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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-[[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methylsulfanyl]pyridine 950201-42-0 C18H22BNO2S
    4-[[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methylsulfanyl]pyridine
    —— 2-<(bromomethyl)sulfonyl>cycloheptanone 91586-92-4 C8H13BrO3S
    2-<(bromomethyl)sulfonyl>cycloheptanone
    —— 2-(1-adamantyl)-N-tert-butyl-2-oxoethanethioamide 1187551-50-3 C16H25NOS
    2-(1-adamantyl)-N-tert-butyl-2-oxoethanethioamide
    —— propyl trans-1-propenyl trisulfide 23838-27-9 C6H12S3
    propyl trans-1-propenyl trisulfide
    —— 2-<(chloromethyl)sulfonyl>cycloheptanone 91586-93-5 C8H13ClO3S
    2-<(chloromethyl)sulfonyl>cycloheptanone
    —— S-methyl (E)-1-propenesulfonothioate 117869-74-6 C4H8O2S2
    S-methyl (E)-1-propenesulfonothioate
    —— 2-<4-Chlor-phenylmercapto>-1,1-dimethyl-aethylamin 167762-90-5 C10H14ClNS
    2-<4-Chlor-phenylmercapto>-1,1-dimethyl-aethylamin
    —— 5,6-bis-(n-Propylthio)-1,2,5-thiadiazolo<3,4,-b>pyrazin 55387-83-2 C10H14N4S3
    5,6-bis-(n-Propylthio)-1,2,5-thiadiazolo<3,4,-b>pyrazin
    —— (S)-2-methyl-3-(2-methyl-1,3-dithian-2-yl)propan-1-ol 917767-33-0 C9H18OS2
    (S)-2-methyl-3-(2-methyl-1,3-dithian-2-yl)propan-1-ol
    —— (2S,3R)-2-methyl-1-(2-methyl-1,3-dithian-2-yl)hex-5-en-3-ol 917767-26-1 C12H22OS2
    (2S,3R)-2-methyl-1-(2-methyl-1,3-dithian-2-yl)hex-5-en-3-ol
    —— (S)-2-methyl-3-(2-methyl-1,3-dithian-2-yl)propanal 917767-34-1 C9H16OS2
    (S)-2-methyl-3-(2-methyl-1,3-dithian-2-yl)propanal
    —— 2,5-dimethyl-1,3-oxathiole 81715-46-0 C5H8OS
    2,5-dimethyl-1,3-oxathiole
    —— methyl (2-(4-aminobenzyl)-4,6-bisthiomethylpyrimidin-5-yl)acetate 1134496-87-9 C16H19N3O2S2
    methyl (2-(4-aminobenzyl)-4,6-bisthiomethylpyrimidin-5-yl)acetate
    —— propylidene-dithiobiuret 5333-35-7 C5H9N3S2
    propylidene-dithiobiuret
    —— 4,7-bis-methylsulfanyl-1<i>H</i>-imidazo[4,5-<i>d</i>]pyridazine 98277-49-7 C7H8N4S2
    4,7-bis-methylsulfanyl-1<i>H</i>-imidazo[4,5-<i>d</i>]pyridazine
    —— 2-[[4-Ethyl-5-(2-furyl)-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide 439899-36-2 C10H13N5O2S
    2-[[4-Ethyl-5-(2-furyl)-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide
    —— dithiocarbonic acid <i>O,S</i>-bis-dimethylaminomethyl ester 98433-18-2 C7H16N2OS2
    dithiocarbonic acid <i>O,S</i>-bis-dimethylaminomethyl ester
    —— 1,4-Bis[[4-(4-methylphenyl)sulfanylphenyl]sulfanyl]benzene 1151766-62-9 C32H26S4
    1,4-Bis[[4-(4-methylphenyl)sulfanylphenyl]sulfanyl]benzene
    —— 4-[(4-Methylphenyl)sulfanyl]-2-phenyl-1,3-thiazole 130775-34-7 C16H13NS2
    4-[(4-Methylphenyl)sulfanyl]-2-phenyl-1,3-thiazole
    —— 2-(1H-imidazol-2-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1337932-83-8 C20H19N3O3S
    2-(1H-imidazol-2-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— di-tert-butyl 1-(4-methoxy-2-(methylthio)pyrimidin-5-yl)hydrazine-1,2-dicarboxylate 1441760-89-9 C16H26N4O5S
    di-tert-butyl 1-(4-methoxy-2-(methylthio)pyrimidin-5-yl)hydrazine-1,2-dicarboxylate
    —— (+)-2-(R)-(2-phenylacetyl)-2-ethyl-1,3-dithiane 1-(R)-oxide 175417-33-1 C14H18O2S2
    (+)-2-(R)-(2-phenylacetyl)-2-ethyl-1,3-dithiane 1-(R)-oxide
    —— (+)-2-(R)-(3,3-dimethylbutanoyl)-2-ethyl-1,3-dithiane 1-(R)-oxide 332048-54-1 C12H22O2S2
    (+)-2-(R)-(3,3-dimethylbutanoyl)-2-ethyl-1,3-dithiane 1-(R)-oxide
    —— 4,8-dithia-2,2,6,6,10,10-hexamethylundecane-1,11-ol 147992-52-7 C15H32O2S2
    4,8-dithia-2,2,6,6,10,10-hexamethylundecane-1,11-ol
    —— (1-Ethoxycarbothioylsulfanyl-5,5-dimethyl-4-oxohexyl) 2,2-dimethylpropanoate 517867-29-7 C16H28O4S2
    (1-Ethoxycarbothioylsulfanyl-5,5-dimethyl-4-oxohexyl) 2,2-dimethylpropanoate
    —— tert-butythioketene 54191-76-3 C6H10S
    tert-butythioketene
    —— 1-ethylsulfinyl-3,3-dimethylbut-1-yne 929692-40-0 C8H14OS
    1-ethylsulfinyl-3,3-dimethylbut-1-yne
    —— (3,3-dimethylbut-1-ynylsulfinyl)acetic acid ethyl ester 929692-41-1 C10H16O3S
