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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Pyrimidine, 2,2'-(1,10-decanediylbis(thio))bis(4,6-dimethyl- 123392-11-0 C22H34N4S2
    Pyrimidine, 2,2'-(1,10-decanediylbis(thio))bis(4,6-dimethyl-
    —— Morpholine, 4,4'-(1,6-hexanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis- 123392-15-4 C24H36N6O2S2
    Morpholine, 4,4'-(1,6-hexanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis-
    —— Morpholine, 4,4'-(1,4-butanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis- 123392-13-2 C22H32N6O2S2
    Morpholine, 4,4'-(1,4-butanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis-
    —— Morpholine, 4,4'-(1,5-pentanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis- 123392-14-3 C23H34N6O2S2
    Morpholine, 4,4'-(1,5-pentanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis-
    —— N,N-dimethyl-2-[(1-methylimidazol-2-yl)sulfanylmethyl]aniline;hydron;dichloride —— C13H19Cl2N3S
    N,N-dimethyl-2-[(1-methylimidazol-2-yl)sulfanylmethyl]aniline;hydron;dichloride
    —— N-Methyl-1-(2-(phenylthio)phenyl)-2-propylamine oxalate 127876-84-0 C18H21NO4S
    N-Methyl-1-(2-(phenylthio)phenyl)-2-propylamine oxalate
    —— 4-(2-Difluoromethylsulfanyl-phenyl)-2-methyl-5-oxo-1,4,5,7-tetrahydro-furo[3,4-b]pyridine-3-carboxylic acid methyl ester 126335-07-7 C17H15F2NO4S
    4-(2-Difluoromethylsulfanyl-phenyl)-2-methyl-5-oxo-1,4,5,7-tetrahydro-furo[3,4-b]pyridine-3-carboxylic acid methyl ester
    —— [2-(3,4-dimethoxyphenyl)sulfanylphenyl]methanamine;hydron;chloride —— C15H18ClNO2S
    [2-(3,4-dimethoxyphenyl)sulfanylphenyl]methanamine;hydron;chloride
    —— hydron;4-[2-(methylaminomethyl)phenyl]sulfanylbenzene-1,3-diol;bromide —— C14H16BrNO2S
    hydron;4-[2-(methylaminomethyl)phenyl]sulfanylbenzene-1,3-diol;bromide
    —— 1-[2-(3,4-dimethoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;hydron;chloride —— C17H22ClNO2S
    1-[2-(3,4-dimethoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;hydron;chloride
    —— hydron;[2-(3-methoxyphenyl)sulfanylphenyl]methanamine;chloride —— C14H16ClNOS
    hydron;[2-(3-methoxyphenyl)sulfanylphenyl]methanamine;chloride
    —— N-Methyl-2-(2-(phenylthio)phenyl)ethylamine oxalate 127876-79-3 C17H19NO4S
    N-Methyl-2-(2-(phenylthio)phenyl)ethylamine oxalate
    —— Phenol, 3-((2-((dipropylamino)methyl)phenyl)thio)-, hydrochloride 127906-68-7 C19H26ClNOS
    Phenol, 3-((2-((dipropylamino)methyl)phenyl)thio)-, hydrochloride
    —— 2-[2-(aminomethyl)phenyl]sulfanylphenol;hydron;chloride —— C13H14ClNOS
    2-[2-(aminomethyl)phenyl]sulfanylphenol;hydron;chloride
    —— hydron;[2-(4-methoxyphenyl)sulfanylphenyl]methanamine;chloride —— C14H16ClNOS
    hydron;[2-(4-methoxyphenyl)sulfanylphenyl]methanamine;chloride
    —— Phenol, 2-((2-((dipropylamino)methyl)phenyl)thio)-, hydrochloride 127906-67-6 C19H26ClNOS
