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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-6-(methylamino)-4-(1H-pyrazol-3-yl)pyridine-3,5-dicarbonitrile 1187543-22-1 C21H14ClN7S2
    2-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-6-(methylamino)-4-(1H-pyrazol-3-yl)pyridine-3,5-dicarbonitrile
    —— S-(2-iodophenyl) N,N-diethylthiocarbamate 141079-74-5 C11H14INOS
    S-(2-iodophenyl) N,N-diethylthiocarbamate
    —— 2-benzylsulfanyl-4-methoxy-7-methyl-1(3)<i>H</i>-imidazo[4,5-<i>d</i>]pyridazine 6954-07-0 C14H14N4OS
    2-benzylsulfanyl-4-methoxy-7-methyl-1(3)<i>H</i>-imidazo[4,5-<i>d</i>]pyridazine
    —— cis-1.2-Dipropylsulfonyl-ethylen 1071691-61-6 C8H16O4S2
    cis-1.2-Dipropylsulfonyl-ethylen
    —— 4,7-Bis-propylmercapto-1H-imidazo<4,5-d>pyridazin 3434-05-7 C11H16N4S2
    4,7-Bis-propylmercapto-1H-imidazo<4,5-d>pyridazin
    —— 2-<i>tert</i>-butylsulfanyl-benzaldehyde (<i>E</i>)-oxime 65924-66-5 C11H15NOS
    2-<i>tert</i>-butylsulfanyl-benzaldehyde (<i>E</i>)-oxime
    —— N<sup>2</sup>-methyl-4-(propylthio)-1,2-phenylenediamine 637331-51-2 C10H16N2S
    N<sup>2</sup>-methyl-4-(propylthio)-1,2-phenylenediamine
    —— 2-(4-Fluorophenyl)-3-(4-methylsulfanylphenyl)cycloprop-2-en-1-one 531548-45-5 C16H11FOS
    2-(4-Fluorophenyl)-3-(4-methylsulfanylphenyl)cycloprop-2-en-1-one
    —— 3-tert-Butyl-5-(diisopropylamino)-4-(phenylthio)isoxazol 125379-80-8 C19H28N2OS
    3-tert-Butyl-5-(diisopropylamino)-4-(phenylthio)isoxazol
    —— 2,3,7,8,12,13-hexakis(ethylsulfanyl)-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene 1600518-26-0 C33H42S6
    2,3,7,8,12,13-hexakis(ethylsulfanyl)-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene
    —— 1-D-3-O-(3-phenyl-3-phenylthiopropanoyl)-4-O-trimethylacetyl-1,2:5,6-di-O-isopropylidene-chiro-inositol 769931-71-7 C32H40O8S
    1-D-3-O-(3-phenyl-3-phenylthiopropanoyl)-4-O-trimethylacetyl-1,2:5,6-di-O-isopropylidene-chiro-inositol
    —— 2,3,7,8,12,13-hexakis(benzylsulfanyl)-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene 1600518-28-2 C63H54S6
    2,3,7,8,12,13-hexakis(benzylsulfanyl)-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene
    —— 2,3,7,8,12,13-hexakis-(isopropylsulfanyl)-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene 1600518-27-1 C39H54S6
    2,3,7,8,12,13-hexakis-(isopropylsulfanyl)-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene
    —— N-[2,2-dimethyl-1-(5-methylsulfanyltetrazol-2-yl)propylidene]hydroxylamine 114064-96-9 C7H13N5OS
    N-[2,2-dimethyl-1-(5-methylsulfanyltetrazol-2-yl)propylidene]hydroxylamine
    —— 235431-71-7 C13H21NOS
