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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (Z)-3-(4-Phenylsulfanyl-phenylcarbamoyl)-acrylic acid 106058-28-0 C16H13NO3S
    (Z)-3-(4-Phenylsulfanyl-phenylcarbamoyl)-acrylic acid
    —— 2-(4,5-Dichloro-2-nitro-phenylsulfanyl)-4-methoxy-phenylamine 488085-86-5 C13H10Cl2N2O3S
    2-(4,5-Dichloro-2-nitro-phenylsulfanyl)-4-methoxy-phenylamine
    —— 1,1-Dimethyl-4,4-di-n-propyl-thiosemicarbazid 27827-97-0 C9H21N3S
    1,1-Dimethyl-4,4-di-n-propyl-thiosemicarbazid
    —— (4,4-dideuterio-4-phenylsulfanylbutyl) acetate 109244-30-6 C12H16O2S
    (4,4-dideuterio-4-phenylsulfanylbutyl) acetate
    —— 3-Methyl-4-methylthio-5-phenyl-1,3-thiazol-2-on 53879-40-6 C11H11NOS2
    3-Methyl-4-methylthio-5-phenyl-1,3-thiazol-2-on
    —— 2,4-bis[(1-methyl-1H-imidazol-2-yl)sulfanyl]pyrimidine 96592-00-6 C12H12N6S2
    2,4-bis[(1-methyl-1H-imidazol-2-yl)sulfanyl]pyrimidine
    —— cis-1,2-Bis-<p-tolyl-mercapto>-1,2-dichlor-aethylen 4526-51-6 C16H14Cl2S2
    cis-1,2-Bis-<p-tolyl-mercapto>-1,2-dichlor-aethylen
    —— 6-[2-(4-chloro-6-dimethylamino-[1,3,5]triazin-2-ylamino)-phenylsulfanyl]-tetra-<i>N</i>-methyl-[1,3,5]triazine-2,4-diamine 50829-84-0 C18H23ClN10S
    6-[2-(4-chloro-6-dimethylamino-[1,3,5]triazin-2-ylamino)-phenylsulfanyl]-tetra-<i>N</i>-methyl-[1,3,5]triazine-2,4-diamine
    —— 4-(m-methylphenyl)-1,1,1-tris(phenylthio)butane 111171-83-6 C29H28S3
    4-(m-methylphenyl)-1,1,1-tris(phenylthio)butane
    —— 5-[4-(3-chloro-anilino)-6-(4-chloro-phenylsulfanyl)-[1,3,5]triazin-2-ylamino]-2-hydroxy-benzoic acid 61513-17-5 C22H15Cl2N5O3S
    5-[4-(3-chloro-anilino)-6-(4-chloro-phenylsulfanyl)-[1,3,5]triazin-2-ylamino]-2-hydroxy-benzoic acid
    —— <i>N</i>-hydroxy-6-propylsulfanyl-pyrazine-2-carboximidic acid amide 66533-73-1 C8H12N4OS
    <i>N</i>-hydroxy-6-propylsulfanyl-pyrazine-2-carboximidic acid amide
    —— 2,2-Dibutylmercapto-3,3-dimethyl-butan 408340-70-5 C14H30S2
    2,2-Dibutylmercapto-3,3-dimethyl-butan
    —— 1-Methyl-2-octylsulfanyl-1H-imidazole; hydrobromide 50968-28-0 BrH*C12H22N2S
    1-Methyl-2-octylsulfanyl-1H-imidazole; hydrobromide
    —— 1-(Methylthio)-endo-5-phenyl-4-(trifluoracetyl)-7-oxa-2-thiabicyclo<2.2.1>heptan-3-on 102435-84-7 C14H11F3O3S2
    1-(Methylthio)-endo-5-phenyl-4-(trifluoracetyl)-7-oxa-2-thiabicyclo<2.2.1>heptan-3-on
    —— 5,5'-diamino-2,2'-sulfanediyl-di-phenol; dihydrochloride 108651-18-9 C12H12N2O2S*2ClH
    5,5'-diamino-2,2'-sulfanediyl-di-phenol; dihydrochloride
    —— [4-Fluoro-2-(4-methylsulfanyl-phenylsulfanyl)-phenyl]-methanol 58913-05-6 C14H13FOS2
    [4-Fluoro-2-(4-methylsulfanyl-phenylsulfanyl)-phenyl]-methanol
