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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-methyl-2-(3-methylbutane-1-sulfonyl)propionic acid 1218915-21-9 C9H18O4S
    2-methyl-2-(3-methylbutane-1-sulfonyl)propionic acid
    —— 4-(4,4-dimethyl-4,5-dihydro-2-oxazolinyl)-3-phenyl-5-(phenylthiomethyl)isoxazole 132632-37-2 C21H20N2O2S
    4-(4,4-dimethyl-4,5-dihydro-2-oxazolinyl)-3-phenyl-5-(phenylthiomethyl)isoxazole
    —— 2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole 1512853-05-2 C13H9N3S2
    2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole
    —— 4-Ethylmercapto-2,6-diamino-pyridin 18960-90-2 C7H11N3S
    4-Ethylmercapto-2,6-diamino-pyridin
    —— 2-Methyl-2-(4,4,4-trifluorobutylsulfonyl)propan-1-amine 1356116-75-0 C8H16F3NO2S
    2-Methyl-2-(4,4,4-trifluorobutylsulfonyl)propan-1-amine
    —— 4-methyl-6-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridazin-3-ylamine 882500-14-3 C16H20N4O2S2
    4-methyl-6-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridazin-3-ylamine
    —— 5-methyl-6-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridazin-3-ylamine 882500-13-2 C16H20N4O2S2
    5-methyl-6-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridazin-3-ylamine
    —— 4.5-Bis-benzylmercapto-3-oxo-2.3-dihydro-pyridazin 5592-55-2 C18H16N2OS2
    4.5-Bis-benzylmercapto-3-oxo-2.3-dihydro-pyridazin
    —— 3,4,5-Tris-(4-brom-benzylmercapto)-pyridazin 5589-91-3 C25H19Br3N2S3
    3,4,5-Tris-(4-brom-benzylmercapto)-pyridazin
    —— 1,3-Bis-dodecylmercapto-propan 18365-75-8 C27H56S2
    1,3-Bis-dodecylmercapto-propan
    —— 4-Benzylthio-5-methoxy-2-phenyl-3-pyridazinon 5509-77-3 C18H16N2O2S
    4-Benzylthio-5-methoxy-2-phenyl-3-pyridazinon
    —— 4-bromo-2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole 1512853-06-3 C13H8BrN3S2
    4-bromo-2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole
    —— (5-phenylsulfanyl-pyridine-2-yl)-thiazole-2-yl-amine 1144109-15-8 C14H11N3S2
    (5-phenylsulfanyl-pyridine-2-yl)-thiazole-2-yl-amine
    —— 4-chloro-2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole 1512853-07-4 C13H8ClN3S2
    4-chloro-2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole
    —— methyl 2-[(4-chlorophenyl)sulfanyl]-3,4,6-trimethyl-5-(phenylselanyl)benzoate 1254592-91-0 C23H21ClO2SSe
    methyl 2-[(4-chlorophenyl)sulfanyl]-3,4,6-trimethyl-5-(phenylselanyl)benzoate
    —— methyl 6-[(4-ethylphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate 1254592-99-8 C24H24O2SSe
    methyl 6-[(4-ethylphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate
    —— (1'S,3'R,7'S,8'Z,11'S)-1',8'-dimethylspiro[1,3-dithiolane-2,12'-tricyclo[9.3.0.03,7]tetradeca-5,8-diene]-2'-one 85269-19-8 C18H24OS2
