222547-35-5 C29H34S2
    5-[2,2-bis(phenylsulfanyl)ethyl]-2-methyl-8-phenyloct-1-ene
    —— 2-methyl-6-methylthioimidazo<1,2-b>pyridazine 142074-16-6 C8H9N3S
    2-methyl-6-methylthioimidazo<1,2-b>pyridazine
    —— 5-hydroxy-4,4-bisphenylthiohept-1-ene 98793-19-2 C19H22OS2
    5-hydroxy-4,4-bisphenylthiohept-1-ene
    —— (+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane 1353547-45-1 C29H48O2S2Si2
    (+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane
    —— bis[bis(phenylthio)methyl]dimethylsilane 1266779-29-6 C28H28S4Si
    bis[bis(phenylthio)methyl]dimethylsilane
    —— 2-Naphthalen-2-yl-6-phenylsulfanyl-imidazo[1,2-b]pyridazine 180900-91-8 C22H15N3S
    2-Naphthalen-2-yl-6-phenylsulfanyl-imidazo[1,2-b]pyridazine
    —— 3-benzamidomethyl-2-methyl-6-phenylthioimidazo<1,2-b>pyridazine 142074-19-9 C21H18N4OS
    3-benzamidomethyl-2-methyl-6-phenylthioimidazo<1,2-b>pyridazine
    —— 7-(1-methyl-1-phenylthioethyl)-1,4-dioxaspiro<4,5>decane 163068-79-9 C17H24O2S
    7-(1-methyl-1-phenylthioethyl)-1,4-dioxaspiro<4,5>decane
    —— 3-<1-methyl-1-(phenylthio)ethyl>-1-cyclohexanone 161145-67-1 C15H20OS
    3-<1-methyl-1-(phenylthio)ethyl>-1-cyclohexanone
    —— 3-ethyl-7-(phenylthio)-1,5,8,8a-tetrahydro-5-indolizinone 1415683-72-5 C16H17NOS
    3-ethyl-7-(phenylthio)-1,5,8,8a-tetrahydro-5-indolizinone
    —— 1,6-diallyl-4-(phenylthio)-1,2,5,6-tetrahydropyridin-2-one 949103-80-4 C17H19NOS
    1,6-diallyl-4-(phenylthio)-1,2,5,6-tetrahydropyridin-2-one
    —— 5-(2-Oxo-ethylsulfanyl)-2-thioxo-[1,3]dithiole-4-carbaldehyde 1026723-43-2 C6H4O2S4
    5-(2-Oxo-ethylsulfanyl)-2-thioxo-[1,3]dithiole-4-carbaldehyde
    —— Barium reineckate 22708-05-0 C8H12BaCr2N12S8
    Barium reineckate
    —— (1R,2Z,6E,8E,12R)-N-(1-hydroxymethyl-12-methoxy-9-methylpentadeca-2,6,8,14-tetraenyl)-2,2-dimethylthiopropionamide 431982-08-0 C23H39NO2S
    (1R,2Z,6E,8E,12R)-N-(1-hydroxymethyl-12-methoxy-9-methylpentadeca-2,6,8,14-tetraenyl)-2,2-dimethylthiopropionamide
    —— 1-(2-chlorophenyl)sulfanyl-3-[2-methylpropyl(2-morpholin-4-ylethyl)amino]propan-2-ol;hydron;dichloride —— C19H33Cl3N2O2S
    1-(2-chlorophenyl)sulfanyl-3-[2-methylpropyl(2-morpholin-4-ylethyl)amino]propan-2-ol;hydron;dichloride
    —— 4-Methylsulfanyl-6-pyridin-2-yl-2-thiophen-2-yl-pyrimidine 87568-81-8 C14H11N3S2
    4-Methylsulfanyl-6-pyridin-2-yl-2-thiophen-2-yl-pyrimidine
    —— 4-Furan-2-yl-6-methylsulfanyl-2-thiophen-2-yl-pyrimidine 87568-79-4 C13H10N2OS2
    4-Furan-2-yl-6-methylsulfanyl-2-thiophen-2-yl-pyrimidine
    —— 5,6-dihydro-1H-thieno[3,2-c]pyrazole 1447827-71-5 C5H6N2S
    5,6-dihydro-1H-thieno[3,2-c]pyrazole
    —— 2-(6-Bromobenzo[d][1,3]dioxol-5-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-56-0 C18H15BrN4O2S
    2-(6-Bromobenzo[d][1,3]dioxol-5-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2-(methylthio)-3-(benzyloxymethyl)pyrimidin-4-one 146202-39-3 C13H14N2O2S
    2-(methylthio)-3-(benzyloxymethyl)pyrimidin-4-one
    —— 1,2-bis-(2-methylthio-4-oxopyrimidin-3-yl)ethane 89185-12-6 C12H14N4O2S2
    1,2-bis-(2-methylthio-4-oxopyrimidin-3-yl)ethane