    —— Acetic acid (2R,3S,6R)-2-acetoxymethyl-6-phenylsulfanylethynyl-tetrahydro-pyran-3-yl ester 167107-94-0 C18H20O5S
    Acetic acid (2R,3S,6R)-2-acetoxymethyl-6-phenylsulfanylethynyl-tetrahydro-pyran-3-yl ester
    —— 5-nitro-4-(pyrimidin-2-ylthio)-2H-benzimidazole-2-spirocyclohexane 141421-42-3 C16H15N5O2S
    5-nitro-4-(pyrimidin-2-ylthio)-2H-benzimidazole-2-spirocyclohexane
    —— 4-Benzyl-piperazine-1-carboxylic acid 2-phenylsulfanyl-imidazol-1-yl ester 549512-42-7 C21H22N4O2S
    4-Benzyl-piperazine-1-carboxylic acid 2-phenylsulfanyl-imidazol-1-yl ester
    —— 76685-57-9 C25H39NOS2Si
    —— Butyl-(5,5,5-trichlor-pentyl)-sulfid 60303-17-5 C9H17Cl3S
    Butyl-(5,5,5-trichlor-pentyl)-sulfid
    —— 3-[6-chloro-5-fluoro-2-methyl-1-(1-propyl-1H-pyrazol-4-yl)-1H-indol-3-ylsulfanyl]-benzoic acid 1359982-63-0 C22H19ClFN3O2S
    3-[6-chloro-5-fluoro-2-methyl-1-(1-propyl-1H-pyrazol-4-yl)-1H-indol-3-ylsulfanyl]-benzoic acid
    —— 3-[6-chloro-1-(1-ethyl-1H-pyrazol-4-yl)-2-methyl-1H-indol-3-ylsulfanyl]-benzoic acid ethyl ester 1359980-68-9 C23H22ClN3O2S
    3-[6-chloro-1-(1-ethyl-1H-pyrazol-4-yl)-2-methyl-1H-indol-3-ylsulfanyl]-benzoic acid ethyl ester
    —— [1,3]Dithiolo[4,5-d]-1,3-dithiolone, (1-ethylpropylidene)- 144028-63-7 C9H10OS4
    [1,3]Dithiolo[4,5-d]-1,3-dithiolone, (1-ethylpropylidene)-
    —— [4-chloro-2-(4-chloro-1H-indol-3-ylsulfanyl)-benzyl]-methyl-amine 857499-63-9 C16H14Cl2N2S
    [4-chloro-2-(4-chloro-1H-indol-3-ylsulfanyl)-benzyl]-methyl-amine
    —— (6aR,8R,9S,9aR)-2,2,4,4-tetraisopropyl-8-(p-tolylthio)tetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocin-9-yl 4-oxopentanoate 1373616-47-7 C29H48O7SSi2
    (6aR,8R,9S,9aR)-2,2,4,4-tetraisopropyl-8-(p-tolylthio)tetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocin-9-yl 4-oxopentanoate
    —— 2-(7-Chloro-benzo[1,2,4]triazin-3-ylsulfanyl)-1-morpholin-4-yl-ethanone 75122-20-2 C13H13ClN4O2S
    2-(7-Chloro-benzo[1,2,4]triazin-3-ylsulfanyl)-1-morpholin-4-yl-ethanone
    —— 2-(3-bromo-3-phenylallyl)-1-(phenylsulfonyl)-3-(phenylthio)-1H-indole 1372674-49-1 C29H22BrNO2S2
    2-(3-bromo-3-phenylallyl)-1-(phenylsulfonyl)-3-(phenylthio)-1H-indole
    —— 1,1-bis-ethylsulfanyl-2-fluoro-2-methoxy-ethene 70387-19-8 C7H13FOS2
    1,1-bis-ethylsulfanyl-2-fluoro-2-methoxy-ethene
    —— 2-((E)-2-(thiophen-2-yl)vinylthio)-5-bromophenol 1381775-74-1 C12H9BrOS2
    2-((E)-2-(thiophen-2-yl)vinylthio)-5-bromophenol
    —— 55595-83-0 C16H24O2S
    —— [1-(Bis-phenylsulfanyl-methyl)-allyloxy]-tert-butyl-dimethyl-silane 119496-07-0 C22H30OS2Si
    [1-(Bis-phenylsulfanyl-methyl)-allyloxy]-tert-butyl-dimethyl-silane