    —— [(Z)-3-oxo-2,4-bis(phenylsulfanyl)but-1-enyl] 2,2-dimethylpropanoate 119493-38-8 C21H22O3S2
    [(Z)-3-oxo-2,4-bis(phenylsulfanyl)but-1-enyl] 2,2-dimethylpropanoate
    —— ethyl 2-[4-(2-methylpropylsulfanyl)phenyl]acetate 15560-18-6 C14H20O2S
    ethyl 2-[4-(2-methylpropylsulfanyl)phenyl]acetate
    —— 2,6-C6H4(OP(OC10H6(μ-S)C10H6O))2 1226501-54-7 C46H28O6P2S2
    2,6-C6H4(OP(OC10H6(μ-S)C10H6O))2
    —— 1-nitro-2-methyl-2-phenylthiopropane 52265-30-2 C10H13NO2S
    1-nitro-2-methyl-2-phenylthiopropane
    —— 1-[2-Tert-butyl-6-(4-methylphenyl)sulfanylphenyl]-1-methyl-3-phenylurea 1172128-61-8 C25H28N2OS
    1-[2-Tert-butyl-6-(4-methylphenyl)sulfanylphenyl]-1-methyl-3-phenylurea
    —— 1-allyl-3-phenethyl-2-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine 1012787-02-8 C29H28N4S
    1-allyl-3-phenethyl-2-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine
    —— 1-allyl-2,3-dibenzyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine 1012787-03-9 C29H28N4S
    1-allyl-2,3-dibenzyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine
    —— (4-Hydroxy-2-oxo-3-phenylsulfanylbut-3-enyl) 2,2-dimethylpropanoate 119493-25-3 C15H18O4S
    (4-Hydroxy-2-oxo-3-phenylsulfanylbut-3-enyl) 2,2-dimethylpropanoate
    —— 1-D-3-O-(3-phenyl-3-o-aminophenylthiopropanoyl)-4-O-trimethylacetyl-1,2:5,6-di-O-isopropylidene-chiro-inositol 769931-73-9 C32H41NO8S
    1-D-3-O-(3-phenyl-3-o-aminophenylthiopropanoyl)-4-O-trimethylacetyl-1,2:5,6-di-O-isopropylidene-chiro-inositol
    —— [(Z)-4-(2,2-dimethylpropanoyloxy)-2-oxo-3-phenylsulfanylbut-3-enyl] 2,2-dimethylpropanoate 119493-39-9 C20H26O5S
    [(Z)-4-(2,2-dimethylpropanoyloxy)-2-oxo-3-phenylsulfanylbut-3-enyl] 2,2-dimethylpropanoate
    —— 4-Hydroxy-1,3-bis(phenylsulfanyl)but-3-en-2-one 119493-22-0 C16H14O2S2
    4-Hydroxy-1,3-bis(phenylsulfanyl)but-3-en-2-one
    —— 5-[4-methoxy-2-[(E)-6-[4-methoxy-2-(phenylsulfanylmethyl)pyridin-3-yl]hex-3-enyl]pyridin-3-yl]pent-1-en-3-ol 211758-66-6 C30H36N2O3S
    5-[4-methoxy-2-[(E)-6-[4-methoxy-2-(phenylsulfanylmethyl)pyridin-3-yl]hex-3-enyl]pyridin-3-yl]pent-1-en-3-ol
    —— 4-(phenylthio)benzene-1,3-diol 5633-58-9 C12H10O2S
    4-(phenylthio)benzene-1,3-diol
    —— N-(4-((4,6-dichloropyrimidin-2-yl)thio)phenyl)propionamide 936850-32-7 C13H11Cl2N3OS
    N-(4-((4,6-dichloropyrimidin-2-yl)thio)phenyl)propionamide
    —— 2-(4-Isobutylthiophenylthio)benzylchlorid 56056-66-7 C17H19ClS2
    2-(4-Isobutylthiophenylthio)benzylchlorid
    —— [(2-Methylhex-5-en-3-yl)sulfanyl]benzene 64732-74-7 C13H18S
    [(2-Methylhex-5-en-3-yl)sulfanyl]benzene
