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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 7-Chlor-2,4-diamino-1,3,6-triazaphenothiazin 42362-21-0 C9H7ClN6S
    7-Chlor-2,4-diamino-1,3,6-triazaphenothiazin
    —— 2-(3',5'-di-tert-butyl-2'-hydroxyphenyl)-5-(phenylthio)benzotriazole 145233-43-8 C26H29N3OS
    2-(3',5'-di-tert-butyl-2'-hydroxyphenyl)-5-(phenylthio)benzotriazole
    —— 4-thia-2,3-dimethyl-1,6-heptadiene 111948-33-5 C8H14S
    4-thia-2,3-dimethyl-1,6-heptadiene
    —— 5-isopropyl-1-hydroxyethoxymethyl-6-(phenylthio)uracil 137897-91-7 C16H20N2O4S
    5-isopropyl-1-hydroxyethoxymethyl-6-(phenylthio)uracil
    —— Trimethyl-[2-(3-phenylsulfanyl-propyl)-[1,3]dithian-2-yl]-silane 215182-49-3 C16H26S3Si
    Trimethyl-[2-(3-phenylsulfanyl-propyl)-[1,3]dithian-2-yl]-silane
    —— 1-ethoxymethyl-2-phenylthio-5-(2-pyridinyl)imidazole 120671-11-6 C17H17N3OS
    1-ethoxymethyl-2-phenylthio-5-(2-pyridinyl)imidazole
    —— 3-(1-Adamantanthio)-pyridin 54476-12-9 C15H19NS
    3-(1-Adamantanthio)-pyridin
    —— 2-Butin-1,4-diyl-bis(aethylxanthat) 22543-16-4 C10H14O2S4
    2-Butin-1,4-diyl-bis(aethylxanthat)
    —— 4-(3'-Methylthio)phenylbutyric acid 213607-85-3 C11H14O2S
    4-(3'-Methylthio)phenylbutyric acid
    —— 4-(2'-Bromo-5'-methylthio)phenylbutyric acid 213607-86-4 C11H13BrO2S
    4-(2'-Bromo-5'-methylthio)phenylbutyric acid
    —— 2-({2-[(tert-butoxycarbonyl)amino]phenyl}thio)acetic acid 574751-77-2 C13H17NO4S
    2-({2-[(tert-butoxycarbonyl)amino]phenyl}thio)acetic acid
    —— 2-<2-Chlor-phenylthio>-aethanol 13290-15-8 C8H9ClOS
    2-<2-Chlor-phenylthio>-aethanol
    —— Dichloro-bis-(dichloro-methanesulfonyl)-methane 120423-09-8 C3H2Cl6O4S2
    Dichloro-bis-(dichloro-methanesulfonyl)-methane
    —— 1,4-Bis-butylsulfonyl-butan 34756-60-0 C12H26O4S2
    1,4-Bis-butylsulfonyl-butan
    —— 5-amino-3-methyl-7-methylthiopyrimido<4,5-b><1,4>oxazin-2-one 138612-38-1 C8H8N4O2S
    5-amino-3-methyl-7-methylthiopyrimido<4,5-b><1,4>oxazin-2-one
    —— (S)-1-Phenyl-3-phenylsulfanylpropanol 223113-76-6 C15H16OS
    (S)-1-Phenyl-3-phenylsulfanylpropanol
    —— 3-(1-Methyl-1-propyl-butyl)-6-methylsulfanyl-[1,2,4,5]tetrazine 159801-93-1 C11H20N4S
    3-(1-Methyl-1-propyl-butyl)-6-methylsulfanyl-[1,2,4,5]tetrazine
    —— (1-(3-bromophenyl)but-3-enyl)(phenyl)sulfane 1382802-09-6 C16H15BrS
    (1-(3-bromophenyl)but-3-enyl)(phenyl)sulfane
    —— 2-methyl-2-(1-methylvinyl)-1,3-dithiane 64087-41-8 C8H14S2
    2-methyl-2-(1-methylvinyl)-1,3-dithiane
    —— (1-(2-bromophenyl)but-3-enyl)(phenyl)sulfane 1382802-08-5 C16H15BrS
    (1-(2-bromophenyl)but-3-enyl)(phenyl)sulfane
    —— trimethyl-[(2R)-1-[2-[[(2R)-oxiran-2-yl]methyl]-1,3-dithian-2-yl]pentadecan-2-yl]oxysilane 1085711-04-1 C25H50O2S2Si
    trimethyl-[(2R)-1-[2-[[(2R)-oxiran-2-yl]methyl]-1,3-dithian-2-yl]pentadecan-2-yl]oxysilane
    —— 1-phenylthio-2-trifluoroacetoxyoctane 80437-03-2 C16H21F3O2S
    1-phenylthio-2-trifluoroacetoxyoctane
    —— 8-(2,6-difluorobenzyl)-3-hydroxymethyl-7-methyl-2,3-dihydro-5H-thiazolo[3,2-a]pyridin-5-one 1313425-88-5 C16H15F2NO2S
    8-(2,6-difluorobenzyl)-3-hydroxymethyl-7-methyl-2,3-dihydro-5H-thiazolo[3,2-a]pyridin-5-one
    —— 2-{6-[(2-{[(tert-butoxycarbonyl)amino]methyl}phenyl)thio][1,2,4]triazolo[4,3-a]pyridin-3-yl}phenyl tert-butyl carbonate 1344738-21-1 C29H32N4O5S
    2-{6-[(2-{[(tert-butoxycarbonyl)amino]methyl}phenyl)thio][1,2,4]triazolo[4,3-a]pyridin-3-yl}phenyl tert-butyl carbonate
    —— (6-Methyl-pyrid-2-ylthio)-essigsaeure 68840-22-2 C8H9NO2S
    (6-Methyl-pyrid-2-ylthio)-essigsaeure