    (3,3-dimethylbut-1-ynylsulfinyl)acetic acid ethyl ester
    —— thenyl 2-thienyl sulfide 88673-92-1 C9H8S3
    thenyl 2-thienyl sulfide
    —— 2-(thien-2-ylmethylthio)-5-bromopyrimidine 79686-17-2 C9H7BrN2S2
    2-(thien-2-ylmethylthio)-5-bromopyrimidine
    —— 1H-Imidazol-2-amine, 4,5-dihydro-N-[4-[(3-methoxyphenyl)thio]phenyl]- 677343-41-8 C16H17N3OS
    1H-Imidazol-2-amine, 4,5-dihydro-N-[4-[(3-methoxyphenyl)thio]phenyl]-
    —— 2-allylthio-5-isopropyl-6-(thien-2-ylmethyl)-pyrimidin-4(3H)-one 261900-03-2 C15H18N2OS2
    2-allylthio-5-isopropyl-6-(thien-2-ylmethyl)-pyrimidin-4(3H)-one
    —— S-<2-(trimethylsilyl)phenyl> N,N-diethylthiocarbamate 141079-75-6 C14H23NOSSi
    S-<2-(trimethylsilyl)phenyl> N,N-diethylthiocarbamate
    —— tetra-isopropylthiourea 81236-06-8 C13H28N2S
    tetra-isopropylthiourea
    —— N-(6-amino-2-((4,6-dimethoxy-2-(piperidin-1-yl)pyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-43-6 C18H23N7O3S
    N-(6-amino-2-((4,6-dimethoxy-2-(piperidin-1-yl)pyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— N-(2-((4,6-dimethoxy-2-morpholinopyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-73-2 C17H20N6O4S
    N-(2-((4,6-dimethoxy-2-morpholinopyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— N-(2-((2-amino-4,6-dimethoxypyrimidin-5-yl)thio)pyrimidin-4-yl)acetamide 1268274-63-0 C12H14N6O3S
    N-(2-((2-amino-4,6-dimethoxypyrimidin-5-yl)thio)pyrimidin-4-yl)acetamide
    —— N-(2-((4,6-dimethoxy-2-(pyrrolidin-1-yl)pyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-74-3 C17H20N6O3S
    N-(2-((4,6-dimethoxy-2-(pyrrolidin-1-yl)pyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— N-(6-amino-2-((4,6-dimethoxy-2-morpholinopyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-42-5 C17H21N7O4S
    N-(6-amino-2-((4,6-dimethoxy-2-morpholinopyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— N-(2-((4,6-dimethoxy-2-(piperidin-1-yl)pyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-72-1 C18H22N6O3S
    N-(2-((4,6-dimethoxy-2-(piperidin-1-yl)pyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— N-(2-((2,4,6-trimethoxypyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-76-5 C14H15N5O4S
    N-(2-((2,4,6-trimethoxypyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— N-(6-amino-2-((2-amino-4,6-dimethoxypyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-58-3 C13H15N7O3S
    N-(6-amino-2-((2-amino-4,6-dimethoxypyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— N-(2-((2-fluoro-4,6-dimethoxypyrimidin-5-yl)thio)pyrimidin-4-yl)acetamide 1268273-58-0 C12H12FN5O3S
    N-(2-((2-fluoro-4,6-dimethoxypyrimidin-5-yl)thio)pyrimidin-4-yl)acetamide
    —— 1-[(Z)-but-2-enyl]sulfanyl-6-[(E)-but-2-enyl]sulfanylhexane 7142-83-8 C14H26S2
    1-[(Z)-but-2-enyl]sulfanyl-6-[(E)-but-2-enyl]sulfanylhexane
    —— 2-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-6-[(2-hydroxyethyl)amino]-4-(1H-pyrazol-3-yl)pyridine-3,5-dicarbonitrile 1187543-24-3 C22H16ClN7OS2
    2-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-6-[(2-hydroxyethyl)amino]-4-(1H-pyrazol-3-yl)pyridine-3,5-dicarbonitrile
    —— 4-methoxy-7-methyl-2-methylsulfanyl-1(3)<i>H</i>-imidazo[4,5-<i>d</i>]pyridazine 91725-04-1 C8H10N4OS
    4-methoxy-7-methyl-2-methylsulfanyl-1(3)<i>H</i>-imidazo[4,5-<i>d</i>]pyridazine
    —— O-(phenylthio)phenyl N,N-diethylthiocarbamate 141079-59-6 C17H19NOS2
    O-(phenylthio)phenyl N,N-diethylthiocarbamate
    —— 2-amino-5-[[(5-ethyl-2-oxazolyl)methyl]thio]-thiazole 224435-07-8 C9H11N3OS2
    2-amino-5-[[(5-ethyl-2-oxazolyl)methyl]thio]-thiazole
    —— S-<2-(phenylthio)phenyl> N,N-diethylthiocarbamate 141079-73-4 C17H19NOS2
    S-<2-(phenylthio)phenyl> N,N-diethylthiocarbamate
    —— 2-chloro-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4-(1H-pyrazol-3-yl)pyridine-3,5-dicarbonitrile 1163271-63-3 C20H10Cl2N6S2
    2-chloro-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4-(1H-pyrazol-3-yl)pyridine-3,5-dicarbonitrile