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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Thiocarbamidsaeure-S-chlormethylester 91571-79-8 C2H4ClNOS
    Thiocarbamidsaeure-S-chlormethylester
    —— Isopropyl-(3-phenylsulfanylmethyl-pyridin-2-yl)-amine 128271-34-1 C15H18N2S
    Isopropyl-(3-phenylsulfanylmethyl-pyridin-2-yl)-amine
    —— 3-Ethoxy-5-phenylsulfanyl-pent-4-ynethioic acid S-ethyl ester 181587-54-2 C15H18O2S2
    3-Ethoxy-5-phenylsulfanyl-pent-4-ynethioic acid S-ethyl ester
    —— methyl (4-methyl-2-methylthio-3-thienyl) ketone 74597-86-7 C8H10OS2
    methyl (4-methyl-2-methylthio-3-thienyl) ketone
    —— 4H-1,2,4-Triazol-3-amine, 4-[(4-chlorophenyl)methyl]-5-(methylthio)- 87866-41-9 C10H11ClN4S
    4H-1,2,4-Triazol-3-amine, 4-[(4-chlorophenyl)methyl]-5-(methylthio)-
    —— 5-Hexylsulfanyl-4H-[1,2,4]triazol-3-ylamine 100599-71-1 C8H16N4S
    5-Hexylsulfanyl-4H-[1,2,4]triazol-3-ylamine
    —— 3-(2-phenylsulfanyl-ethyl)-sydnone 53492-48-1 C10H10N2O2S
    3-(2-phenylsulfanyl-ethyl)-sydnone
    —— 2,4,6-trimethylphenyl 2,4,6-trimethyldithiobenzoate 56010-66-3 C19H22S2
    2,4,6-trimethylphenyl 2,4,6-trimethyldithiobenzoate
    —— Ethyl methanesulphonyl difluoroacetate 219866-73-6 C5H8F2O4S
    Ethyl methanesulphonyl difluoroacetate
    —— [2,2-bis(phenylthio)ethyl]dimethyl(1-nonylbut-3-enyloxy)silane 332188-13-3 C29H44OS2Si
    [2,2-bis(phenylthio)ethyl]dimethyl(1-nonylbut-3-enyloxy)silane
    —— O,o-diethyl-S-[(2,2-dimethyl-1,3-dithiolan-4-yl)-methyl]-phosphorothioate 35128-22-4 C10H21O3PS3
    O,o-diethyl-S-[(2,2-dimethyl-1,3-dithiolan-4-yl)-methyl]-phosphorothioate
    —— <i>O</i>-(2-mercapto-ethyl)-hydroxylamine; hydrochloride 1071-80-3 C2H7NOS*ClH
    <i>O</i>-(2-mercapto-ethyl)-hydroxylamine; hydrochloride
    —— S-Ethyl-N-ethyl-isothioharnstoff 99988-34-8 C5H12N2S
    S-Ethyl-N-ethyl-isothioharnstoff
    —— [5-Fluoro-2-(4-methylsulfanyl-phenylsulfanyl)-phenyl]-acetic acid 54435-44-8 C15H13FO2S2
    [5-Fluoro-2-(4-methylsulfanyl-phenylsulfanyl)-phenyl]-acetic acid
    —— 2-Chloromethyl-4-fluoro-1-(4-methylsulfanyl-phenylsulfanyl)-benzene 54502-21-5 C14H12ClFS2
    2-Chloromethyl-4-fluoro-1-(4-methylsulfanyl-phenylsulfanyl)-benzene
    —— [5-Fluoro-2-(4-methylsulfanyl-phenylsulfanyl)-phenyl]-acetonitrile 54502-22-6 C15H12FNS2
    [5-Fluoro-2-(4-methylsulfanyl-phenylsulfanyl)-phenyl]-acetonitrile
    —— Bis(3-methylthio-1,2,4-thiadiazol-5-ylthio)methane 444791-15-5 C7H8N4S6
    Bis(3-methylthio-1,2,4-thiadiazol-5-ylthio)methane
