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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (+-)-1'-Methyl-3-(2-methylphenyl)spiro(benzo(b)thiophene-2(3H),4'-piperidine) maleate 123245-21-6 C24H27NO4S
    (+-)-1'-Methyl-3-(2-methylphenyl)spiro(benzo(b)thiophene-2(3H),4'-piperidine) maleate
    —— 6-(2,4-Dimethylphenyl)-4-methylsulfanyl-2-oxopyran-3-carbonitrile 956041-33-1 C15H13NO2S
    6-(2,4-Dimethylphenyl)-4-methylsulfanyl-2-oxopyran-3-carbonitrile
    —— 2,3-dihydro-2-cyano-2-(tert-butylthio)-6-chlorobenzo<b>thiophene 92013-98-4 C13H14ClNS2
    2,3-dihydro-2-cyano-2-(tert-butylthio)-6-chlorobenzo<b>thiophene
    —— N,N-Dimethyl-5-fluoro-2-(3-hydroxyphenylthio)benzylamine maleate 134987-57-8 C19H20FNO5S
    N,N-Dimethyl-5-fluoro-2-(3-hydroxyphenylthio)benzylamine maleate
    —— N-(4-{4-[5-(2-methoxyethoxy)pyrazin-2-ylthio]-2,6-dimethylphenyl}thiazol-2-yl)isonicotinamide 1438638-83-5 C24H23N5O3S2
    N-(4-{4-[5-(2-methoxyethoxy)pyrazin-2-ylthio]-2,6-dimethylphenyl}thiazol-2-yl)isonicotinamide
    —— 2-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-23-4 C19H21NO5S
    2-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 2-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-32-5 C18H19NO5S
    2-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— N,N-Diethyl-2-(phenylthio)benzylamine maleate 127876-74-8 C21H25NO4S
    N,N-Diethyl-2-(phenylthio)benzylamine maleate
    —— N,N-Dimethyl-2-(2-(phenylthio)phenyl)ethylamine maleate 127876-80-6 C20H23NO4S
    N,N-Dimethyl-2-(2-(phenylthio)phenyl)ethylamine maleate
    —— 3,3-dimethoxyspirothiirane-2,2'-tricyclo[3.3.1.13.7]decane 359415-97-7 C13H20O2S
    3,3-dimethoxyspirothiirane-2,2'-tricyclo[3.3.1.13.7]decane
    —— N-Methyl-2-(2,4-dimethoxyphenylthio)benzylamine maleate 127905-88-8 C20H23NO6S
    N-Methyl-2-(2,4-dimethoxyphenylthio)benzylamine maleate
    —— 4-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-39-2 C18H19NO5S
    4-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 2-((2,5-Dimethoxyphenyl)thio)-N,N-dimethylbenzenemethanamine (Z)-2-butenedioate (1:1) 127905-79-7 C21H25NO6S
    2-((2,5-Dimethoxyphenyl)thio)-N,N-dimethylbenzenemethanamine (Z)-2-butenedioate (1:1)
    —— N,N-Dimethyl-1-(2-(phenylthio)phenyl)-2-propylamine maleate 127876-86-2 C21H25NO4S
    N,N-Dimethyl-1-(2-(phenylthio)phenyl)-2-propylamine maleate
    —— 2-((2-(Aminomethyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-50-7 C17H17NO5S
    2-((2-(Aminomethyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 1-((2-(Phenylthio)phenyl)methyl)pyrrolidine (Z)-2-butenedioate (1:1) 127876-75-9 C21H23NO4S
    1-((2-(Phenylthio)phenyl)methyl)pyrrolidine (Z)-2-butenedioate (1:1)
    —— 4-((2-((Methylamino)methyl)phenyl)thio)-1,2-benzenediol (Z)-2-butenedioate (1:1) (salt) 127906-42-7 C18H19NO6S
