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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R,3S)-5,5-Dimethoxy-3-phenylsulfanyl-pentane-1,2-diol 143422-71-3 C13H20O4S
    (2R,3S)-5,5-Dimethoxy-3-phenylsulfanyl-pentane-1,2-diol
    —— 3-[6-chloro-7-fluoro-2-methyl-1-(5-methyl-thiophen-3-yl)-1H-indol-3-ylsulfanyl]-benzoic acid 1359983-07-5 C21H15ClFNO2S2
    3-[6-chloro-7-fluoro-2-methyl-1-(5-methyl-thiophen-3-yl)-1H-indol-3-ylsulfanyl]-benzoic acid
    —— cis-[PdI(bpy)(C6H4(SC6H4(SC6H4NO2-4)-4)-4)] 1333499-75-4 C28H20IN3O2PdS2
    cis-[PdI(bpy)(C6H4(SC6H4(SC6H4NO2-4)-4)-4)]
    —— 2-ethylsulfanyl-5-propyl-furan-3-carbaldehyde 21984-71-4 C10H14O2S
    2-ethylsulfanyl-5-propyl-furan-3-carbaldehyde
    —— 4-(3,5-dimethylphenylthio)-3-(4-(3-fluorobenzoyl)piperazin-1-ylsulfonyl)benzonitrile 1253109-19-1 C26H24FN3O3S2
    4-(3,5-dimethylphenylthio)-3-(4-(3-fluorobenzoyl)piperazin-1-ylsulfonyl)benzonitrile
    —— 2-((2,4-dinitrophenyl)sulphanyl)-5-methoxybenzimidazole 1424375-00-7 C14H10N4O5S
    2-((2,4-dinitrophenyl)sulphanyl)-5-methoxybenzimidazole
    —— {3-[1-(2,4-dinitro-phenyl)-8-(6-iodo-benzo[1,3]dioxol-5-ylsulfanyl)-6-oxo-1,6-dihydro-purin-9-yl]-propyl}-isopropyl-carbamic acid tert-butyl ester 1102466-48-7 C29H30IN7O9S
    {3-[1-(2,4-dinitro-phenyl)-8-(6-iodo-benzo[1,3]dioxol-5-ylsulfanyl)-6-oxo-1,6-dihydro-purin-9-yl]-propyl}-isopropyl-carbamic acid tert-butyl ester
    —— 1-Methyl-2-(13-methyl-tetradecylsulfanyl)-1H-imidazole; hydrochloride 50968-50-8 C19H36N2S*ClH
    1-Methyl-2-(13-methyl-tetradecylsulfanyl)-1H-imidazole; hydrochloride
    —— 1-Chloro-3,3-dimethyl-1-phenylsulfanylbutan-2-one 137351-39-4 C12H15ClOS
    1-Chloro-3,3-dimethyl-1-phenylsulfanylbutan-2-one
    —— 5-Isopropyl-4-phenylthio-3-hydroxy-2-oxo-2.5-dihydrofuran 51642-84-3 C13H14O3S
    5-Isopropyl-4-phenylthio-3-hydroxy-2-oxo-2.5-dihydrofuran
    —— 2-(α-Hydroxybenzyl)-2-trimethylsilylmethyl-1,3-dithian 52214-00-3 C15H24OS2Si
    2-(α-Hydroxybenzyl)-2-trimethylsilylmethyl-1,3-dithian
    —— S-Isobutyl-n-propylthiocarbonat 53120-93-7 C8H16O2S
    S-Isobutyl-n-propylthiocarbonat
    —— 4-(4-Iodo-phenylsulfanyl)-butyric acid 52872-95-4 C10H11IO2S
    4-(4-Iodo-phenylsulfanyl)-butyric acid
    —— (5-methyl-2-methylsulfanyl-thiophen-3-yl)-acetonitrile 40990-30-5 C8H9NS2
    (5-methyl-2-methylsulfanyl-thiophen-3-yl)-acetonitrile
    —— (5-ethoxymethoxy-cyclopent-1-enylsulfanyl)-benzene 847155-07-1 C14H18O2S
    (5-ethoxymethoxy-cyclopent-1-enylsulfanyl)-benzene
    —— 4-p-Tolylsulfanyl-[1,2]dithiolane 52142-42-4 C10H12S3
    4-p-Tolylsulfanyl-[1,2]dithiolane