    —— 57599-00-5 C2H5NOS2*C6H15N
    —— 5-[2-(4-chlorophenylsulfanyl)-2,2-difluoro-ethyl]-dihydro-furan-2-one 1016166-69-0 C12H11ClF2O2S
    5-[2-(4-chlorophenylsulfanyl)-2,2-difluoro-ethyl]-dihydro-furan-2-one
    —— 4-chlorophenyl 3-(4-chlorophenylthio)-2-methyl-N-phenyl-2-propenimidothioate 1154680-11-1 C22H17Cl2NS2
    4-chlorophenyl 3-(4-chlorophenylthio)-2-methyl-N-phenyl-2-propenimidothioate
    —— 4,5-dichloro-<i>N</i>-[3-chloro-4-(chloro-difluoro-methylsulfanyl)-phenyl]-1<i>H</i>-imidazole-2-carboximidic acid 2,6-dichloro-anilide 65812-33-1 C17H8Cl6F2N4S
    4,5-dichloro-<i>N</i>-[3-chloro-4-(chloro-difluoro-methylsulfanyl)-phenyl]-1<i>H</i>-imidazole-2-carboximidic acid 2,6-dichloro-anilide
    —— p-Tolyl-N,N-diaethyl-thiocarbamoyl-trithiocarbonat 19378-35-9 C13H17NS4
    p-Tolyl-N,N-diaethyl-thiocarbamoyl-trithiocarbonat
    —— O,S-Dimethyl-N-4-chlorphenylthiophosphoramidothionat 40186-47-8 C10H15ClNO2PS2
    O,S-Dimethyl-N-4-chlorphenylthiophosphoramidothionat
    —— 134827-02-4 C28H35NO5S2
    —— ((2-chlorophenyl)methylene)bis(phenylsulfane) 1190588-99-8 C19H15ClS2
    ((2-chlorophenyl)methylene)bis(phenylsulfane)
    —— 1-(3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl)-3-(3-(morpholinomethyl)-5-(trifluoromethyl)phenyl)urea 1188909-92-3 C29H28F3N5O4S
    1-(3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl)-3-(3-(morpholinomethyl)-5-(trifluoromethyl)phenyl)urea
    —— 2-methyl-4-phenyl-5-<i>p</i>-tolylmercapto-thiazole 109696-60-8 C17H15NS2
    2-methyl-4-phenyl-5-<i>p</i>-tolylmercapto-thiazole
    —— 6-methylthio-3,5-diphenyl-as-triazine 129190-80-3 C16H13N3S
    6-methylthio-3,5-diphenyl-as-triazine
    —— 2-(2-chlorophenylthio)-6-allylphenol 80002-78-4 C15H13ClOS
    2-(2-chlorophenylthio)-6-allylphenol
    —— 3-Hydroxy-3-phenyl-2-phenylsulfanylmethyl-propionic acid methyl ester 71546-18-4 C17H18O3S
    3-Hydroxy-3-phenyl-2-phenylsulfanylmethyl-propionic acid methyl ester
    —— 2-bromophenyl pentafluorophenylmethyl sulfide 1330062-46-8 C13H6BrF5S
    2-bromophenyl pentafluorophenylmethyl sulfide
    —— 2-[2-hydroxy-3-(o-tolylthio)phenyl]acetic acid 80003-34-5 C15H14O3S
    2-[2-hydroxy-3-(o-tolylthio)phenyl]acetic acid
    —— (Z)-1-diethylamino-1-ethylthio-4-methyl-1,3-pentadiene 87148-30-9 C12H23NS
    (Z)-1-diethylamino-1-ethylthio-4-methyl-1,3-pentadiene
    —— endo,endo-5-(Phenylthio)tricyclo<2.2.0.02,6>hexan-3-ol 93099-29-7 C12H12OS
    endo,endo-5-(Phenylthio)tricyclo<2.2.0.02,6>hexan-3-ol
    —— 1,4-bis-carbamimidoylmercapto-but-2<i>t</i>-ene; dihydrochloride 60784-24-9 C6H12N4S2*2ClH
    1,4-bis-carbamimidoylmercapto-but-2<i>t</i>-ene; dihydrochloride