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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— eicosahydro-4a,8a-dimethyl-4,8-bis(phenylthio)-3,7-dioxadicyclopenta<cd,c'd'>pentaleno<2,1,6-hia:5,4,3-h'i'a'>diindene 73953-18-1 C34H38O2S2
    eicosahydro-4a,8a-dimethyl-4,8-bis(phenylthio)-3,7-dioxadicyclopenta<cd,c'd'>pentaleno<2,1,6-hia:5,4,3-h'i'a'>diindene
    —— 2-ethylmercapto-5-ethyl-3-thiophenecarboxaldehyde 14498-99-8 C9H12OS2
    2-ethylmercapto-5-ethyl-3-thiophenecarboxaldehyde
    —— 1-mercapto-1,1-bis(trimethylsilyl)propane-2-thione 1493803-90-9 C9H22S2Si2
    1-mercapto-1,1-bis(trimethylsilyl)propane-2-thione
    —— 2-phenylthio-2-trimethylsilylbutane 85969-74-0 C13H22SSi
    2-phenylthio-2-trimethylsilylbutane
    —— 2,2-Dimethyl-3-(1',1'-dimethylethyl)-hex-5-en-3-thiol 65566-36-1 C12H24S
    2,2-Dimethyl-3-(1',1'-dimethylethyl)-hex-5-en-3-thiol
    —— 1-mercapto-3-methyl-1,1-bis(trimethylsilyl)butane-2-thione 1493803-96-5 C11H26S2Si2
    1-mercapto-3-methyl-1,1-bis(trimethylsilyl)butane-2-thione
    —— 2,5-difluoro-4-(methylsulfanyl)phenylamine 1415731-01-9 C7H7F2NS
    2,5-difluoro-4-(methylsulfanyl)phenylamine
    —— 1-mercapto-1,1-bis(trimethylsilyl)pent-4-ene-2-thione 1493804-10-6 C11H24S2Si2
    1-mercapto-1,1-bis(trimethylsilyl)pent-4-ene-2-thione
    —— 1,4-Benzoxathiin, 1H-imidazole 113698-34-3 C11H12N2OS
    1,4-Benzoxathiin, 1H-imidazole
    —— Phenyl 2,2,3,3,3-pentafluoropropyl sulfide 129264-95-5 C9H7F5S
    Phenyl 2,2,3,3,3-pentafluoropropyl sulfide
    —— 3-[bis(methoxy)methyl]-5-(methylthio)isoxazole 569657-31-4 C7H11NO3S
    3-[bis(methoxy)methyl]-5-(methylthio)isoxazole
    —— 6-Dimethoxymethyl-2-isopropoxy-4-methylsulfanyl-nicotinonitrile 904309-72-4 C13H18N2O3S
    6-Dimethoxymethyl-2-isopropoxy-4-methylsulfanyl-nicotinonitrile
    —— 2-(methylthio)thiophenecarbaldehyde 88511-86-8 C6H6OS2
    2-(methylthio)thiophenecarbaldehyde
    —— prop-2-enyl 2-[[4-(dimethylamino)phenyl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate 6997-61-1 C27H27N3O3S2
    prop-2-enyl 2-[[4-(dimethylamino)phenyl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— Ethyl 2-[(cyclohex-3-en-1-yl)methylidene]-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate 6997-64-4 C24H26N2O3S2
    Ethyl 2-[(cyclohex-3-en-1-yl)methylidene]-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N,N-diethylcarbamodithioic acid (2,2,2-trichloro-1-formamidoethyl) ester 4607-16-3 C8H13Cl3N2OS2
    N,N-diethylcarbamodithioic acid (2,2,2-trichloro-1-formamidoethyl) ester
    —— (2S)-1-[(4S)-4-benzyl-2-sulfanylidene-1,3-oxazolidin-3-yl]-2-[(1R)-1-hydroxy-2-(2-pentyl-1,3-dithian-2-yl)ethyl]octan-1-one 907217-46-3 C29H45NO3S3