    4-((2-((Methylamino)methyl)phenyl)thio)-1,2-benzenediol (Z)-2-butenedioate (1:1) (salt)
    —— N,N-Dimethyl-2-(2,4-dimethoxyphenylthio)benzylamine 127905-76-4 C21H25NO6S
    N,N-Dimethyl-2-(2,4-dimethoxyphenylthio)benzylamine
    —— N,N-Dimethyl-2-(phenylthio)benzylamine maleate 127876-73-7 C19H21NO4S
    N,N-Dimethyl-2-(phenylthio)benzylamine maleate
    —— (Z)-2-tert-butylsulfanyl-4-methoxynon-2-ene 88909-73-3 C14H28OS
    (Z)-2-tert-butylsulfanyl-4-methoxynon-2-ene
    —— 8-(6-(1H-pyrazol-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine 1289543-91-4 C21H24N8O2S
    8-(6-(1H-pyrazol-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine
    —— 6-methyl-2-(methylthio)-N-(tetrahydrofuran-3-yl)pyrimidin-4-amine 1071977-16-6 C10H15N3OS
    6-methyl-2-(methylthio)-N-(tetrahydrofuran-3-yl)pyrimidin-4-amine
    —— 8-(6-(1H-pyrazol-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine 1289544-13-3 C22H26N8O2S
    8-(6-(1H-pyrazol-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine
    —— 6-methyl-2-methylsulfanyl-pyrimidine-4-carbonitrile 65735-62-8 C7H7N3S
    6-methyl-2-methylsulfanyl-pyrimidine-4-carbonitrile
    —— 4-N,N-di-n-propylamino-6-methyl-2-methylthiopyrimidine 111697-14-4 C12H21N3S
    4-N,N-di-n-propylamino-6-methyl-2-methylthiopyrimidine
    —— 1-(5-amino-2-chloro-4-fluoro-phenylthio)-cyclopropanecarboxylic acid 140909-31-5 C10H9ClFNO2S
    1-(5-amino-2-chloro-4-fluoro-phenylthio)-cyclopropanecarboxylic acid
    —— 3-(6-methyl-2-methylsulfanyl-pyrimidin-4-yl)-bicyclo[3.2.1]octane-2.4-dione 1111805-45-8 C14H16N2O2S
    3-(6-methyl-2-methylsulfanyl-pyrimidin-4-yl)-bicyclo[3.2.1]octane-2.4-dione
    —— 2-Methylmercapto-4-ethoxy-6-methyl-pyrimidin 7749-53-3 C8H12N2OS
    2-Methylmercapto-4-ethoxy-6-methyl-pyrimidin
    —— 4-benzylamino-6-methyl-2-methylthiopyrimidine 109389-09-5 C13H15N3S
    4-benzylamino-6-methyl-2-methylthiopyrimidine
    —— 2-(Methylthio)-6-methyl-pyrimidin-thiol-(4) 6310-04-9 C6H8N2S2
    2-(Methylthio)-6-methyl-pyrimidin-thiol-(4)
    —— N-isopropyl-6-methyl-2-(methylthio)pyrimidin-4-amine 874791-36-3 C9H15N3S
    N-isopropyl-6-methyl-2-(methylthio)pyrimidin-4-amine
    —— 4-(1-Bromo-2,2-diethoxyethyl)-6-methyl-2-methylsulfanylpyrimidine 874476-61-6 C12H19BrN2O2S
    4-(1-Bromo-2,2-diethoxyethyl)-6-methyl-2-methylsulfanylpyrimidine
    —— 4-N,N-di-n-butylamino-6-methyl-2-methylthiopyrimidine 111697-15-5 C14H25N3S
    4-N,N-di-n-butylamino-6-methyl-2-methylthiopyrimidine
    —— 4-methyl-2-methylthio-6-(2,2,2-trifluoroethylamino)pyrimidine 951153-47-2 C8H10F3N3S
    4-methyl-2-methylthio-6-(2,2,2-trifluoroethylamino)pyrimidine
    —— 4-cycloheptylamino-6-methyl-2-methylsulfanyl-pyrimidin-5-carbaldehyde 869219-81-8 C14H21N3OS
