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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl 4,6-diethyl-5-(2-bromoethyl)-2-(phenylsulfanyl)-benzoate 1023305-12-5 C20H23BrO2S
    methyl 4,6-diethyl-5-(2-bromoethyl)-2-(phenylsulfanyl)-benzoate
    —— 6-[2-(2-tetrahydropyranyloxy)ethylthio]imidazo[1,2-b]pyridazine 114603-93-9 C13H17N3O2S
    6-[2-(2-tetrahydropyranyloxy)ethylthio]imidazo[1,2-b]pyridazine
    —— 2-allyl-3-<methoxy(phenylthio)(trimethylsilyl)methyl>cyclopentanone 112699-42-0 C19H28O2SSi
    2-allyl-3-<methoxy(phenylthio)(trimethylsilyl)methyl>cyclopentanone
    —— methyl 4,6-dimethyl-5-(2-bromoethyl)-2-(phenylsulfanyl)-benzoate 1023305-11-4 C18H19BrO2S
    methyl 4,6-dimethyl-5-(2-bromoethyl)-2-(phenylsulfanyl)-benzoate
    —— 3-<methoxy(phenylthio)(trimethylsilyl)methyl>-2-methylcyclohexanone 112699-44-2 C18H28O2SSi
    3-<methoxy(phenylthio)(trimethylsilyl)methyl>-2-methylcyclohexanone
    —— 3-<methoxy(phenylthio)(trimethylsilyl)methyl>-2-propargylcyclopentanone 112699-43-1 C19H26O2SSi
    3-<methoxy(phenylthio)(trimethylsilyl)methyl>-2-propargylcyclopentanone
    —— 3-<methoxy(phenylthio)(trimethylsilyl)methyl>-2-methylcyclopentanone 112699-40-8 C17H26O2SSi
    3-<methoxy(phenylthio)(trimethylsilyl)methyl>-2-methylcyclopentanone
    —— 1-Eth-(E)-ylideneamino-2-methylsulfanyl-1H-pyrrole-3,4-dicarboxylic acid dimethyl ester 132397-47-8 C11H14N2O4S
    1-Eth-(E)-ylideneamino-2-methylsulfanyl-1H-pyrrole-3,4-dicarboxylic acid dimethyl ester
    —— methyl 2,3,4,5-tetramethyl-6-(phenylsulfanyl)benzoate 1190219-91-0 C18H20O2S
    methyl 2,3,4,5-tetramethyl-6-(phenylsulfanyl)benzoate
    —— Isopropyldiethylthionocarbamat 49634-93-7 C8H17NOS
    Isopropyldiethylthionocarbamat
    —— 2-(methylsulfanyl)-5H,6H,7H,8H,9H-cyclohepta[d]pyrimidin-5-one 954153-62-9 C10H12N2OS
    2-(methylsulfanyl)-5H,6H,7H,8H,9H-cyclohepta[d]pyrimidin-5-one
    —— 6-cyclohexylthiopyridazin-3-amine 113121-40-7 C10H15N3S
    6-cyclohexylthiopyridazin-3-amine
    —— 6-((4-bromophenyl)sulfanyl)-3-pyridazinamine 1450622-48-6 C10H8BrN3S
    6-((4-bromophenyl)sulfanyl)-3-pyridazinamine
    —— 6-p-fluorophenylthiopyridazin-3-amine 113121-46-3 C10H8FN3S
    6-p-fluorophenylthiopyridazin-3-amine
    —— 6-p-totylthiopyridazin-3-amine 91347-34-1 C11H11N3S
    6-p-totylthiopyridazin-3-amine
    —— 6-Propan-2-ylsulfanylpyridazin-3-amine 1319731-81-1 C7H11N3S
    6-Propan-2-ylsulfanylpyridazin-3-amine
    —— 6-p-dimethylaminophenylthiopyridazin-3-amine 113121-52-1 C12H14N4S
    6-p-dimethylaminophenylthiopyridazin-3-amine
    —— 2-amino-5-<2-(N-methylamino)phenylthio>-4-methylpyrimidine 92608-38-3 C12H14N4S
    2-amino-5-<2-(N-methylamino)phenylthio>-4-methylpyrimidine