    —— 2-Methyl-3-methylsulfanyl-7-[1-methylsulfanyl-prop-(Z)-ylidene]-4,5,6,7-tetrahydro-benzo[b]thiophene 54103-25-2 C14H20S3
    2-Methyl-3-methylsulfanyl-7-[1-methylsulfanyl-prop-(Z)-ylidene]-4,5,6,7-tetrahydro-benzo[b]thiophene
    —— Dithiocarbonic acid O-tert-butyl ester S-(1-methylsulfanyl-ethyl) ester 41335-11-9 C8H16OS3
    Dithiocarbonic acid O-tert-butyl ester S-(1-methylsulfanyl-ethyl) ester
    —— 7,7'-Dimethyl-2,2'-di-(benzo<1,4>thiazinyliden)-5,5'-diol 57037-48-6 C18H14N2O2S2
    7,7'-Dimethyl-2,2'-di-(benzo<1,4>thiazinyliden)-5,5'-diol
    —— (Phenylthio-2-phenyl-1)ethyldiphenylphosphinoxid 60625-46-9 C26H23OPS
    (Phenylthio-2-phenyl-1)ethyldiphenylphosphinoxid
    —— 3-[6-chloro-2-methyl-1-(1-propyl-1H-pyrazol-4-yl)-1H-indol-3-ylsulfanyl]-benzoic acid ethyl ester 1359981-17-1 C24H24ClN3O2S
    3-[6-chloro-2-methyl-1-(1-propyl-1H-pyrazol-4-yl)-1H-indol-3-ylsulfanyl]-benzoic acid ethyl ester
    —— Dimethyl-phosphinodithioic acid 1-ethylsulfanyl-ethyl ester 5761-88-6 C6H15PS3
    Dimethyl-phosphinodithioic acid 1-ethylsulfanyl-ethyl ester
    —— (2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1,1-dimethyl-heptylsulfanyl)-benzene 84108-54-3 C15H11F13S
    (2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1,1-dimethyl-heptylsulfanyl)-benzene
    —— 1,1-bis-ethanesulfonyl-2-methyl-propene 3122-25-6 C8H16O4S2
    1,1-bis-ethanesulfonyl-2-methyl-propene
    —— 5-methyl-6-methylthioimidazo<4,5-c>pyridazine 79690-91-8 C7H8N4S
    5-methyl-6-methylthioimidazo<4,5-c>pyridazine
    —— 2-ethoxycarbonylsulfanyl-4-methyl-thiazole 5316-73-4 C7H9NO2S2
    2-ethoxycarbonylsulfanyl-4-methyl-thiazole
    —— 1-{1-[5-(3-chloro-phenyl)-isoxazol-3-yl]-ethyl}-2-methylsulfanyl-1,4,5,6-tetrahydro-pyrimidine 956360-67-1 C16H18ClN3OS
    1-{1-[5-(3-chloro-phenyl)-isoxazol-3-yl]-ethyl}-2-methylsulfanyl-1,4,5,6-tetrahydro-pyrimidine
    —— 3-(3-phenylsulfanylbutan-2-yl)cyclohexan-1-one 103409-50-3 C16H22OS
    3-(3-phenylsulfanylbutan-2-yl)cyclohexan-1-one
    —— N,N-Dimethylthiocarbaminsaeure-O-(E)-2-butenylester 39707-20-5 C7H13NOS
    N,N-Dimethylthiocarbaminsaeure-O-(E)-2-butenylester
    —— 3-[(4-phenylthiazol-2-yl)thiomethyl]piperidine 876148-14-0 C15H18N2S2
    3-[(4-phenylthiazol-2-yl)thiomethyl]piperidine
    —— phenyl 2-bromo-3,3-difluoroallyl sulfide 1425538-76-6 C9H7BrF2S
    phenyl 2-bromo-3,3-difluoroallyl sulfide
    —— Diisopropyl-thiocarbamic acid O-(2-phenylsulfanyl-ethyl) ester 13193-03-8 C15H23NOS2
    Diisopropyl-thiocarbamic acid O-(2-phenylsulfanyl-ethyl) ester
    —— 1-(2-Hydroxymethyl-1-phenylsulfanyl-cyclopropyl)-prop-2-en-1-ol 84851-75-2 C13H16O2S
