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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-methylpropylazanium;N-(2-methylpropyl)carbamodithioate 64221-12-1 C4H11N*C5H11NS2
    2-methylpropylazanium;N-(2-methylpropyl)carbamodithioate
    —— N-(tert-butoxycarbonyl)-4-amino-4-[(methylsulfinyl)methyl]-2,5-cyclohexadienone 1033192-93-6 C13H19NO4S
    N-(tert-butoxycarbonyl)-4-amino-4-[(methylsulfinyl)methyl]-2,5-cyclohexadienone
    —— N-(2-acetamidoethyl)-2-methyl-5-(2-(pyridin-2-ylamino)thiazol-5-ylthio)benzamide 1012060-81-9 C20H21N5O2S2
    N-(2-acetamidoethyl)-2-methyl-5-(2-(pyridin-2-ylamino)thiazol-5-ylthio)benzamide
    —— Methyl-pivaloyl-disulfid 31172-08-4 C6H12OS2
    Methyl-pivaloyl-disulfid
    —— N-(tert-butoxycarbonyl)-4-amino-4-[1'-(ethylsulfonyl)ethyl]-2,5-cyclohexadienone 1033192-96-9 C15H23NO5S
    N-(tert-butoxycarbonyl)-4-amino-4-[1'-(ethylsulfonyl)ethyl]-2,5-cyclohexadienone
    —— 3-(6-chloropyridine-3-yl)-4-(phenylthio)-1H-pyrazol-5(4H)-one 1308248-18-1 C14H10ClN3OS
    3-(6-chloropyridine-3-yl)-4-(phenylthio)-1H-pyrazol-5(4H)-one
    —— (3-Chloro-phenyl)-thiocarbamic acid S-phenyl ester 77499-94-6 C13H10ClNOS
    (3-Chloro-phenyl)-thiocarbamic acid S-phenyl ester
    —— 2-Chlor-5-pyridyl-thiocyanat 41288-93-1 C6H3ClN2S
    2-Chlor-5-pyridyl-thiocyanat
    —— 52670-37-8 C2H7OS
    —— N,N-Dimethyl-α-aminoisobutyrthioamid 107640-47-1 C6H14N2S
    N,N-Dimethyl-α-aminoisobutyrthioamid
    —— 1,3-bis(methylsulfonyl)propane 58313-53-4 C5H12O4S2
    1,3-bis(methylsulfonyl)propane
    —— Butyl-thiocarbamic acid; compound with butylamine 64573-66-6 C4H11N*C5H11NOS
    Butyl-thiocarbamic acid; compound with butylamine
    —— 4,7-dihydroxy-2-phenylsulfanyl-thieno[3,2-c]pyridine-6-carboxylic acid n-butyl ester 909010-74-8 C18H17NO4S2
    4,7-dihydroxy-2-phenylsulfanyl-thieno[3,2-c]pyridine-6-carboxylic acid n-butyl ester
    —— 2-amino-4-(1-methylimidazol-2-ylthio)-1-nitrobenzene 55564-41-5 C10H10N4O2S
    2-amino-4-(1-methylimidazol-2-ylthio)-1-nitrobenzene
    —— Formic acid;phenyl carbamimidothioate 6326-41-6 C8H10N2O2S
    Formic acid;phenyl carbamimidothioate
    —— 4,7-dihydroxy-2-phenylsulfanyl-thieno[2,3-c]pyridine-5-carboxylic acid n-butyl ester 909010-75-9 C18H17NO4S2
    4,7-dihydroxy-2-phenylsulfanyl-thieno[2,3-c]pyridine-5-carboxylic acid n-butyl ester
    —— triphenyl-1,3,5 phenylthio-4 Δ-2 pyrazoline 106584-62-7 C27H22N2S
    triphenyl-1,3,5 phenylthio-4 Δ-2 pyrazoline
    —— 2,4-Bis(propylthio)butanal 130603-69-9 C10H20OS2
    2,4-Bis(propylthio)butanal
    —— 2-amino-4-(imidazol-2-ylthio)-1-nitrobenzene 55564-49-3 C9H8N4O2S
    2-amino-4-(imidazol-2-ylthio)-1-nitrobenzene
    —— 1,1,1-trifluoro-3-(octane-1-sulfonyl)propane-2,2-diol 197774-48-4 C11H21F3O4S
    1,1,1-trifluoro-3-(octane-1-sulfonyl)propane-2,2-diol
    —— 6-(butylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide 494226-38-9 C11H14N4OS
    6-(butylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide
    —— diphenyl-4,6 phenylthio-5 tetrahydro-1,2,3,4 thio-2 pyrimidine 106643-82-7 C22H18N2S2
    diphenyl-4,6 phenylthio-5 tetrahydro-1,2,3,4 thio-2 pyrimidine
    —— diphenyl-3,5 phenylthio-4 Δ-2 pyrazoline 106584-63-8 C21H18N2S
    diphenyl-3,5 phenylthio-4 Δ-2 pyrazoline
    —— N,S-di(4-thiapentyl)-2-amino-5-hydroxy-thiophenol 1416808-91-7 C14H23NOS3
    N,S-di(4-thiapentyl)-2-amino-5-hydroxy-thiophenol
    —— 1,4-Bis-(phenylmercaptomethyl)-piperazin 6326-35-8 C18H22N2S2
    1,4-Bis-(phenylmercaptomethyl)-piperazin
    —— 4-t-Butylthio-2-methylbutanol 62296-23-5 C9H20OS
    4-t-Butylthio-2-methylbutanol