    —— tert-butyl 2-aminooxy-2-(phenylthio)acetate 135996-03-1 C12H17NO3S
    tert-butyl 2-aminooxy-2-(phenylthio)acetate
    —— 6-(p-tolylthio)pyrimidine-2,4(1H,3H)-dione 80947-49-5 C11H10N2O2S
    6-(p-tolylthio)pyrimidine-2,4(1H,3H)-dione
    —— 1-Ethylmercapto-2-cyclohexyliden-ethan-1-ol 103649-10-1 C10H18OS
    1-Ethylmercapto-2-cyclohexyliden-ethan-1-ol
    —— 3,3-bis-methylsulfanyl-propan-1-ol 36678-00-9 C5H12OS2
    3,3-bis-methylsulfanyl-propan-1-ol
    —— 4-(2-hydroxy-ethoxy)-2-methylthiopyrimidine 112010-47-6 C7H10N2O2S
    4-(2-hydroxy-ethoxy)-2-methylthiopyrimidine
    —— 1-((p-Chlorophenyl)thio)-3-(isopropyl(2-morpholinoethyl)amino)-2-propanol dihydrochloride 22820-25-3 C18H31Cl3N2O2S
    1-((p-Chlorophenyl)thio)-3-(isopropyl(2-morpholinoethyl)amino)-2-propanol dihydrochloride
    —— 1,1-Bis-methylsulfanyl-2-vinyl-cyclopropane 58681-15-5 C7H12S2
    1,1-Bis-methylsulfanyl-2-vinyl-cyclopropane
    —— N,N-diethyl-O-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]-α-methylbenzyl}hydroxylamine 153714-89-7 C24H32FNO3S
    N,N-diethyl-O-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]-α-methylbenzyl}hydroxylamine
    —— 6-(4-Chloro-phenylsulfanyl)-1H-pyrimidine-2,4-dione 80947-48-4 C10H7ClN2O2S
    6-(4-Chloro-phenylsulfanyl)-1H-pyrimidine-2,4-dione
    —— 6-<(3,5-dimethylphenyl)thio>uracil 155854-42-5 C12H12N2O2S
    6-<(3,5-dimethylphenyl)thio>uracil
    —— 6-(4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)pyrimidine-2,4(1H,3H)-dione 1275607-99-2 C14H15N5O3S
    6-(4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)pyrimidine-2,4(1H,3H)-dione
    —— acryloyl-2,3-dihydro-1H-pyrido[2,3-b][1,4]thiazine 827336-96-9 C10H10N2OS
    acryloyl-2,3-dihydro-1H-pyrido[2,3-b][1,4]thiazine
    —— methyl mercaptoethyl sulfone 24517-45-1 C3H8O2S2
    methyl mercaptoethyl sulfone
    —— (4-Methoxycarbonylmethylsulfanyl-pyrimidin-2-ylsulfanyl)-acetic acid methyl ester 112498-37-0 C10H12N2O4S2
    (4-Methoxycarbonylmethylsulfanyl-pyrimidin-2-ylsulfanyl)-acetic acid methyl ester
    —— 4-[2-(4-Chloro-phenylsulfanyl)-phenyl]-6-methyl-2-phenyl-1,4-dihydro-pyrimidine-5-carboxylic acid ethyl ester 143996-71-8 C26H23ClN2O2S
    4-[2-(4-Chloro-phenylsulfanyl)-phenyl]-6-methyl-2-phenyl-1,4-dihydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 5-bromo-2chloro-4-(phenylthio)pyrimidine 358978-10-6 C10H6BrClN2S
    5-bromo-2chloro-4-(phenylthio)pyrimidine
    —— 2,4-bis(benzylthio)-5-bromopyridine 125154-09-8 C18H15BrN2S2
    2,4-bis(benzylthio)-5-bromopyridine
    —— methyl 2-methoxy-N-methyl-2,3-butadienimidothioate 188180-25-8 C7H11NOS
    methyl 2-methoxy-N-methyl-2,3-butadienimidothioate
    —— (Z)-3-ethylthio-5,5-dimethyl-2-cyclohexenylidene acetonitrile 76399-20-7 C12H17NS
    (Z)-3-ethylthio-5,5-dimethyl-2-cyclohexenylidene acetonitrile
    —— (E)-3-ethylthio-5,5-dimethyl-2-cyclohexenylidene acetonitrile 76399-21-8 C12H17NS
    (E)-3-ethylthio-5,5-dimethyl-2-cyclohexenylidene acetonitrile
    —— N-(5-bromo-4-methylsulphanylpyrimidin-2-yl)-N'-pyridin-2-yl-benzene-1,4-diamine 1034358-79-6 C16H14BrN5S
    N-(5-bromo-4-methylsulphanylpyrimidin-2-yl)-N'-pyridin-2-yl-benzene-1,4-diamine