    1-(2-Hydroxymethyl-1-phenylsulfanyl-cyclopropyl)-prop-2-en-1-ol
    —— 1-Chloro-1-phenylsulfanyl-octan-2-one 87143-60-0 C14H19ClOS
    1-Chloro-1-phenylsulfanyl-octan-2-one
    —— 8-acetoxy-2-methyl-9-(phenylthio)-2-nonene 153171-79-0 C18H26O2S
    8-acetoxy-2-methyl-9-(phenylthio)-2-nonene
    —— 52416-57-6 C16H27N3S
    —— 3-(4-amino-3-methylsulfanyl-5-thioxo-4,5-dihydro-[1,2,4]triazol-1-yl)-propionitrile 42076-18-6 C6H9N5S2
    3-(4-amino-3-methylsulfanyl-5-thioxo-4,5-dihydro-[1,2,4]triazol-1-yl)-propionitrile
    —— cis-1-ethynyl-4-(3,3,3-trifluoropropylsulfonylmethyl)cyclohexane 1097630-09-5 C12H17F3O2S
    cis-1-ethynyl-4-(3,3,3-trifluoropropylsulfonylmethyl)cyclohexane
    —— cyclopent-3-en-1-yl(1,1,1,3,3,3-hexafluoropropan-2-yl)sulfane 1499-90-7 C8H8F6S
    cyclopent-3-en-1-yl(1,1,1,3,3,3-hexafluoropropan-2-yl)sulfane
    —— tert-butyl ({4-(2-fluoropyridin-3-yl)-5-[(1-methyl-1H-imidazol-2-yl)thio]thiophen-2-yl}methyl)methylcarbamate 1138035-29-6 C20H23FN4O2S2
    tert-butyl ({4-(2-fluoropyridin-3-yl)-5-[(1-methyl-1H-imidazol-2-yl)thio]thiophen-2-yl}methyl)methylcarbamate
    —— 1598427-04-3 C17H22O2S2
    —— 5-(2-hydroxy-ethylsulfanyl)-3,6-dimethyl-1-phenyl-1<i>H</i>-pyrimidine-2,4-dione 50436-04-9 C14H16N2O3S
    5-(2-hydroxy-ethylsulfanyl)-3,6-dimethyl-1-phenyl-1<i>H</i>-pyrimidine-2,4-dione
    —— 8H-Dithieno[2,3-b;2',3'-e]thiopyran 42057-16-9 C9H6S3
    8H-Dithieno[2,3-b;2',3'-e]thiopyran
    —— 4-Ethanesulfinyl-4-ethylsulfanyl-2-methylsulfanyl-butyric acid methyl ester 49585-61-7 C10H20O3S3
    4-Ethanesulfinyl-4-ethylsulfanyl-2-methylsulfanyl-butyric acid methyl ester
    —— 4-amino-5-(2-nitro-phenylsulfanyl)-2-phenyl-2<i>H</i>-pyridazin-3-one 41739-89-3 C16H12N4O3S
    4-amino-5-(2-nitro-phenylsulfanyl)-2-phenyl-2<i>H</i>-pyridazin-3-one
    —— 8-Methoxy-10-phenyl-9-oxa-1,5-dithia-spiro[5.5]undecane 40990-06-5 C15H20O2S2
    8-Methoxy-10-phenyl-9-oxa-1,5-dithia-spiro[5.5]undecane
    —— 3,5-Bis-p-phenylthiobenzoylmethylen-1,2,4-trithiolan 57215-94-8 C30H20O2S5
    3,5-Bis-p-phenylthiobenzoylmethylen-1,2,4-trithiolan
    —— (E)-4-thiocyanato-5-phenylthio-4-octene 1148025-78-8 C15H19NS2
    (E)-4-thiocyanato-5-phenylthio-4-octene
    —— 1-[2-Butylsulfanyl-4-phenyl-5-(1-phenylpentyl)thiophen-3-yl]ethanone 1394951-12-2 C27H32OS2
    1-[2-Butylsulfanyl-4-phenyl-5-(1-phenylpentyl)thiophen-3-yl]ethanone
    —— 6-[2-(4-dimethylamino-6-methyl-[1,3,5]triazin-2-ylamino)-phenylsulfanyl]-tetra-<i>N</i>-methyl-[1,3,5]triazine-2,4-diamine 50829-87-3 C19H26N10S
    6-[2-(4-dimethylamino-6-methyl-[1,3,5]triazin-2-ylamino)-phenylsulfanyl]-tetra-<i>N</i>-methyl-[1,3,5]triazine-2,4-diamine