    —— (4-Cyano-3-methoxycarbonylmethylsulfanyl-isothiazol-5-ylsulfanyl)-acetic acid methyl ester 77729-65-8 C10H10N2O4S3
    (4-Cyano-3-methoxycarbonylmethylsulfanyl-isothiazol-5-ylsulfanyl)-acetic acid methyl ester
    —— 1-(4-Methylsulfanyl-phenyl)-cyclohexylamine 125802-15-5 C13H19NS
    1-(4-Methylsulfanyl-phenyl)-cyclohexylamine
    —— 4-(Imidazolidin-2-ylideneamino)-6-methyl-3-methylsulfanyl-4H-[1,2,4]triazin-5-one 118458-78-9 C8H12N6OS
    4-(Imidazolidin-2-ylideneamino)-6-methyl-3-methylsulfanyl-4H-[1,2,4]triazin-5-one
    —— 1,2-bis(5,7-dihydrodibenzo<b,g>-1,4-thiazocin-6-ylidene)hydrazine 87213-31-8 C28H22N4S2
    1,2-bis(5,7-dihydrodibenzo<b,g>-1,4-thiazocin-6-ylidene)hydrazine
    —— methyl 3-(phenylthio)-2-(phenylthiomethyl)propionate 92806-63-8 C17H18O2S2
    methyl 3-(phenylthio)-2-(phenylthiomethyl)propionate
    —— 4-methyl-7-phenyl-5-phenylthio-5-(trimethylsilyl)heptan-3-one 482358-17-8 C23H32OSSi
    4-methyl-7-phenyl-5-phenylthio-5-(trimethylsilyl)heptan-3-one
    —— (4E,8E)-3,3,10,10-Tetraethyl-3,6,7,10-tetrahydro-[1,2,5,8]dithiadiazecine 108168-02-1 C14H26N2S2
    (4E,8E)-3,3,10,10-Tetraethyl-3,6,7,10-tetrahydro-[1,2,5,8]dithiadiazecine
    —— 5,8-Diaza-3,3,10,10-tetraethyl-1,2-dithiacyclodecane 159982-44-2 C14H30N2S2
    5,8-Diaza-3,3,10,10-tetraethyl-1,2-dithiacyclodecane
    —— 5,9-Diaza-3,3,11,11-tetraethyl-1,2-dithiacycloundecane 159982-45-3 C15H32N2S2
    5,9-Diaza-3,3,11,11-tetraethyl-1,2-dithiacycloundecane
    —— 2,2,5,5-Tetraethyl-3,4-dithiahexane-1,6-diol 159982-41-9 C12H26O2S2
    2,2,5,5-Tetraethyl-3,4-dithiahexane-1,6-diol
    —— (2R,7R,9S,4E)-10-<2'-(4''-hydroxybutyl)-1',3'-dithian-2'-yl>-2,4-dimethyldec-4-ene-1,7,9-triol 152755-17-4 C20H38O4S2
    (2R,7R,9S,4E)-10-<2'-(4''-hydroxybutyl)-1',3'-dithian-2'-yl>-2,4-dimethyldec-4-ene-1,7,9-triol
    —— 6-(indole-2-sulfenyl)-3-methoxypyridazine 463976-05-8 C13H11N3OS
    6-(indole-2-sulfenyl)-3-methoxypyridazine
    —— 3-Methoxy-6-benzylthio-pyridazin 92576-07-3 C12H12N2OS
    3-Methoxy-6-benzylthio-pyridazin
    —— 3-(4-fluoro-phenylsulfanyl)-6-methoxy-pyridazine 454182-08-2 C11H9FN2OS
    3-(4-fluoro-phenylsulfanyl)-6-methoxy-pyridazine
    —— (E)-3-Methyl-5-phenylsulfanyl-pent-2-enoic acid ethyl ester 82353-28-4 C14H18O2S
    (E)-3-Methyl-5-phenylsulfanyl-pent-2-enoic acid ethyl ester
    —— 3-(2-chloro-4-fluoro-phenylsulfanyl)-6-methoxy-pyridazine 454182-07-1 C11H8ClFN2OS
    3-(2-chloro-4-fluoro-phenylsulfanyl)-6-methoxy-pyridazine
    —— (3S,4R,6S)-6-(tert-Butyl-diphenyl-silanyloxy)-3-phenylsulfanyl-hept-1-en-4-ol 754201-18-8 C29H36O2SSi