    (2S)-1-[(4S)-4-benzyl-2-sulfanylidene-1,3-oxazolidin-3-yl]-2-[(1R)-1-hydroxy-2-(2-pentyl-1,3-dithian-2-yl)ethyl]octan-1-one
    —— 2-((difluoromethyl)thio)-4-methylpyrimidine 129550-03-4 C6H6F2N2S
    2-((difluoromethyl)thio)-4-methylpyrimidine
    —— 3-ethylsulfanyl-5-(trifluoromethyl)pyridine-2-carbonitrile 1421952-04-6 C9H7F3N2S
    3-ethylsulfanyl-5-(trifluoromethyl)pyridine-2-carbonitrile
    —— 1-[(E)-1-methylsulfanyl-2-methylsulfinylethenyl]sulfanylbutane 83483-42-5 C8H16OS3
    1-[(E)-1-methylsulfanyl-2-methylsulfinylethenyl]sulfanylbutane
    —— 1,4-dimethyl-2-methylthiopyrimidinium iodide 114570-89-7 C7H11N2S*I
    1,4-dimethyl-2-methylthiopyrimidinium iodide
    —— (methyl-4 pyrimidinyl-2) thio-2 nitro-5 pyridine 79134-18-2 C10H8N4O2S
    (methyl-4 pyrimidinyl-2) thio-2 nitro-5 pyridine
    —— 2-{[(3,5-dichloropyridin-4-yl)methyl]sulfanyl}-4-methylpyrimidine 1256558-76-5 C11H9Cl2N3S
    2-{[(3,5-dichloropyridin-4-yl)methyl]sulfanyl}-4-methylpyrimidine
    —— 4-methyl-2-{[(2,3,6-trichlorophenyl)methyl]sulfanyl}pyrimidine 1256557-57-9 C12H9Cl3N2S
    4-methyl-2-{[(2,3,6-trichlorophenyl)methyl]sulfanyl}pyrimidine
    —— 4,4'-dichloro-6,6'-bis-dimethylaminomethyl-2,2'-sulfanediyl-di-phenol 101784-60-5 C18H22Cl2N2O2S
    4,4'-dichloro-6,6'-bis-dimethylaminomethyl-2,2'-sulfanediyl-di-phenol
    —— 6-Imino-2-methylsulfanyl-1-phenylpyrimidine-5-carbonitrile 6517-32-4 C12H10N4S
    6-Imino-2-methylsulfanyl-1-phenylpyrimidine-5-carbonitrile
    —— 1,3-bis-N-t-butyloxy-carbonyl-2-methanesulfonyl-propane 848770-39-8 C14H28N2O6S
    1,3-bis-N-t-butyloxy-carbonyl-2-methanesulfonyl-propane
    —— 5-[6-[4-(Trifluoromethyl)pyrimidin-2-yl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole 1428566-20-4 C13H6F3N7S2
    5-[6-[4-(Trifluoromethyl)pyrimidin-2-yl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole
    —— S-(5-methyl-1,3,4-thiadiazol-2-yl) (2Z)-(5-amino-1,2,4-thiadiazol-3-yl)(methoxyimino)ethanethioate 1239325-68-8 C8H8N6O2S3
    S-(5-methyl-1,3,4-thiadiazol-2-yl) (2Z)-(5-amino-1,2,4-thiadiazol-3-yl)(methoxyimino)ethanethioate
    —— 3-(4-chlorophenyl)sulfanyl-N-(propan-2-ylideneamino)propanamide 5727-80-0 C12H15ClN2OS
    3-(4-chlorophenyl)sulfanyl-N-(propan-2-ylideneamino)propanamide
    —— Methyl 4-[(4-methylphenyl)sulfanyl]-2-phenyl-5-pyrimidinyl ether 4696-05-3 C18H16N2OS
    Methyl 4-[(4-methylphenyl)sulfanyl]-2-phenyl-5-pyrimidinyl ether
    —— 2-benzyl-2-(1-trifluoromethyl-3-butenyl)-1,3-dithiane 1150593-31-9 C16H19F3S2
    2-benzyl-2-(1-trifluoromethyl-3-butenyl)-1,3-dithiane
    —— 2-[hydroxy(phenyl)methyl]-2-(1-trifluoromethyl-3-butenyl)-1,3-dithiane 1150593-32-0 C16H19F3OS2
    2-[hydroxy(phenyl)methyl]-2-(1-trifluoromethyl-3-butenyl)-1,3-dithiane
    —— N1-(5-{[2-nitro-4-(trifluoromethyl)phenyl]thio}-1H-1,2,4-triazol-3-yl)-2,3,3-trichloroacrylamide 4728-29-4 C12H5Cl3F3N5O3S
