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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-fluoro-propane-1-thiol 462-44-2 C3H7FS
    3-fluoro-propane-1-thiol
    —— 1,3-dichloro-1-(phenylthio)propane 52072-18-1 C9H10Cl2S
    1,3-dichloro-1-(phenylthio)propane
    —— 3-(phenylthio)-3-methoxypropene 38307-39-0 C10H12OS
    3-(phenylthio)-3-methoxypropene
    —— 5-fluoro-pentane-1-thiol 592-81-4 C5H11FS
    5-fluoro-pentane-1-thiol
    —— ethyl 3-(phenylsulfanyl)-6-(pyridin-3-ylmethoxy)benzo[b]thiophene-2-carboxylate 227103-94-8 C23H19NO3S2
    ethyl 3-(phenylsulfanyl)-6-(pyridin-3-ylmethoxy)benzo[b]thiophene-2-carboxylate
    —— 1-(11-bromo-undecylsulfanyl)dodecane 361484-08-4 C23H47BrS
    1-(11-bromo-undecylsulfanyl)dodecane
    —— 2-methylthiocarbohydrazide 106745-61-3 C2H8N4S
    2-methylthiocarbohydrazide
    —— 4-(3-isopropylsulfanylphenyl)-1,2,3,6-tetrahydropyridine 1430328-31-6 C14H19NS
    4-(3-isopropylsulfanylphenyl)-1,2,3,6-tetrahydropyridine
    —— 3-amino-2-chloro-6-methyl-4-(methylthio)pyridine 182256-64-0 C7H9ClN2S
    3-amino-2-chloro-6-methyl-4-(methylthio)pyridine
    —— N-<1-(N,N-Dimethylthiocarbamoyl)-1,2-dimethylpropyl>acetamid 107640-42-6 C10H20N2OS
    N-<1-(N,N-Dimethylthiocarbamoyl)-1,2-dimethylpropyl>acetamid
    —— dimethyl 2-phenylthiomethylenemalonate 85891-12-9 C13H14O4S
    dimethyl 2-phenylthiomethylenemalonate
    —— 1,1'-(2-(phenylthio)ethane-1,1-diyl)-bis(3,5-dimethyl-1H-pyrazole) 1292840-76-6 C18H22N4S
    1,1'-(2-(phenylthio)ethane-1,1-diyl)-bis(3,5-dimethyl-1H-pyrazole)
    —— 1,1'-(2-(phenylthio)ethane-1,1-diyl)-bis(3,5-diisopropyl-1H-pyrazole) 1292840-77-7 C26H38N4S
    1,1'-(2-(phenylthio)ethane-1,1-diyl)-bis(3,5-diisopropyl-1H-pyrazole)
    —— Thiophenoxythioessigsaeure-S-aethylester 29279-23-0 C10H12OS2
    Thiophenoxythioessigsaeure-S-aethylester
    —— 3-amino-2-methoxy-6-methyl-4-(methylthio)pyridine 179057-06-8 C8H12N2OS
    3-amino-2-methoxy-6-methyl-4-(methylthio)pyridine
    —— 2-methoxy-6-methyl-4-(methylthio)-3-nitropyridine 179056-93-0 C8H10N2O3S
    2-methoxy-6-methyl-4-(methylthio)-3-nitropyridine
    —— methyl 3-deoxy-5,6-O-isopropylidene-3-p-tolylthio-β-D-galactofuranoside 1375486-74-0 C17H24O5S
    methyl 3-deoxy-5,6-O-isopropylidene-3-p-tolylthio-β-D-galactofuranoside
    —— bis(2-methyltetrahydrofuryl-2)sulfide 62308-51-4 C10H18O2S
    bis(2-methyltetrahydrofuryl-2)sulfide
    —— chloro 1,3,3-trichloro-2,2,4,4-tetramethycyclobutyl disulfide 872880-23-4 C8H12Cl4S2