    —— 3-chloro-4-[2-[[(1,1-dimethylethoxy)carbonyl]-amino]-ethylthio]benzeneacetic acid methyl ester 393186-02-2 C16H22ClNO4S
    3-chloro-4-[2-[[(1,1-dimethylethoxy)carbonyl]-amino]-ethylthio]benzeneacetic acid methyl ester
    —— 9,10-dihydrodi[1,2,3]triazolo[1,5-b:5',1'-f][1,3,6]thiadiazepine 501345-66-0 C6H6N6S
    9,10-dihydrodi[1,2,3]triazolo[1,5-b:5',1'-f][1,3,6]thiadiazepine
    —— 2-methyl-5-(phenylthio)thiophene 1360571-24-9 C11H10S2
    2-methyl-5-(phenylthio)thiophene
    —— 6-methylsulfanyl-imidazo[1,2-<i>b</i>]pyridazine 61582-31-8 C7H7N3S
    6-methylsulfanyl-imidazo[1,2-<i>b</i>]pyridazine
    —— 3-Bromo-5-methyl-2-(methylthio)-thiophene 61074-67-7 C6H7BrS2
    3-Bromo-5-methyl-2-(methylthio)-thiophene
    —— 5-<2-Amino-5-nitrophenyl)thiol>-2-dimethylaminoethyl-4-chlor-(2H)-pyridazinon 65225-75-4 C14H16ClN5O3S
    5-<2-Amino-5-nitrophenyl)thiol>-2-dimethylaminoethyl-4-chlor-(2H)-pyridazinon
    —— (2E)-Methyl 2-<(E)-4'-tert-Butyldimethylsiloxy-1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>penta-2',4'-dienyloxymethyl>-3-<dimethyl(phenyl)silyl>propenoate 145746-12-9 C32H52O6S2Si2
    (2E)-Methyl 2-<(E)-4'-tert-Butyldimethylsiloxy-1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>penta-2',4'-dienyloxymethyl>-3-<dimethyl(phenyl)silyl>propenoate
    —— (2E)-Methyl 2-<(E)-1'-<2-(2''',2'''-Dimethoxyethyl)-1,3-dithian-2-yl>-4'-oxopent-2-enyloxymethyl>-3-<dimethyl(phenyl)silyl>propenoate 145746-20-9 C26H38O6S2Si
    (2E)-Methyl 2-<(E)-1'-<2-(2''',2'''-Dimethoxyethyl)-1,3-dithian-2-yl>-4'-oxopent-2-enyloxymethyl>-3-<dimethyl(phenyl)silyl>propenoate
    —— ethyl 1-(3-oxo-2,3-dihydrobenzo<b>thiophen-2-yl)imidazole-2-carboxylate 161801-88-3 C14H12N2O3S
    ethyl 1-(3-oxo-2,3-dihydrobenzo<b>thiophen-2-yl)imidazole-2-carboxylate
    —— 9,10-dihydrobis[1,2,3]triazolo[1,5-f:5',1'-b][1,3,6]thiadiazepine-3,5-dicarboxylic acid 651768-95-5 C8H6N6O4S
    9,10-dihydrobis[1,2,3]triazolo[1,5-f:5',1'-b][1,3,6]thiadiazepine-3,5-dicarboxylic acid
    —— (2E)-Methyl 3-<Dimethyl(phenyl)silyl>-2-<(E)-1'-<(2''-formylmethyl)-1'',3''-dithian-2''-yl>-3'-methyl-4'-oxopent-2'-enyloxymethyl>propenoate 145746-27-6 C25H34O5S2Si
    (2E)-Methyl 3-<Dimethyl(phenyl)silyl>-2-<(E)-1'-<(2''-formylmethyl)-1'',3''-dithian-2''-yl>-3'-methyl-4'-oxopent-2'-enyloxymethyl>propenoate
    —— (2E)-Methyl 2-<(E)-1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-4',4'-(ethylenedioxy)-3'-methylpent-2'-enyloxymethyl>-3-<dimethyl(phenyl)silyl>propenoate 145746-26-5 C29H44O7S2Si
    (2E)-Methyl 2-<(E)-1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-4',4'-(ethylenedioxy)-3'-methylpent-2'-enyloxymethyl>-3-<dimethyl(phenyl)silyl>propenoate
    —— 2-bromo-benzo[<i>b</i>]thiophen-3-one 161801-95-2 C8H5BrOS