    N1-(5-{[2-nitro-4-(trifluoromethyl)phenyl]thio}-1H-1,2,4-triazol-3-yl)-2,3,3-trichloroacrylamide
    —— {[4-Benzyl-5-(furan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate 6704-98-9 C15H12N3O3S-
    {[4-Benzyl-5-(furan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— 8-(4-Nitro-phenylmercapto)-chinolin 1873-66-1 C15H10N2O2S
    8-(4-Nitro-phenylmercapto)-chinolin
    —— 3-chloro-5-phenylsulfanyl-1-(2-trimethylsilanyl-ethoxymethyl)-1H-pyrazole-4-carbaldehyde 1174231-73-2 C16H21ClN2O2SSi
    3-chloro-5-phenylsulfanyl-1-(2-trimethylsilanyl-ethoxymethyl)-1H-pyrazole-4-carbaldehyde
    —— 3-chloro-5-(phenylthio)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-pyrazole 1174231-65-2 C15H21ClN2OSSi
    3-chloro-5-(phenylthio)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-pyrazole
    —— (3-chloro-5-(phenylthio)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-pyrazol-4-yl)(phenyl)methanol 1174231-72-1 C22H27ClN2O2SSi
    (3-chloro-5-(phenylthio)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-pyrazol-4-yl)(phenyl)methanol
    —— p-bromodifluoromethylthiophenylisocyanate 83882-75-1 C8H4BrF2NOS
    p-bromodifluoromethylthiophenylisocyanate
    —— 2-[[5-(3-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone 5707-48-2 C18H20N4OS2
    2-[[5-(3-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone
    —— 5-({[6-Methyl-2-(methylsulfanyl)pyrimidin-4-yl]sulfanyl}methyl)-4-(prop-2-en-1-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione 6128-45-6 C12H15N5S3
    5-({[6-Methyl-2-(methylsulfanyl)pyrimidin-4-yl]sulfanyl}methyl)-4-(prop-2-en-1-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione
    —— 4-hydrazinyl-2-methylthio-6-(4-morpholino)pyrimidine 94416-05-4 C9H15N5OS
    4-hydrazinyl-2-methylthio-6-(4-morpholino)pyrimidine
    —— 2-[8]quinolylmercapto-aniline 108619-16-5 C15H12N2S
    2-[8]quinolylmercapto-aniline
    —— 8-(2-nitro-phenylsulfanyl)-quinoline 107916-45-0 C15H10N2O2S
    8-(2-nitro-phenylsulfanyl)-quinoline
    —— 8-(2,4-Dinitro-phenylmercapto)-chinolin 1873-67-2 C15H9N3O4S
    8-(2,4-Dinitro-phenylmercapto)-chinolin
    —— 4-Methyl-3-prop-2-ynylsulfanyl-4H-[1,2,4]triazole 5340-72-7 C6H7N3S
    4-Methyl-3-prop-2-ynylsulfanyl-4H-[1,2,4]triazole
    —— 2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-bis(2-methylpropyl)acetamide 5680-07-9 C18H25FN4OS2
    2-[[5-(2-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-bis(2-methylpropyl)acetamide
    —— 10-(Cyclohexyl)-10H-9-thia-10-silaanthracen 61431-09-2 C18H20SSi
    10-(Cyclohexyl)-10H-9-thia-10-silaanthracen
    —— (Methylthio)-thiocarboxylthiocyanat 42871-53-4 C3H3NS3
    (Methylthio)-thiocarboxylthiocyanat