    chloro 1,3,3-trichloro-2,2,4,4-tetramethycyclobutyl disulfide
    —— bis(1,3,3-trichloro-2,2,4,4-tetramethycyclobutyl) trisulfide 872880-25-6 C16H24Cl6S3
    bis(1,3,3-trichloro-2,2,4,4-tetramethycyclobutyl) trisulfide
    —— 2,2-Bis(ethylsulfanyl)-4-(fluoromethylidene)-1,1,3,3-tetramethylcyclobutane 217805-13-5 C13H23FS2
    2,2-Bis(ethylsulfanyl)-4-(fluoromethylidene)-1,1,3,3-tetramethylcyclobutane
    —— 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-isothiocyanatomethylsulfanyl-decane 177326-46-4 C12H6F17NS2
    1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-isothiocyanatomethylsulfanyl-decane
    —— bis(1,3,3-trichloro-2,2,4,4-tetramethycyclobutyl) pentasulfide 872880-26-7 C16H24Cl6S5
    bis(1,3,3-trichloro-2,2,4,4-tetramethycyclobutyl) pentasulfide
    —— 1-<3-(4-hydroxyphenyl)propyl>-2-(methylthio)imidazole 95333-56-5 C13H16N2OS
    1-<3-(4-hydroxyphenyl)propyl>-2-(methylthio)imidazole
    —— N-methyl-3-[(3,3,3-trifluoropropyl)sulphinyl]propan-1-amine 1353009-02-5 C7H14F3NOS
    N-methyl-3-[(3,3,3-trifluoropropyl)sulphinyl]propan-1-amine
    —— 8-methoxy-5-methylthioimidazo<2,1-b><1,3,5>benzothiadiazepine 81382-56-1 C12H11N3OS2
    8-methoxy-5-methylthioimidazo<2,1-b><1,3,5>benzothiadiazepine
    —— 2-methylsulfanyl-3-p-tolyl-5-trifluoromethylpyrimidin-4(3H)-one 1262446-27-4 C13H11F3N2OS
    2-methylsulfanyl-3-p-tolyl-5-trifluoromethylpyrimidin-4(3H)-one
    —— 2-Phenylthio-5-trifluormethylanilin 52548-94-4 C13H10F3NS
    2-Phenylthio-5-trifluormethylanilin
    —— (4-nitro-phenyl)-(2-nitro-4-trifluoromethyl-phenyl)-sulfide 2839-53-4 C13H7F3N2O4S
    (4-nitro-phenyl)-(2-nitro-4-trifluoromethyl-phenyl)-sulfide
    —— 2-(phenylthio)-5-trifluoromethyl-phenylacetonitrile 52549-00-5 C15H10F3NS
    2-(phenylthio)-5-trifluoromethyl-phenylacetonitrile
    —— 1-<2-(2-imidazolyl)thio-5-trifluoromethylphenyliminocarbonyl>-4-methylpiperazine 88251-83-6 C16H18F3N5OS
    1-<2-(2-imidazolyl)thio-5-trifluoromethylphenyliminocarbonyl>-4-methylpiperazine
    —— 2-(phenylthio)-5-trifluoromethyl-phenylacetic acid 52549-01-6 C15H11F3O2S
    2-(phenylthio)-5-trifluoromethyl-phenylacetic acid
    —— 2-(phenylthio)-5-trifluoromethyl-benzyl chloride 52548-99-9 C14H10ClF3S
    2-(phenylthio)-5-trifluoromethyl-benzyl chloride
    —— N-cyclopropyl-2-(2,4-dinitro-phenylsulfanyl)-benzamide 950858-16-9 C16H13N3O5S
    N-cyclopropyl-2-(2,4-dinitro-phenylsulfanyl)-benzamide
