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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— S<sup>6</sup>,2'-cyclo-isocytidine 74652-99-6 C9H11N3O4S
    S<sup>6</sup>,2'-cyclo-isocytidine
    —— S<sup>2</sup>,2'-cyclo-5-bromo-2-thiouridine 74610-60-9 C9H9BrN2O4S
    S<sup>2</sup>,2'-cyclo-5-bromo-2-thiouridine
    —— 1,12-diisothiocyanatododecane 105214-58-2 C14H24N2S2
    1,12-diisothiocyanatododecane
    —— 2-Methylthio-1-allyl-pyrimidon-(4) 6204-00-8 C8H10N2OS
    2-Methylthio-1-allyl-pyrimidon-(4)
    —— Cyclohexyldithiocarbamate 51300-97-1 C10H17NO2S2
    Cyclohexyldithiocarbamate
    —— S-cyclopropyl cyclopropanethiosulfonate 139631-63-3 C6H10O2S2
    S-cyclopropyl cyclopropanethiosulfonate
    —— S-1-chlorocyclopropyl cyclopropanethiosulfonate 139631-64-4 C6H9ClO2S2
    S-1-chlorocyclopropyl cyclopropanethiosulfonate
    —— 2H-Hexafluor-propan-1-thiol 684-14-0 C3H2F6S
    2H-Hexafluor-propan-1-thiol
    —— 6-methoxy-2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde 1134633-67-2 C19H14N4O2S
    6-methoxy-2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde
    —— 3,5-dimethoxy-2-(5-nitro-1H-indol-3-ylthio)phenol 1448175-29-8 C16H14N2O5S
    3,5-dimethoxy-2-(5-nitro-1H-indol-3-ylthio)phenol
    —— 3-chloro-4-[(4-chlorophenyl)thio]-5-hydroxy-2(5H)-furanone 52180-41-3 C10H6Cl2O3S
    3-chloro-4-[(4-chlorophenyl)thio]-5-hydroxy-2(5H)-furanone
    —— (disulfido)carbonic acid <i>SS</i>-isopropyl ester <i>O</i>-methyl ester 61775-32-4 C5H10O2S2
    (disulfido)carbonic acid <i>SS</i>-isopropyl ester <i>O</i>-methyl ester
    —— Cyclopropanecarbonitrile, 1-[(phenylthio)methyl]- 1387565-86-7 C11H11NS
    Cyclopropanecarbonitrile, 1-[(phenylthio)methyl]-
    —— N-(1-phenylmethyl-1-propyl)-N-(2-phenylsulfanylethyl)formamide 886759-20-2 C19H23NOS
    N-(1-phenylmethyl-1-propyl)-N-(2-phenylsulfanylethyl)formamide
    —— 2-(diethylamino)ethyl octyl sulfoxide 69002-75-1 C14H31NOS
    2-(diethylamino)ethyl octyl sulfoxide
    —— Chlorthiosulfonsaeure-methylester 91571-60-7 CH3ClO2S2
    Chlorthiosulfonsaeure-methylester
    —— 8-Chloro-6-(1-methyl-4-piperidyl)-6H-dibenz<b,e>-1,4-oxathiepin 83986-02-1 C19H20ClNOS
    8-Chloro-6-(1-methyl-4-piperidyl)-6H-dibenz<b,e>-1,4-oxathiepin
    —— Acetonitrile, isothiocyanato- 32772-75-1 C3H2N2S
    Acetonitrile, isothiocyanato-
    —— N-Vinylthiopropionamid 37109-53-8 C5H9NS
    N-Vinylthiopropionamid
    —— 1-(4-fluorophenyl)ethyl-(2-phenylsulfanyl)ethylamine 886759-18-8 C16H18FNS
    1-(4-fluorophenyl)ethyl-(2-phenylsulfanyl)ethylamine
    —— [2-Phenylsulfanylethyl(trimethylsilyl)amino] thiohypochlorite 157736-02-2 C11H18ClNS2Si
    [2-Phenylsulfanylethyl(trimethylsilyl)amino] thiohypochlorite
    —— 2-{[4-(2-ethoxy-2-oxoethyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester 886527-05-5 C15H23NO4S2
    2-{[4-(2-ethoxy-2-oxoethyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester
    —— N-(2-Phenylmercapto-aethyl)-biguanid 91011-18-6 C10H15N5S
    N-(2-Phenylmercapto-aethyl)-biguanid
    —— benzyl(4-ethylphenyl)sulfane 100976-97-4 C15H16S
    benzyl(4-ethylphenyl)sulfane
    —— N-(1-cyclohexyl-1-phenylmethyl)-N-(2-phenylsulfanylethyl)formamide 886759-23-5 C22H27NOS
    N-(1-cyclohexyl-1-phenylmethyl)-N-(2-phenylsulfanylethyl)formamide
    —— 1-phenylmethyl-1-propyl-(2-phenylsulfanyl)ethylamine 886759-14-4 C18H23NS