    —— <2-(4-Isobutylthiophenylthio)phenyl>acetonitril 56056-68-9 C18H19NS2
    <2-(4-Isobutylthiophenylthio)phenyl>acetonitril
    —— 2(4-Isobutylthiophenylthio)benzoesaeure 50900-48-6 C17H18O2S2
    2(4-Isobutylthiophenylthio)benzoesaeure
    —— 2-(Hydroxydisulfanyl)-2-methylpropane 252897-89-5 C4H10OS2
    2-(Hydroxydisulfanyl)-2-methylpropane
    —— 2‑benzylthio‑5‑(4‑aminophenyl)‑1,3,4‑oxadiazole 889790-16-3 C15H13N3OS
    2‑benzylthio‑5‑(4‑aminophenyl)‑1,3,4‑oxadiazole
    —— 4,6,16,18,28,30-hexaaza-5,29-diphenyl-17-methylsulfanyl-2,8,14,20,26,32,38-heptaoxacalix[7]-arene 1260029-67-1 C49H32N6O7S
    4,6,16,18,28,30-hexaaza-5,29-diphenyl-17-methylsulfanyl-2,8,14,20,26,32,38-heptaoxacalix[7]-arene
    —— 1,3-dimethyl-5-nitro-6-(pyridin-4-ylthio)-1H-pyrimidin-2,4-dione 1123800-05-4 C11H10N4O4S
    1,3-dimethyl-5-nitro-6-(pyridin-4-ylthio)-1H-pyrimidin-2,4-dione
    —— 6-(methylthio)pyridin-3-ol 859538-78-6 C6H7NOS
    6-(methylthio)pyridin-3-ol
    —— 6-Ethylsulfanyl-1,3-dimethyl-5-nitropyrimidine-2,4-dione 82000-35-9 C8H11N3O4S
    6-Ethylsulfanyl-1,3-dimethyl-5-nitropyrimidine-2,4-dione
    —— 1,3-dimethyl-1,5-dihydropyrimido<4,5-b><1,4>benzothiazine-2,4(3H)-dione 65693-72-3 C12H11N3O2S
    1,3-dimethyl-1,5-dihydropyrimido<4,5-b><1,4>benzothiazine-2,4(3H)-dione
    —— butylhydrogentetrasulfane 118873-10-2 C4H10S4
    butylhydrogentetrasulfane
    —— 4,6-dichloro-2-(4-fluorobenzylthio)pyrimidine 1418112-78-3 C11H7Cl2FN2S
    4,6-dichloro-2-(4-fluorobenzylthio)pyrimidine
    —— Ethyl 2-(1,3-dimethyl-5-nitro-2,6-dioxopyrimidin-4-yl)sulfanylacetate 82000-33-7 C10H13N3O6S
    Ethyl 2-(1,3-dimethyl-5-nitro-2,6-dioxopyrimidin-4-yl)sulfanylacetate
    —— 6-Benzylsulfanyl-1,3-dimethyl-5-nitropyrimidine-2,4-dione 82000-36-0 C13H13N3O4S
    6-Benzylsulfanyl-1,3-dimethyl-5-nitropyrimidine-2,4-dione
    —— 1,3-dimethyl-5-nitro-6-(pyridin-N-oxide-4-ylsulfanyl)-1H-pyrimidin-2,4-dione 1123800-06-5 C11H10N4O5S
    1,3-dimethyl-5-nitro-6-(pyridin-N-oxide-4-ylsulfanyl)-1H-pyrimidin-2,4-dione
    —— 4,6-dichloro-2-(methylthio)pyridine 86634-72-2 C6H5Cl2NS
    4,6-dichloro-2-(methylthio)pyridine
    —— 2-Nitro-1-(4-benzylmercapto-phenyl)-propen-(1) 88357-15-7 C16H15NO2S
    2-Nitro-1-(4-benzylmercapto-phenyl)-propen-(1)
    —— Acrylsaeure-<5-chlor-2-(phenylthio)anilid> 76542-04-6 C15H12ClNOS
    Acrylsaeure-<5-chlor-2-(phenylthio)anilid>
    —— Sulfide, isobutyl o-tolyl 15561-00-9 C11H16S
    Sulfide, isobutyl o-tolyl
    —— (2R)-N-methoxy-N,2-dimethyl-3-phenylsulfanylpropanamide 160238-80-2 C12H17NO2S
    (2R)-N-methoxy-N,2-dimethyl-3-phenylsulfanylpropanamide