    —— mercuric thiocyanate 879681-01-3 C2HgN2S2
    mercuric thiocyanate
    —— 2,6,6-trimethyl-3-(phenylthio)-6,7-dihydro-1H-indol-4(5H)-one 1219450-38-0 C17H19NOS
    2,6,6-trimethyl-3-(phenylthio)-6,7-dihydro-1H-indol-4(5H)-one
    —— 4'-[2-(4-methoxytetrahydropyran-4-yl)thiazol-5-ylthio]acetophenone ethylene acetal 161386-05-6 C19H23NO4S2
    4'-[2-(4-methoxytetrahydropyran-4-yl)thiazol-5-ylthio]acetophenone ethylene acetal
    —— 4'-[4-bromo-2-(4-methoxytetrahydropyran-4-yl)thiazol-5-ylthio]acetophenone ethylene acetal 161386-07-8 C19H22BrNO4S2
    4'-[4-bromo-2-(4-methoxytetrahydropyran-4-yl)thiazol-5-ylthio]acetophenone ethylene acetal
    —— (3R,5S,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-3-phenylsulfanyl-1-oxa-spiro[4.4]nonan-2-one 629665-88-9 C20H30O3SSi
    (3R,5S,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-3-phenylsulfanyl-1-oxa-spiro[4.4]nonan-2-one
    —— 1-methyl-4,5-bis(phenylthio)-1H-imidazole 1478042-86-2 C16H14N2S2
    1-methyl-4,5-bis(phenylthio)-1H-imidazole
    —— 5-phenyl-2-methylthio-1-p-tolyl-1,6-dihydropyrimidin-6-one 133858-36-3 C18H16N2OS
    5-phenyl-2-methylthio-1-p-tolyl-1,6-dihydropyrimidin-6-one
    —— 5-bromo-2-(isopropylthio)thiazole 1202278-33-8 C6H8BrNS2
    5-bromo-2-(isopropylthio)thiazole
    —— 5-methyl-2-methylsulfanyl-3-p-tolylpyrimidin-4(3H)-one 1262446-29-6 C13H14N2OS
    5-methyl-2-methylsulfanyl-3-p-tolylpyrimidin-4(3H)-one
    —— 2-[(4-methylphenyl)sulfanyl]pyridinium-N-(4-fluorophenyl)imide 569338-71-2 C18H15FN2S
    2-[(4-methylphenyl)sulfanyl]pyridinium-N-(4-fluorophenyl)imide
    —— 5-dimethylamino-2-methylsulfanyl-3-p-tolylpyrimidin-4(3H)-one 1262446-30-9 C14H17N3OS
    5-dimethylamino-2-methylsulfanyl-3-p-tolylpyrimidin-4(3H)-one
    —— (4-bromophenyl)(prop-1-yn-1-yl)sulfane 85143-29-9 C9H7BrS
    (4-bromophenyl)(prop-1-yn-1-yl)sulfane
    —— 4-Phenylthio-pyridin-1-oxid 33421-08-8 C11H9NOS
    4-Phenylthio-pyridin-1-oxid
    —— [4-Tert-butylsulfanyl-1,1-bis(phenylsulfanyl)but-1-en-3-yn-2-yl]sulfanylbenzene 64672-74-8 C26H24S4
    [4-Tert-butylsulfanyl-1,1-bis(phenylsulfanyl)but-1-en-3-yn-2-yl]sulfanylbenzene
    —— N-Phenyl-thiobenzimidic acid phenyl ester 97563-72-9 C19H15NS
    N-Phenyl-thiobenzimidic acid phenyl ester
    —— 4'-[4-(4-methoxytetrahydropyran-4-yl)thien-2-ylthio]acetophenone ethylene acetal 161385-99-5 C20H24O4S2
    4'-[4-(4-methoxytetrahydropyran-4-yl)thien-2-ylthio]acetophenone ethylene acetal
    —— 4'-[2-(4-methoxytetrahydropyran-4-yl)thiazol-4-ylthio]acetophenone ethylene acetal 161386-09-0 C19H23NO4S2
    4'-[2-(4-methoxytetrahydropyran-4-yl)thiazol-4-ylthio]acetophenone ethylene acetal
    —— 3-[3-amino-4-(4-hydroxy-phenylsulfanyl)-phenoxymethyl]-benzonitrile 943771-05-9 C20H16N2O2S
    3-[3-amino-4-(4-hydroxy-phenylsulfanyl)-phenoxymethyl]-benzonitrile
    —— 2-(2-Amino-5-cyano-6-methylsulfanyl-pyrimidin-4-ylsulfanyl)-acetamide 114460-79-6 C8H9N5OS2
    2-(2-Amino-5-cyano-6-methylsulfanyl-pyrimidin-4-ylsulfanyl)-acetamide
    —— 4-Methylbenzenesulfonic acid;4-oxopentyl carbamimidothioate 6625-27-0 C13H20N2O4S2
    4-Methylbenzenesulfonic acid;4-oxopentyl carbamimidothioate
    —— Bis-<1,3-dichlor-propyl-(2)>-disulfid 1561-69-9 C6H10Cl4S2
    Bis-<1,3-dichlor-propyl-(2)>-disulfid
    —— chloromethylthiirane-S-monooxide 29027-25-6 C3H5ClOS
    chloromethylthiirane-S-monooxide
    —— <2-(1-propynyl)cyclohepten-1-yl>thioacetic acid 77416-33-2 C12H16O2S
    <2-(1-propynyl)cyclohepten-1-yl>thioacetic acid
    —— O-Ethyl-S-n-isopropyldithiocarbonat 67038-54-4 C6H12OS2
    O-Ethyl-S-n-isopropyldithiocarbonat