    (1'S,3'R,7'S,8'Z,11'S)-1',8'-dimethylspiro[1,3-dithiolane-2,12'-tricyclo[9.3.0.03,7]tetradeca-5,8-diene]-2'-one
    —— 6-amino-4-(4-methylsulfanyl-phenyl)-2-oxo-1,2,3,4-tetrahydro-pyridine-3,5-dicarboxylic acid diethyl ester 52505-26-7 C18H22N2O5S
    6-amino-4-(4-methylsulfanyl-phenyl)-2-oxo-1,2,3,4-tetrahydro-pyridine-3,5-dicarboxylic acid diethyl ester
    —— 8-[1-Phenyl-meth-(Z)-ylidene]-1,5-dithia-spiro[5.5]undecane 1-oxide 89655-99-2 C16H20OS2
    8-[1-Phenyl-meth-(Z)-ylidene]-1,5-dithia-spiro[5.5]undecane 1-oxide
    —— methyl 6-[(4-methoxyphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate 1254592-97-6 C23H22O3SSe
    methyl 6-[(4-methoxyphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate
    —— 2-[(Tert-butylamino)methyl]-6-[3-[(tert-butylamino)methyl]-5-chloro-2-hydroxyphenyl]sulfanyl-4-chlorophenol 86366-94-1 C22H30Cl2N2O2S
    2-[(Tert-butylamino)methyl]-6-[3-[(tert-butylamino)methyl]-5-chloro-2-hydroxyphenyl]sulfanyl-4-chlorophenol
    —— methyl 2,4-dimethyl-6-[(4-methylphenyl)sulfanyl]-3-(phenylselanyl)benzoate 1254592-93-2 C23H22O2SSe
    methyl 2,4-dimethyl-6-[(4-methylphenyl)sulfanyl]-3-(phenylselanyl)benzoate
    —— methyl 2,4-dimethyl-3-(phenylselanyl)-6-(phenylsulfanyl)benzoate 1254592-90-9 C22H20O2SSe
    methyl 2,4-dimethyl-3-(phenylselanyl)-6-(phenylsulfanyl)benzoate
    —— 2-Isopropyliden-thiophenol 54225-78-4 C9H10OS
    2-Isopropyliden-thiophenol
    —— methyl 2-[(4-ethylphenyl)sulfanyl]-3,4,6-trimethyl-5-(phenylselanyl)benzoate 1254593-00-4 C25H26O2SSe
    methyl 2-[(4-ethylphenyl)sulfanyl]-3,4,6-trimethyl-5-(phenylselanyl)benzoate
    —— methyl 2,4-dimethyl-6-[(naphthalen-2-yl)sulfanyl]-3-(phenylselanyl)benzoate 1254592-98-7 C26H22O2SSe
    methyl 2,4-dimethyl-6-[(naphthalen-2-yl)sulfanyl]-3-(phenylselanyl)benzoate
    —— 4-[4-(3-fluoro-benzyloxy)-2-(pyrido[2,3-d]pyrimidin-4-ylamino)-phenylsulfanyl]-phenol 943771-48-0 C26H19FN4O2S
    4-[4-(3-fluoro-benzyloxy)-2-(pyrido[2,3-d]pyrimidin-4-ylamino)-phenylsulfanyl]-phenol
    —— methyl 6-[(3-chlorophenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate 1254592-92-1 C22H19ClO2SSe
    methyl 6-[(3-chlorophenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate
    —— methyl 6-[(3-methoxyphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate 1254592-96-5 C23H22O3SSe
    methyl 6-[(3-methoxyphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate
    —— 7-Phenylsulfanyl-3H-benzooxazol-2-one 81740-26-3 C13H9NO2S
    7-Phenylsulfanyl-3H-benzooxazol-2-one
    —— methyl 2,4-dimethyl-6-[(3-methylphenyl)sulfanyl]-3-(phenylselanyl)benzoate 1254592-94-3 C23H22O2SSe
    methyl 2,4-dimethyl-6-[(3-methylphenyl)sulfanyl]-3-(phenylselanyl)benzoate