    1-phenylmethyl-1-propyl-(2-phenylsulfanyl)ethylamine
    —— Methanethiol, N-(2-phenylthioethyl)amidino-, hydrogen thiosulfate 40283-97-4 C10H14N2O3S3
    Methanethiol, N-(2-phenylthioethyl)amidino-, hydrogen thiosulfate
    —— 2-(2-Phenylsulfanylethyl)-4,5-dimethyl-3,6-dihydro-2H-1,2-thiazine 157736-13-5 C14H19NS2
    2-(2-Phenylsulfanylethyl)-4,5-dimethyl-3,6-dihydro-2H-1,2-thiazine
    —— 1-cyclohexyl-1-phenylmethyl-(2-phenylsulfanyl)ethylamine 886759-17-7 C21H27NS
    1-cyclohexyl-1-phenylmethyl-(2-phenylsulfanyl)ethylamine
    —— 1-cyclobutyl-1-phenylmethyl-(2-phenylsulfanyl)ethylamine 886759-16-6 C19H23NS
    1-cyclobutyl-1-phenylmethyl-(2-phenylsulfanyl)ethylamine
    —— N-[1-(4-fluorophenyl)ethyl]-N-(2-phenylsulfanylethyl)formamide 886759-24-6 C17H18FNOS
    N-[1-(4-fluorophenyl)ethyl]-N-(2-phenylsulfanylethyl)formamide
    —— N-(1-cyclobutyl-1-phenylmethyl)-N-(2-phenylsulfanylethyl)formamide 886759-22-4 C20H23NOS
    N-(1-cyclobutyl-1-phenylmethyl)-N-(2-phenylsulfanylethyl)formamide
    —— 1-Chloro-4-(1-phenylprop-2-enylsulfanyl)benzene 1173006-72-8 C15H13ClS
    1-Chloro-4-(1-phenylprop-2-enylsulfanyl)benzene
    —— 2-((2-fluorophenyl)thio)acetonitrile 61081-27-4 C8H6FNS
    2-((2-fluorophenyl)thio)acetonitrile
    —— β-Hydroxyethyl-2-methallylsulfid 60154-79-2 C6H12OS
    β-Hydroxyethyl-2-methallylsulfid
    —— 2,2,2-trifluoro-N-methyl-N-(2-phenylsulfanylethyl)acetamide 173267-12-4 C11H12F3NOS
    2,2,2-trifluoro-N-methyl-N-(2-phenylsulfanylethyl)acetamide
    —— N-acetyl-N-benzyl-2-(phenylthio)ethylamine 191545-71-8 C17H19NOS
    N-acetyl-N-benzyl-2-(phenylthio)ethylamine
    —— 2-(o-tolylthio)acetonitrile 103575-38-8 C9H9NS
    2-(o-tolylthio)acetonitrile
    —— 1-(6-Chloropyridazin-3-yl)oxy-3-(2-phenylsulfanylethylamino)propan-2-ol 138803-32-4 C15H18ClN3O2S
    1-(6-Chloropyridazin-3-yl)oxy-3-(2-phenylsulfanylethylamino)propan-2-ol
    —— 1-(2-methylsulfanylphenyl)-N-(2-phenylsulfanylethyl)methanimine 1258493-81-0 C16H17NS2
    1-(2-methylsulfanylphenyl)-N-(2-phenylsulfanylethyl)methanimine
    —— 2,2,2-trifluoro-N-(2-(phenylthio)ethyl)acetamide 173267-11-3 C10H10F3NOS
    2,2,2-trifluoro-N-(2-(phenylthio)ethyl)acetamide
    —— N-(2-hydroxyethyl)-N'-<2-(phenylthio)ethyl>urea 66923-49-7 C11H16N2O2S
    N-(2-hydroxyethyl)-N'-<2-(phenylthio)ethyl>urea
    —— N-(2-Phenylmercapto-aethyl)-propionamid 2173-29-7 C11H15NOS
    N-(2-Phenylmercapto-aethyl)-propionamid
    —— 2-methyl-7,7-di[(phenylsulfanyl)methyl]bicyclo[3.3.0]oct-1-en-3-one 938436-24-9 C23H24OS2
    2-methyl-7,7-di[(phenylsulfanyl)methyl]bicyclo[3.3.0]oct-1-en-3-one
    —— cis-3-nonen-1-thiol 265655-15-0 C9H18S
    cis-3-nonen-1-thiol
    —— Glutaraldehydbis-(diphenylmercaptal) 53480-96-9 C29H28S4
    Glutaraldehydbis-(diphenylmercaptal)
    —— 2-cyano-3-(2-methyl-2-trifluoroacetamidopropanethio)-pyridine 342816-11-9 C12H12F3N3OS
    2-cyano-3-(2-methyl-2-trifluoroacetamidopropanethio)-pyridine
    —— 3-(2-chloroethylsulfanyl)-2-methylprop-1-ene 60154-80-5 C6H11ClS
    3-(2-chloroethylsulfanyl)-2-methylprop-1-ene
    —— 3-Ethensulfonyl-2-methylpropen 60154-78-1 C6H10O2S
    3-Ethensulfonyl-2-methylpropen
    —— 2,3-bis(2,5-dimethylthiophen-3-yl)-5-(phenylsulfanyl)cyclopent-2-en-1-one 1380607-60-2 C23H22OS3
    2,3-bis(2,5-dimethylthiophen-3-yl)-5-(phenylsulfanyl)cyclopent-2-en-1-one