    —— 2-(phenylthio)thiolane 1-oxide 162934-90-9 C10H12OS2
    2-(phenylthio)thiolane 1-oxide
    —— 3-Chlor-5-methylthio-1,2,4-triazol 51108-40-8 C3H4ClN3S
    3-Chlor-5-methylthio-1,2,4-triazol
    —— N-2-Pyrazinylmethyl-S-phenylmercaptoacetamid 55316-48-8 C13H13N3OS
    N-2-Pyrazinylmethyl-S-phenylmercaptoacetamid
    —— 3-benzyl-1-methyl-2-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine 1012787-14-2 C26H24N4S
    3-benzyl-1-methyl-2-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine
    —— 4-Amino-6-dibenzylamino-2-methylmercapto-pyrimidin 60755-24-0 C19H20N4S
    4-Amino-6-dibenzylamino-2-methylmercapto-pyrimidin
    —— 2-amino-3-(phenylthio)pyridine 64064-61-5 C11H10N2S
    2-amino-3-(phenylthio)pyridine
    —— N-(5-bromo-3-(phenylthio)pyridin-2-yl)thiazolo[5,4-b]pyridin-2-amine hydrochloride 953041-94-6 C17H11BrN4S2*ClH
    N-(5-bromo-3-(phenylthio)pyridin-2-yl)thiazolo[5,4-b]pyridin-2-amine hydrochloride
    —— 3,7-Diphenyl-1H-[1,2,4]triazino[5,6-e][1,3,4]thiadiazine 120588-53-6 C16H11N5S
    3,7-Diphenyl-1H-[1,2,4]triazino[5,6-e][1,3,4]thiadiazine
    —— 2-(1'-Phenylthio-cycloprop-1'-yl)-propen 63049-11-6 C12H14S
    2-(1'-Phenylthio-cycloprop-1'-yl)-propen
    —— 7-(1-hydroxy-4-thiacyclohexyl)-7-phenylthio-8-oxo-2,2-dimethyl-3-oxa-1-azabicyclo[4.2.0]octane 98810-72-1 C19H25NO3S2
    7-(1-hydroxy-4-thiacyclohexyl)-7-phenylthio-8-oxo-2,2-dimethyl-3-oxa-1-azabicyclo[4.2.0]octane
    —— 2-(1-Hydroxy-ethyl)-3-phenylsulfanyl-cyclohexanone 74457-11-7 C14H18O2S
    2-(1-Hydroxy-ethyl)-3-phenylsulfanyl-cyclohexanone
    —— 8-chloro-3,4,5,6-tetrahydro-5-phenyl-2H-1,6-benzothiazocine 87697-05-0 C16H16ClNS
    8-chloro-3,4,5,6-tetrahydro-5-phenyl-2H-1,6-benzothiazocine
    —— 2-benzyl-3-(2-pyridyl)thio-propionic acid ethyl ester 116622-22-1 C17H19NO2S
    2-benzyl-3-(2-pyridyl)thio-propionic acid ethyl ester
    —— N-[2-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octane-1-sulfonyl)-ethyl]-formamide 1158091-34-9 C11H10F13NO3S
    N-[2-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octane-1-sulfonyl)-ethyl]-formamide
    —— (4,4-Dimethyl-cyclobut-1-enylsulfanyl)-benzene 63048-76-0 C12H14S
    (4,4-Dimethyl-cyclobut-1-enylsulfanyl)-benzene
    —— (1,1-dioxo-1λ<sup>6</sup>-thietan-3-yl)amine trifluoroacetate 1331887-01-4 C2HF3O2*C3H7NO2S
    (1,1-dioxo-1λ<sup>6</sup>-thietan-3-yl)amine trifluoroacetate
    —— Mo(N(t-Bu)(3,5-C6H3Me2))3(η1-PhC(SPh)N) 647858-87-5 C49H64MoN4S
    Mo(N(t-Bu)(3,5-C6H3Me2))3(η1-PhC(SPh)N)
    —— 2-pentylsulfanyl-pyrimidin-4-ylamine 60722-69-2 C9H15N3S
    2-pentylsulfanyl-pyrimidin-4-ylamine
    —— 6-(Benzyloxy)-2-(methylsulfanyl)pyrimidin-4-amine 60722-76-1 C12H13N3OS
    6-(Benzyloxy)-2-(methylsulfanyl)pyrimidin-4-amine
    —— (Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester 159684-42-1 C22H24O4S2
    (Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester
    —— (1RS,3S)-3,4-isopropylidenedioxy-1-methoxy-1-phenylthio-butan-2-one 872311-74-5 C14H18O4S
    (1RS,3S)-3,4-isopropylidenedioxy-1-methoxy-1-phenylthio-butan-2-one
    —— 1-butylsulfanyl-4-methylsulfanyl-buta-1,3-diene 100949-60-8 C9H16S2
    1-butylsulfanyl-4-methylsulfanyl-buta-1,3-diene
    —— 3-[(2-bromophenyl)thio]benzo[b]thiophene-2-carboxylic acid 1618666-15-1 C15H9BrO2S2
    3-[(2-bromophenyl)thio]benzo[b]thiophene-2-carboxylic acid
    —— bis(N-tert-butoxycarbonyl-2-pyrrolyl)sulfide 187237-63-4 C18H24N2O4S
    bis(N-tert-butoxycarbonyl-2-pyrrolyl)sulfide
    —— 1-(methylthio)cycloheptanecarbaldehyde 1287313-05-6 C9H16OS
    1-(methylthio)cycloheptanecarbaldehyde