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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4,5-bis(4-(prop-2-ynyloxy)phenylthio)phthalonitrile 1323159-12-1 C26H16N2O2S2
    4,5-bis(4-(prop-2-ynyloxy)phenylthio)phthalonitrile
    —— 4,5-bis(4-(pent-4-ynyloxy)phenylthio)phthalonitrile 1323159-14-3 C30H24N2O2S2
    4,5-bis(4-(pent-4-ynyloxy)phenylthio)phthalonitrile
    —— 4,5-bis(4-(but-3-ynyloxy)phenylthio)phthalonitrile 1323159-13-2 C28H20N2O2S2
    4,5-bis(4-(but-3-ynyloxy)phenylthio)phthalonitrile
    —— N,N-dimethyl-2-(phenylthio)benzamide 31913-95-8 C15H15NOS
    N,N-dimethyl-2-(phenylthio)benzamide
    —— 7-(phenylthio)-1,4-dioxaspiro<4.4>non-6-ene 96227-47-3 C13H14O2S
    7-(phenylthio)-1,4-dioxaspiro<4.4>non-6-ene
    —— 2-chloromethyl-3-methyl-4-(1-methyl-piperidin-3-ylmethylsulfanyl)-pyridine-hydrochloride 251345-05-8 C14H21ClN2S*ClH
    2-chloromethyl-3-methyl-4-(1-methyl-piperidin-3-ylmethylsulfanyl)-pyridine-hydrochloride
    —— 7-(phenylthio)-1,4-dioxaspiro<4.5>decane 96227-52-0 C14H18O2S
    7-(phenylthio)-1,4-dioxaspiro<4.5>decane
    —— 7-(phenylthio)1,4-dioxaspiro[4.4]nonane 96227-51-9 C13H16O2S
    7-(phenylthio)1,4-dioxaspiro[4.4]nonane
    —— 2-ethyl-2-(14,16-dioxaheptadec-5-ynyl)-1,3-dithiane 928030-70-0 C21H38O2S2
    2-ethyl-2-(14,16-dioxaheptadec-5-ynyl)-1,3-dithiane
    —— 7-(3-Phenylsulfanyl-propyl)-1,4-dioxa-spiro[4.4]nonane 200860-53-3 C16H22O2S
    7-(3-Phenylsulfanyl-propyl)-1,4-dioxa-spiro[4.4]nonane
    —— 4-{5-fluoro-3-[4-(1-hydroxyethyl)phenylthio]-phenyl}-4-methoxytetrahydropyran 153714-86-4 C20H23FO3S
    4-{5-fluoro-3-[4-(1-hydroxyethyl)phenylthio]-phenyl}-4-methoxytetrahydropyran
    —— 2-chloromethyl-3-methyl-4-{2-[2-(2,2,2-trifluoro-ethoxy)-ethoxy]-ethylsulfanyl}-pyridine 198200-28-1 C13H17ClF3NO2S
    2-chloromethyl-3-methyl-4-{2-[2-(2,2,2-trifluoro-ethoxy)-ethoxy]-ethylsulfanyl}-pyridine
    —— 4-{2-[2-(2-chloro-ethoxy)-ethoxy]-ethylsulfanyl}-2-chloromethyl-3-methyl-pyridine-hydrochloride 251560-54-0 C13H19Cl2NO2S*ClH
    4-{2-[2-(2-chloro-ethoxy)-ethoxy]-ethylsulfanyl}-2-chloromethyl-3-methyl-pyridine-hydrochloride
    —— (E)-1-(Phenylthio)-4-(2-oxocyclopentyl)-1-butene 155335-83-4 C15H18OS
    (E)-1-(Phenylthio)-4-(2-oxocyclopentyl)-1-butene
    —— 2-[2-cyclohepta-2,4,6-trienyl-1-(4'-(tert-butylthio)phenyl)ethylidene]malononitrile 1430198-65-4 C22H22N2S
    2-[2-cyclohepta-2,4,6-trienyl-1-(4'-(tert-butylthio)phenyl)ethylidene]malononitrile
    —— N-benzyl-2-(phenylthio)-(E)-2-heptenamide 1294896-76-6 C20H23NOS
    N-benzyl-2-(phenylthio)-(E)-2-heptenamide