    (3S,4R,6S)-6-(tert-Butyl-diphenyl-silanyloxy)-3-phenylsulfanyl-hept-1-en-4-ol
    —— 2-(1H-1,2,4-triazol-3-ylsulfanyl)acetamide 24127-93-3 C4H6N4OS
    2-(1H-1,2,4-triazol-3-ylsulfanyl)acetamide
    —— (2-azidophenyl)(phenyl)sulfane 62156-85-8 C12H9N3S
    (2-azidophenyl)(phenyl)sulfane
    —— 4-(1,3-Dioxan-2-yl)-3-(phenylsulfanyl)benzonitrile 1164204-80-1 C17H15NO2S
    4-(1,3-Dioxan-2-yl)-3-(phenylsulfanyl)benzonitrile
    —— (4-ethylamino-5-thiophen-2-ylmethyl-pyrimidin-2-ylsulfanyl)-acetic acid ethyl ester 476302-22-4 C15H19N3O2S2
    (4-ethylamino-5-thiophen-2-ylmethyl-pyrimidin-2-ylsulfanyl)-acetic acid ethyl ester
    —— (4-amino-5-thiophen-2-ylmethyl-pyrimidin-2-ylsulfanyl)-acetic acid ethyl ester 476302-04-2 C13H15N3O2S2
    (4-amino-5-thiophen-2-ylmethyl-pyrimidin-2-ylsulfanyl)-acetic acid ethyl ester
    —— tert-butyl-(2-{(3S)-methyl-(6S)-[2-(4-methylpent-1-enyl)[1,3]dithian-2-ylmethyl]-tetrahydropyran-(2S)-yl}ethoxy)diphenyl-silane 502159-95-7 C35H52O2S2Si
    tert-butyl-(2-{(3S)-methyl-(6S)-[2-(4-methylpent-1-enyl)[1,3]dithian-2-ylmethyl]-tetrahydropyran-(2S)-yl}ethoxy)diphenyl-silane
    —— 2-Allylsulfanyl-6-amino-pyridine-3,5-dicarbonitrile 119022-87-6 C10H8N4S
    2-Allylsulfanyl-6-amino-pyridine-3,5-dicarbonitrile
    —— 4-(4-Bromoanilino)-6-chloro-2-methylsulfanylpyrimidine-5-carbonitrile 171511-22-1 C12H8BrClN4S
    4-(4-Bromoanilino)-6-chloro-2-methylsulfanylpyrimidine-5-carbonitrile
    —— phenyl(1-o-tolylbut-3-enyl)sulfane 1382802-15-4 C17H18S
    phenyl(1-o-tolylbut-3-enyl)sulfane
    —— 6-Phenylsulfanyl-cyclohex-2-enone 88354-73-8 C12H12OS
    6-Phenylsulfanyl-cyclohex-2-enone
    —— (3-Methylene-4-phenylsulfanyl-cyclohexyl)-acetic acid ethyl ester 88354-75-0 C17H22O2S
    (3-Methylene-4-phenylsulfanyl-cyclohexyl)-acetic acid ethyl ester
    —— (3-Oxo-4-phenylsulfanyl-cyclohexyl)-acetic acid ethyl ester 88354-74-9 C16H20O3S
    (3-Oxo-4-phenylsulfanyl-cyclohexyl)-acetic acid ethyl ester
    —— anti-α-(p-Tolylthio)acetophenone oxime 50314-81-3 C15H15NOS
    anti-α-(p-Tolylthio)acetophenone oxime
    —— Methyl-(2-phenylsulfanyl-1-vinyl-but-3-enyl)-amine 225514-17-0 C13H17NS
    Methyl-(2-phenylsulfanyl-1-vinyl-but-3-enyl)-amine
    —— (E)-6-Phenylsulfanyl-hex-5-enal 66529-66-6 C12H14OS
    (E)-6-Phenylsulfanyl-hex-5-enal
    —— 7-Cyano-8-phenylethyl-3,4-dihydro-2H-pyrimido<2,3-b><1,3>thiazin-6-one 95535-03-8 C16H15N3OS
    7-Cyano-8-phenylethyl-3,4-dihydro-2H-pyrimido<2,3-b><1,3>thiazin-6-one