    —— methyl 2,4,5-trimethyl-6-[(4-methylphenyl)sulfanyl]-3-(phenylselanyl)benzoate 1254592-95-4 C24H24O2SSe
    methyl 2,4,5-trimethyl-6-[(4-methylphenyl)sulfanyl]-3-(phenylselanyl)benzoate
    —— 6-chloro-4-(methylthio)pyridazin-3-amine 896740-03-7 C5H6ClN3S
    6-chloro-4-(methylthio)pyridazin-3-amine
    —— <i>N</i><sup>4</sup>,<i>N</i><sup>4</sup>-dimethyl-2-methylsulfanyl-pyrimidine-4,6-diyldiamine 52222-40-9 C7H12N4S
    <i>N</i><sup>4</sup>,<i>N</i><sup>4</sup>-dimethyl-2-methylsulfanyl-pyrimidine-4,6-diyldiamine
    —— 4-ethylamino-2-methylthio-6-propylthiopyrimidine 1373127-44-6 C10H17N3S2
    4-ethylamino-2-methylthio-6-propylthiopyrimidine
    —— 5-bromo-N<sup>4</sup>-ethyl-2-(methylthio)pyrimidine-4,6-diamine 1620910-79-3 C7H11BrN4S
    5-bromo-N<sup>4</sup>-ethyl-2-(methylthio)pyrimidine-4,6-diamine
    —— 4-Amino-2-methylsulfanyl-6-piperidinopyrimidine 96225-84-2 C10H16N4S
    4-Amino-2-methylsulfanyl-6-piperidinopyrimidine
    —— 2-Methyl-4-thiocyanato-1-isothiocyanato-benzol 18986-03-3 C9H6N2S2
    2-Methyl-4-thiocyanato-1-isothiocyanato-benzol
    —— N<sup>4</sup>-ethyl-2-(methylthio)pyrimidine-4,6-diamine 78448-99-4 C7H12N4S
    N<sup>4</sup>-ethyl-2-(methylthio)pyrimidine-4,6-diamine
    —— 5-chloro-N<sup>4</sup>-ethyl-2-(methylthio)pyrimidine-4,6-diamine 1620910-81-7 C7H11ClN4S
    5-chloro-N<sup>4</sup>-ethyl-2-(methylthio)pyrimidine-4,6-diamine
    —— <i>N</i><sup>4</sup>-benzyl-2-methylsulfanyl-pyrimidine-4,6-diamine 60722-63-6 C12H14N4S
    <i>N</i><sup>4</sup>-benzyl-2-methylsulfanyl-pyrimidine-4,6-diamine
    —— 5,6-dichloro-2-(methylthio)pyrimidine-4-amine 1620910-63-5 C5H5Cl2N3S
    5,6-dichloro-2-(methylthio)pyrimidine-4-amine
    —— 2-(4-amino-2-methylthiopyrimidin-6-ylamino)-6-methyl-1H-pyridinium-3-thiolate 81587-39-5 C11H13N5S2
    2-(4-amino-2-methylthiopyrimidin-6-ylamino)-6-methyl-1H-pyridinium-3-thiolate
    —— 4diethylamino-6-propylthio-2-methylthiopyrimidine 1373127-49-1 C12H21N3S2
    4diethylamino-6-propylthio-2-methylthiopyrimidine
    —— 4-amino-2-methylthio-6-(4-thiomorpholino)pyrimidine 96225-88-6 C9H14N4S2
    4-amino-2-methylthio-6-(4-thiomorpholino)pyrimidine
    —— 5-(2-hydroxyethyl)-2-methylthio-4-pyrimidone 89943-45-3 C7H10N2O2S
    5-(2-hydroxyethyl)-2-methylthio-4-pyrimidone
    —— Ethyl-cis-4-heptenylthioether 55320-20-2 C9H18S
    Ethyl-cis-4-heptenylthioether
    —— 4-benzyl-3-phenylthio-4,5-dihydrofuran-2(3H)-one 96540-46-4 C17H16O2S
    4-benzyl-3-phenylthio-4,5-dihydrofuran-2(3H)-one
    —— 2-ethyl-3-<methoxy(phenylthio)(trimethylsilyl)methyl>cyclopentanone 112699-41-9 C18H28O2SSi
    2-ethyl-3-<methoxy(phenylthio)(trimethylsilyl)methyl>cyclopentanone
    —— isothiocyanato-2 pentene-1 97040-51-2 C6H9NS
    isothiocyanato-2 pentene-1