    —— (Z)-N-benzyl-4,4-di(ethoxycarbonyl)-2-(phenylthio)-2-butenamide 1294896-67-5 C23H25NO5S
    (Z)-N-benzyl-4,4-di(ethoxycarbonyl)-2-(phenylthio)-2-butenamide
    —— N-benzyl-2-(1,3-dioxolan-2-yl)-2-(phenylthio)acetamide 1294897-60-1 C18H19NO3S
    N-benzyl-2-(1,3-dioxolan-2-yl)-2-(phenylthio)acetamide
    —— (Z)-1-(Phenylthio)-4-(2-oxocyclopentyl)-1-butene 155335-81-2 C15H18OS
    (Z)-1-(Phenylthio)-4-(2-oxocyclopentyl)-1-butene
    —— (-)-(2S,3R)-(4E)-2,3-epoxy-6-methyl-4-(phenylsulfonyl)-4-heptene 304881-48-9 C14H18OS
    (-)-(2S,3R)-(4E)-2,3-epoxy-6-methyl-4-(phenylsulfonyl)-4-heptene
    —— (E)-(3,3,3-trifluoro-1-(p-tolylthio)prop-1-enyl)-diisopropylsilane 1147999-67-4 C16H23F3SSi
    (E)-(3,3,3-trifluoro-1-(p-tolylthio)prop-1-enyl)-diisopropylsilane
    —— (E)-(3,3,3-trifluoro-1-(p-tolylthio)prop-1-enyl)trimethylsilane 940881-11-8 C13H17F3SSi
    (E)-(3,3,3-trifluoro-1-(p-tolylthio)prop-1-enyl)trimethylsilane
    —— bis-3-(cyclohex-1-enyl)-2-propynyl sulfide 269717-78-4 C18H22S
    bis-3-(cyclohex-1-enyl)-2-propynyl sulfide
    —— bis(γ-cyclohexenylpropargyl)sulfone 269717-80-8 C18H22O2S
    bis(γ-cyclohexenylpropargyl)sulfone
    —— 1,1-(ethylenedioxy)-1-phenyl-2-(2-methyl-1,3-dithian-2-yl)ethane 144712-27-6 C15H20O2S2
    1,1-(ethylenedioxy)-1-phenyl-2-(2-methyl-1,3-dithian-2-yl)ethane
    —— 3-Benzylsulfanyl-5-cyanomethylsulfanyl-isothiazole-4-carbonitrile 24134-99-4 C13H9N3S3
    3-Benzylsulfanyl-5-cyanomethylsulfanyl-isothiazole-4-carbonitrile
    —— bis-3-(cyclohex-1-enyl)-2-propynyl sulfoxide 269717-79-5 C18H22OS
    bis-3-(cyclohex-1-enyl)-2-propynyl sulfoxide
    —— (3-pyrrolylthio)acetic acid 89597-76-2 C6H7NO2S
    (3-pyrrolylthio)acetic acid
    —— trans-4-(phenylthio)-trans-decahydro-1-naphthalenone 98678-09-2 C16H20OS
    trans-4-(phenylthio)-trans-decahydro-1-naphthalenone
    —— α-Chlorethyl-propylsulfon 1728-91-2 C5H11ClO2S
    α-Chlorethyl-propylsulfon
    —— Potassium; 4-methylsulfanyl-phenolate 37407-34-4 C7H7OS*K
    Potassium; 4-methylsulfanyl-phenolate
    —— [(η6-p-cymene)RuCl(η2-2,6-C5H3N(CH2OP(OC10H6)(μ-S)(C10H6O))2-κP,κP)]Cl 934736-97-7 C57H45ClNO6P2RuS2*Cl
    [(η6-p-cymene)RuCl(η2-2,6-C5H3N(CH2OP(OC10H6)(μ-S)(C10H6O))2-κP,κP)]Cl
    —— (2R,3S)-2-Methyl-3-phenylsulfanyl-heptanethioic acid S-benzyl ester 146405-80-3 C21H26OS2
    (2R,3S)-2-Methyl-3-phenylsulfanyl-heptanethioic acid S-benzyl ester
    —— 5-Methanesulfonyl-bicyclo[2.2.1]hept-2-ene 854211-75-9 C8H12O2S
    5-Methanesulfonyl-bicyclo[2.2.1]hept-2-ene
    —— 1-(methylsulfonyl)nonan-3-one 1354643-02-9 C10H20O3S