    Phenol, 2-((2-((dipropylamino)methyl)phenyl)thio)-, hydrochloride
    —— Phenol, 3-((2-((dimethylamino)methyl)phenyl)thio)-, hydrobromide 127906-25-6 C15H18BrNOS
    Phenol, 3-((2-((dimethylamino)methyl)phenyl)thio)-, hydrobromide
    —— hydron;1-[2-(2-methoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;chloride —— C16H20ClNOS
    hydron;1-[2-(2-methoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;chloride
    —— [2-(3-Hydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium;chloride —— C15H18ClNOS
    [2-(3-Hydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium;chloride
    —— hydron;1-[2-(4-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride —— C15H18ClNOS
    hydron;1-[2-(4-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride
    —— Benzenemethanamine, 2-((2-methoxyphenyl)thio)-, hydrochloride 127905-98-0 C14H16ClNOS
    Benzenemethanamine, 2-((2-methoxyphenyl)thio)-, hydrochloride
    —— hydron;1-[2-(2-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride —— C15H18ClNOS
    hydron;1-[2-(2-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride
    —— hydron;1-[2-(3-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride —— C15H18ClNOS
    hydron;1-[2-(3-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride
    —— hydron;1-[2-(4-methoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;chloride —— C16H20ClNOS
    hydron;1-[2-(4-methoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;chloride
    —— Phenol, 3-((2-(1-(dimethylamino)ethyl)phenyl)thio)-, hydrobromide, (-)- 127906-86-9 C16H20BrNOS
    Phenol, 3-((2-(1-(dimethylamino)ethyl)phenyl)thio)-, hydrobromide, (-)-
    —— 2-[2-[[di(propan-2-yl)amino]methyl]phenyl]sulfanylphenol;hydron;chloride —— C19H26ClNOS
    2-[2-[[di(propan-2-yl)amino]methyl]phenyl]sulfanylphenol;hydron;chloride
    —— 1-Phenyl-2-(4-hydroxy-phenyl)-3.5-dioxo-4-(2-phenylmercapto-ethyl)-pyrazolidin 1174-98-7 C23H20N2O3S
    1-Phenyl-2-(4-hydroxy-phenyl)-3.5-dioxo-4-(2-phenylmercapto-ethyl)-pyrazolidin
    —— Carbamimidothioic acid, pentyl ester, monohydrobromide 4270-00-2 C6H14BrN2S-
    Carbamimidothioic acid, pentyl ester, monohydrobromide
    —— ethylsulfanylethane;platinum(2+);dihydrochloride —— C8H22Cl2PtS2+2
    ethylsulfanylethane;platinum(2+);dihydrochloride
    —— ((2-Methylbutyl)thio)formamidine 44816-46-8 C6H14N2S
    ((2-Methylbutyl)thio)formamidine
    —— Sodium dithioformate 69316-68-3 CH3NaS2
    Sodium dithioformate
    —— Diicosyltetrasulfane —— C40H82S4
    Diicosyltetrasulfane
    —— 2-Cyclohexene-1-methanethiol, 2,6,6-trimethyl- 71820-48-9 C10H18S
    2-Cyclohexene-1-methanethiol, 2,6,6-trimethyl-
    —— 3,3,4,4,5,5-Hexafluoro-1-(3,3,4,4,5,5-hexafluorohexyldisulfanyl)hexane 118400-71-8 C12H14F12S2
    3,3,4,4,5,5-Hexafluoro-1-(3,3,4,4,5,5-hexafluorohexyldisulfanyl)hexane