    2-bromo-benzo[<i>b</i>]thiophen-3-one
    —— 2-hydroxy-methylenebenzo[b]thiophen-3-one 1237727-00-2 C9H6O2S
    2-hydroxy-methylenebenzo[b]thiophen-3-one
    —— 1,1,2-Trifluoro-1-phenylsulfanyl-pentan-3-one 101361-07-3 C11H11F3OS
    1,1,2-Trifluoro-1-phenylsulfanyl-pentan-3-one
    —— 2,3-Dihydro-6-methoxycarbonylaminoimidazo<2,1-b>thiazole 141722-36-3 C7H9N3O2S
    2,3-Dihydro-6-methoxycarbonylaminoimidazo<2,1-b>thiazole
    —— 2-Propenoic acid, 2-cyano-3-(phenylthio)-, ethyl ester 90280-04-9 C12H11NO2S
    2-Propenoic acid, 2-cyano-3-(phenylthio)-, ethyl ester
    —— Thioessigsaeure-(N<sup>2</sup>,N<sup>2</sup>-dimethyl-hydrazid) 89695-58-9 C4H10N2S
    Thioessigsaeure-(N<sup>2</sup>,N<sup>2</sup>-dimethyl-hydrazid)
    —— 5-allylsulfanyl-3<i>H</i>-[1,3,4]thiadiazole-2-thione 19921-53-0 C5H6N2S3
    5-allylsulfanyl-3<i>H</i>-[1,3,4]thiadiazole-2-thione
    —— 2,5-Bis(2'-((2''-(di methylamino)ethyl)thio)-5'-methylpyrimidin-4'-yl)thiophene 131407-82-4 C22H30N6S3
    2,5-Bis(2'-((2''-(di methylamino)ethyl)thio)-5'-methylpyrimidin-4'-yl)thiophene
    —— 5,5-dimethyl-4-[(trimethylsilyl)oxy]-4-(2-phenylethyl)-2-phenylthio-tetrahydrofuran 249766-64-1 C23H32O2SSi
    5,5-dimethyl-4-[(trimethylsilyl)oxy]-4-(2-phenylethyl)-2-phenylthio-tetrahydrofuran
    —— bis[(E)-1-(chloromethyl)-2-chlorovinyl]sulfide 1360444-66-1 C6H6Cl4S
    bis[(E)-1-(chloromethyl)-2-chlorovinyl]sulfide
    —— 4-Oxo-3-phenylsulfanyl-cyclohexanecarboxylic acid methyl ester 121810-16-0 C14H16O3S
    4-Oxo-3-phenylsulfanyl-cyclohexanecarboxylic acid methyl ester
    —— 5-Hydroxymethyl-4,6-dimethyl-2-methylsulfanyl-nicotinonitrile 113859-05-5 C10H12N2OS
    5-Hydroxymethyl-4,6-dimethyl-2-methylsulfanyl-nicotinonitrile
    —— 5-Methoxymethoxymethyl-4,6-dimethyl-2-methylsulfanyl-nicotinonitrile 113859-11-3 C12H16N2O2S
    5-Methoxymethoxymethyl-4,6-dimethyl-2-methylsulfanyl-nicotinonitrile
    —— (Z)-1-bromo-4-phenyl-1-phenylthio-1-butene 140243-98-7 C16H15BrS
    (Z)-1-bromo-4-phenyl-1-phenylthio-1-butene
    —— 1-Iodo-4-(methylsulfonyl)butane 558465-90-0 C5H11IO2S
    1-Iodo-4-(methylsulfonyl)butane
    —— 1-chloro-4-phenyl-1-phenylthio-1-butene 140243-97-6 C16H15ClS
    1-chloro-4-phenyl-1-phenylthio-1-butene
    —— ethyl 3-(p-toylthio)acrylate 1138-92-7 C12H14O2S
    ethyl 3-(p-toylthio)acrylate
    —— Carbamothioic acid, methyl-, S-decyl ester 92411-96-6 C12H25NOS
    Carbamothioic acid, methyl-, S-decyl ester
    —— 6-Methyl-1-methylsulfanyl-cyclohexene 70871-39-5 C8H14S
    6-Methyl-1-methylsulfanyl-cyclohexene
    —— 3-tert-butoxy-1-isopropyl-2-methylsulfanyl-1H-pyrrole 1247948-23-7 C12H21NOS
    3-tert-butoxy-1-isopropyl-2-methylsulfanyl-1H-pyrrole