    1-(methylsulfonyl)nonan-3-one
    —— (2R,3S)-2-Methyl-3-phenylsulfanyl-heptanoyl chloride 1026130-29-9 C14H19ClOS
    (2R,3S)-2-Methyl-3-phenylsulfanyl-heptanoyl chloride
    —— 2-ethyl-3-methyl-5-(3-methylbut-2-en-2-yl)-4-(phenylthio)furan 1613703-95-9 C18H22OS
    2-ethyl-3-methyl-5-(3-methylbut-2-en-2-yl)-4-(phenylthio)furan
    —— 1-(methylsulfonyl)-2-(phenylthio)ethane 90704-79-3 C9H12O2S2
    1-(methylsulfonyl)-2-(phenylthio)ethane
    —— 1-Chloro-4-methanesulfonyl-butane 53394-82-4 C5H11ClO2S
    1-Chloro-4-methanesulfonyl-butane
    —— 3-Hydroxybutylmethyl sulphone 120695-72-9 C5H12O3S
    3-Hydroxybutylmethyl sulphone
    —— t-Butyl 3-Amino-2,2-dimethyl-3-thioxopropanoate 75235-67-5 C9H17NO2S
    t-Butyl 3-Amino-2,2-dimethyl-3-thioxopropanoate
    —— 5-Bromo-1-phenylsulfanyl-hex-5-en-3-ol 87763-89-1 C12H15BrOS
    5-Bromo-1-phenylsulfanyl-hex-5-en-3-ol
    —— 5-Ethyl-4-(1-hydroxy-3-phenylsulfanyl-propyl)-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid ethyl ester 477842-62-9 C19H28O5S
    5-Ethyl-4-(1-hydroxy-3-phenylsulfanyl-propyl)-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid ethyl ester
    —— 4-(1-Hydroxy-3-phenylsulfanyl-propyl)-5-isopropyl-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid ethyl ester 477842-64-1 C20H30O5S
    4-(1-Hydroxy-3-phenylsulfanyl-propyl)-5-isopropyl-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid ethyl ester
    —— 4-(1-Hydroxy-3-phenylsulfanyl-propyl)-2,2,5,5-tetramethyl-[1,3]dioxolane-4-carboxylic acid ethyl ester 477842-61-8 C19H28O5S
    4-(1-Hydroxy-3-phenylsulfanyl-propyl)-2,2,5,5-tetramethyl-[1,3]dioxolane-4-carboxylic acid ethyl ester
    —— Acetic acid 3-oxo-1-(2-phenylsulfanyl-ethyl)-butyl ester 87763-98-2 C14H18O3S
    Acetic acid 3-oxo-1-(2-phenylsulfanyl-ethyl)-butyl ester
    —— (E)-(S)-4-Hydroxy-5-phenylsulfanyl-pent-2-enenitrile 109574-79-0 C11H11NOS
    (E)-(S)-4-Hydroxy-5-phenylsulfanyl-pent-2-enenitrile
    —— 4-(1-Hydroxy-3-phenylsulfanyl-propyl)-5-isopropyl-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid methyl ester 477842-63-0 C19H28O5S
    4-(1-Hydroxy-3-phenylsulfanyl-propyl)-5-isopropyl-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid methyl ester
    —— 1-{4-[2-(pyrimidin-2-ylsulfanyl)-phenylamino]-piperidin-1-yl}-ethanone 919118-78-8 C17H20N4OS
    1-{4-[2-(pyrimidin-2-ylsulfanyl)-phenylamino]-piperidin-1-yl}-ethanone
    —— 3-[1,3,4]thiadiazol-2-ylsulfanyl-propionic acid methyl ester 69893-96-5 C6H8N2O2S2
    3-[1,3,4]thiadiazol-2-ylsulfanyl-propionic acid methyl ester