    —— 1-(1-(5-chloro-2-phenylthio)phenyl)ethyl-4-(2-hydroxyethyl)piperazine 112446-35-2 C20H25ClN2OS
    1-(1-(5-chloro-2-phenylthio)phenyl)ethyl-4-(2-hydroxyethyl)piperazine
    —— 2-(4-{1-[5-Chloro-2-(2-chloro-phenylsulfanyl)-phenyl]-ethyl}-piperazin-1-yl)-ethanol 112446-36-3 C20H24Cl2N2OS
    2-(4-{1-[5-Chloro-2-(2-chloro-phenylsulfanyl)-phenyl]-ethyl}-piperazin-1-yl)-ethanol
    —— 1-{1-[5-Chloro-2-(2-chloro-phenylsulfanyl)-phenyl]-ethyl}-4-methyl-piperazine 112446-31-8 C19H22Cl2N2S
    1-{1-[5-Chloro-2-(2-chloro-phenylsulfanyl)-phenyl]-ethyl}-4-methyl-piperazine
    —— 1-{1-[5-Chloro-2-(4-chloro-phenylsulfanyl)-phenyl]-ethyl}-4-methyl-piperazine 112446-32-9 C19H22Cl2N2S
    1-{1-[5-Chloro-2-(4-chloro-phenylsulfanyl)-phenyl]-ethyl}-4-methyl-piperazine
    —— 1-[1-(5-Bromo-2-phenylsulfanyl-phenyl)-ethyl]-4-methyl-piperazine 112446-48-7 C19H23BrN2S
    1-[1-(5-Bromo-2-phenylsulfanyl-phenyl)-ethyl]-4-methyl-piperazine
    —— Benzoic acid, 4-((5-(3,5-dinitrophenyl)-4-phenyl-4H-1,2,4-triazol-3-yl)thio)- 119228-58-9 C21H13N5O6S
    Benzoic acid, 4-((5-(3,5-dinitrophenyl)-4-phenyl-4H-1,2,4-triazol-3-yl)thio)-
    —— Benzoic acid, 4-((5-(3,5-dinitrophenyl)-4-(4-methoxyphenyl)-4H-1,2,4-triazol-3-yl)thio)- 119228-59-0 C22H15N5O7S
    Benzoic acid, 4-((5-(3,5-dinitrophenyl)-4-(4-methoxyphenyl)-4H-1,2,4-triazol-3-yl)thio)-
    —— Benzoic acid, 4-((5-(3,5-dinitrophenyl)-4-(2-methylphenyl)-4H-1,2,4-triazol-3-yl)thio)- 119228-56-7 C22H15N5O6S
    Benzoic acid, 4-((5-(3,5-dinitrophenyl)-4-(2-methylphenyl)-4H-1,2,4-triazol-3-yl)thio)-
    —— N-Acetyl-1-(p-chlorphenylthio)-2,2-dichloraethylamin 58956-87-9 C10H10Cl3NOS
    N-Acetyl-1-(p-chlorphenylthio)-2,2-dichloraethylamin
    —— 2-(2,6-Dinitro-4-trifluoromethylphenylthio)benzimidazol 60968-22-1 C14H7F3N4O4S
    2-(2,6-Dinitro-4-trifluoromethylphenylthio)benzimidazol
    —— 4,4,6-trimethyl-2-methylsulfanyl-5,6-dihydro-4<i>H</i>-[1,3]oxazine 60644-42-0 C8H15NOS
    4,4,6-trimethyl-2-methylsulfanyl-5,6-dihydro-4<i>H</i>-[1,3]oxazine
    —— (5-Cyanomethylsulfanyl-2-thioxo-[1,3]dithiol-4-ylsulfanyl)-acetonitrile 179010-11-8 C7H4N2S5
    (5-Cyanomethylsulfanyl-2-thioxo-[1,3]dithiol-4-ylsulfanyl)-acetonitrile
    —— 2-(prop-1-en-1-ylthio)aniline 1204588-94-2 C9H11NS
    2-(prop-1-en-1-ylthio)aniline
    —— N,N-dicyclohexyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide 444152-48-1 C23H31N3O2S
    N,N-dicyclohexyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-(6-Amino-3,5-dicyano-pyridin-2-ylsulfanyl)-acetamide 119022-83-2 C9H7N5OS
    2-(6-Amino-3,5-dicyano-pyridin-2-ylsulfanyl)-acetamide
    —— N-tert-butyl-4-{[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl}butanamide 5161-52-4 C17H20F3N3O2S
    N-tert-butyl-4-{[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl}butanamide