    4-cycloheptylamino-6-methyl-2-methylsulfanyl-pyrimidin-5-carbaldehyde
    —— 4-(1-(5-Bromo-2-(phenylthio)phenyl)ethyl)-1-methylpiperazine bismaleate 112446-64-7 C27H31BrN2O8S
    4-(1-(5-Bromo-2-(phenylthio)phenyl)ethyl)-1-methylpiperazine bismaleate
    —— Piperazine, 4-(1-(5-chloro-2-((3,4-dichlorophenyl)thio)phenyl)ethyl)-1-methyl-, (Z)-2-butenedioate, hydrate (1:2:1) 112446-51-2 C27H29Cl3N2O8S
    Piperazine, 4-(1-(5-chloro-2-((3,4-dichlorophenyl)thio)phenyl)ethyl)-1-methyl-, (Z)-2-butenedioate, hydrate (1:2:1)
    —— 5-(methylthio)thiophene-2-carboximidamide hydrochloride 1621363-56-1 C6H8N2S2*ClH
    5-(methylthio)thiophene-2-carboximidamide hydrochloride
    —— 2-Amino-4-phenylmercapto-6-methyl-pyrimidin 91347-37-4 C11H11N3S
    2-Amino-4-phenylmercapto-6-methyl-pyrimidin
    —— Piperazine, 1-(1-(5-chloro-2-((3,4-dichlorophenyl)thio)phenyl)ethyl)-4-(2-methoxyethyl)-, (Z)-2-butenedioate (1:2) 112446-56-7 C29H33Cl3N2O9S
    Piperazine, 1-(1-(5-chloro-2-((3,4-dichlorophenyl)thio)phenyl)ethyl)-4-(2-methoxyethyl)-, (Z)-2-butenedioate (1:2)
    —— N,2-bis(1-adamantyl)-2-oxoethanethioamide 1187551-52-5 C22H31NOS
    N,2-bis(1-adamantyl)-2-oxoethanethioamide
    —— N-(1-adamantyl)-3,3-dimethyl-2-oxobutanethioamide 1187551-51-4 C16H25NOS
    N-(1-adamantyl)-3,3-dimethyl-2-oxobutanethioamide
    —— (2-(Phenylthio)phenyl)acetamidine maleate 117596-36-8 C18H18N2O4S
    (2-(Phenylthio)phenyl)acetamidine maleate
    —— 4-(1-(5-Chloro-2-((2,5-dichlorophenyl)thio)phenyl)ethyl)-1-piperazineethanol bismaleate 112446-55-6 C28H31Cl3N2O9S
    4-(1-(5-Chloro-2-((2,5-dichlorophenyl)thio)phenyl)ethyl)-1-piperazineethanol bismaleate
    —— 1-Piperazineethanol, 4-(1-imino-2-(2-(phenylthio)phenyl)ethyl)-, (Z)-2-butenedioate (salt), hydrate (1:2:1) 117596-45-9 C28H33N3O9S
    1-Piperazineethanol, 4-(1-imino-2-(2-(phenylthio)phenyl)ethyl)-, (Z)-2-butenedioate (salt), hydrate (1:2:1)
    —— 2-(4-chlorophenyl)sulfanyl-N-methoxy-N-methylpyridine-3-carboxamide 639514-77-5 C14H13ClN2O2S
    2-(4-chlorophenyl)sulfanyl-N-methoxy-N-methylpyridine-3-carboxamide
    —— N-(2-amino-6-methyl-4-pyrimidinyl)-N-[3-fluoro-4-(4-pyridinylsulfanyl)phenyl]amine 570415-01-9 C16H14FN5S
    N-(2-amino-6-methyl-4-pyrimidinyl)-N-[3-fluoro-4-(4-pyridinylsulfanyl)phenyl]amine
    —— 4-(1-(5-Chloro-2-((2,5-dichlorophenyl)thio)phenyl)ethyl)-1-methylpiperazine bismaleate 112462-69-8 C27H29Cl3N2O8S
    4-(1-(5-Chloro-2-((2,5-dichlorophenyl)thio)phenyl)ethyl)-1-methylpiperazine bismaleate
    —— 4-(1-(5-Chloro-2-((2-chlorophenyl)thio)phenyl)ethyl)-1-piperazineethanol bismaleate 112446-53-4 C28H32Cl2N2O9S
    4-(1-(5-Chloro-2-((2-chlorophenyl)thio)phenyl)ethyl)-1-piperazineethanol bismaleate
    —— 3-fluoro-4-(4-pyridinylsulfanyl)aniline 569658-00-0 C11H9FN2S
    3-fluoro-4-(4-pyridinylsulfanyl)aniline