    —— N-[(1-(phenylsulfonyl)-3-(phenylthio)-1H-indol-2-yl)methyl]propanamide 1211088-43-5 C24H22N2O3S2
    N-[(1-(phenylsulfonyl)-3-(phenylthio)-1H-indol-2-yl)methyl]propanamide
    —— methyl 2-(phenylthio)-5-trifluoromethyl-benzoate 52548-97-7 C15H11F3O2S
    methyl 2-(phenylthio)-5-trifluoromethyl-benzoate
    —— 2-(phenylthio)-5-trifluoromethyl-benzyl alcohol 52548-98-8 C14H11F3OS
    2-(phenylthio)-5-trifluoromethyl-benzyl alcohol
    —— 8-methoxyimidazo<2,1-b><1,3,5>benzothiadiazepine-5(6H)-thione 88251-76-7 C11H9N3OS2
    8-methoxyimidazo<2,1-b><1,3,5>benzothiadiazepine-5(6H)-thione
    —— 2-(2-Nitro-4-trifluoromethylphenylthio)benzimidazol 60968-23-2 C14H8F3N3O2S
    2-(2-Nitro-4-trifluoromethylphenylthio)benzimidazol
    —— 2-(2-amino-4-trifluoromethylphenylthio)imidazole 88251-71-2 C10H8F3N3S
    2-(2-amino-4-trifluoromethylphenylthio)imidazole
    —— 8-trifluoromethylimidazo<2,1-b><1,3,5>benzothiadiazepine-5(6H)-one 81382-62-9 C11H6F3N3OS
    8-trifluoromethylimidazo<2,1-b><1,3,5>benzothiadiazepine-5(6H)-one
    —— 8-trifluoromethyl-5-(4-methyl-1-piperazinyl)imidazo<2,1-b><1,3,5>benzothiadiazepine 88267-21-4 C16H16F3N5S
    8-trifluoromethyl-5-(4-methyl-1-piperazinyl)imidazo<2,1-b><1,3,5>benzothiadiazepine
    —— 8-methoxy-5-(4-methyl-1-piperazinyl)imidazo<2,1-b><1,3,5>benzothiadiazepine 88251-79-0 C16H19N5OS
    8-methoxy-5-(4-methyl-1-piperazinyl)imidazo<2,1-b><1,3,5>benzothiadiazepine
    —— 2-(2,4-dinitro-phenylsulfanyl)-N-methyl-benzamide 950858-10-3 C14H11N3O5S
    2-(2,4-dinitro-phenylsulfanyl)-N-methyl-benzamide
    —— 2-(2,4-dinitro-phenylsulfanyl)-N-ethyl-benzamide 950858-12-5 C15H13N3O5S
    2-(2,4-dinitro-phenylsulfanyl)-N-ethyl-benzamide
    —— 2-(1H-benzimidazol-2-ylsulfanyl)-5-(trifluoromethyl)aniline 157168-68-8 C14H10F3N3S
    2-(1H-benzimidazol-2-ylsulfanyl)-5-(trifluoromethyl)aniline
    —— N-cyclopentyl-2-(2,4-dinitro-phenylsulfanyl)-benzamide 950858-15-8 C18H17N3O5S
    N-cyclopentyl-2-(2,4-dinitro-phenylsulfanyl)-benzamide
    —— 2-(2,4-dinitro-phenylsulfanyl)-N-propyl-benzamide 950858-14-7 C16H15N3O5S
    2-(2,4-dinitro-phenylsulfanyl)-N-propyl-benzamide
    —— 3-[2-Amino-4-(trifluoromethyl)phenyl]sulfanylthiophene-2-carboxylic acid 104636-65-9 C12H8F3NO2S2
    3-[2-Amino-4-(trifluoromethyl)phenyl]sulfanylthiophene-2-carboxylic acid
    —— 2-(2-nitro-4-trifluoromethylphenylthio)imidazole 88251-66-5 C10H6F3N3O2S
    2-(2-nitro-4-trifluoromethylphenylthio)imidazole