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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Allyl-2-allylsulfanyl-6-(3,5-dimethyl-benzyl)-5-ethyl-1H-pyrimidin-4-one 199852-53-4 C21H26N2OS
    1-Allyl-2-allylsulfanyl-6-(3,5-dimethyl-benzyl)-5-ethyl-1H-pyrimidin-4-one
    —— 6-(3,5-Dichloro-phenylsulfanyl)-1-ethoxymethyl-5-ethyl-1H-pyrimidine-2,4-dione 144410-27-5 C15H16Cl2N2O3S
    6-(3,5-Dichloro-phenylsulfanyl)-1-ethoxymethyl-5-ethyl-1H-pyrimidine-2,4-dione
    —— (2-ethyl-6-methylphenyl)(2-methylbutyl)sulfane 1286763-66-3 C14H22S
    (2-ethyl-6-methylphenyl)(2-methylbutyl)sulfane
    —— 2-ethyl-6-methylphenyl phenyl sulfide 1286763-72-1 C15H16S
    2-ethyl-6-methylphenyl phenyl sulfide
    —— 5-Cyclopropyl-1-ethoxymethyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione 136160-36-6 C16H18N2O3S
    5-Cyclopropyl-1-ethoxymethyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione
    —— 5-Ethyl-1-phenethyloxymethyl-6-phenylsulfanyl-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one 136160-45-7 C21H22N2O2S2
    5-Ethyl-1-phenethyloxymethyl-6-phenylsulfanyl-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one
    —— 7H-Thiazolo(3,2-a)pyrimidin-7-one, 2,3-dihydro-3-methoxy-6-(1-methylethyl)-5-(phenylmethyl)- 199852-25-0 C17H20N2O2S
    7H-Thiazolo(3,2-a)pyrimidin-7-one, 2,3-dihydro-3-methoxy-6-(1-methylethyl)-5-(phenylmethyl)-
    —— (R)-4-(4-(methylthiomethoxy)piperidin-1-yl)-1-(phenylthio)butan-2-amine 1619923-57-7 C17H28N2OS2
    (R)-4-(4-(methylthiomethoxy)piperidin-1-yl)-1-(phenylthio)butan-2-amine
    —— (R)-4-(azetidin-1-yl)-1-(phenylthio)butan-2-amine 1402141-76-7 C13H20N2S
    (R)-4-(azetidin-1-yl)-1-(phenylthio)butan-2-amine
    —— phenylthioacetaldehyde oxime 121407-61-2 C8H9NOS
    phenylthioacetaldehyde oxime
    —— (R)-1-(3-amino-4-(phenylthio)butyl)azetidin-3-ol 1402141-78-9 C13H20N2OS
    (R)-1-(3-amino-4-(phenylthio)butyl)azetidin-3-ol
    —— Cyclopentylidene-phenylsulfanyl-acetaldehyde 59377-51-4 C13H14OS
    Cyclopentylidene-phenylsulfanyl-acetaldehyde
    —— 7-(3,5-Dimethyl-benzyl)-6-ethyl-3-(2-hydroxy-ethoxy)-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one 199852-36-3 C19H24N2O3S
    7-(3,5-Dimethyl-benzyl)-6-ethyl-3-(2-hydroxy-ethoxy)-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one
    —— (R)-1-(phenylthio)-4-(pyrrolidin-1-yl)butan-2-amine 1244724-89-7 C14H22N2S
    (R)-1-(phenylthio)-4-(pyrrolidin-1-yl)butan-2-amine
    —— 5H-Thiazolo(3,2-a)pyrimidin-5-one, 3-ethoxy-2,3-dihydro-6-(1-methylethyl)-7-(phenylmethyl)- 199852-38-5 C18H22N2O2S
    5H-Thiazolo(3,2-a)pyrimidin-5-one, 3-ethoxy-2,3-dihydro-6-(1-methylethyl)-7-(phenylmethyl)-
    —— (R)-1-(phenylthio)-4-(piperidin-1-yl)butan-2-amine 1402141-77-8 C15H24N2S
    (R)-1-(phenylthio)-4-(piperidin-1-yl)butan-2-amine
    —— (R)-1-(3-amino-4-(phenylthio)butyl)-4-methylpiperidin-4-ol 1402141-80-3 C16H26N2OS
    (R)-1-(3-amino-4-(phenylthio)butyl)-4-methylpiperidin-4-ol
    —— (R)-1-(3-amino-4-(phenylthio)butyl)piperidin-4-ol 1402141-79-0 C15H24N2OS
    (R)-1-(3-amino-4-(phenylthio)butyl)piperidin-4-ol
    —— 7H-Thiazolo(3,2-a)pyrimidin-7-one, 3-(bromomethyl)-2,3-dihydro-6-(1-methylethyl)-5-(phenylmethyl)- 199852-49-8 C17H19BrN2OS
    7H-Thiazolo(3,2-a)pyrimidin-7-one, 3-(bromomethyl)-2,3-dihydro-6-(1-methylethyl)-5-(phenylmethyl)-
    —— N-Trimethylsilanylmethyl-thioformimidic acid phenyl ester 85236-99-3 C11H17NSSi
    N-Trimethylsilanylmethyl-thioformimidic acid phenyl ester
    —— Palladium(1+), chloro(2,2'-dithiobis(ethanamine)-N,N',S)-, (SP-4-2)- 71852-94-3 C4H12ClN2PdS2+
    Palladium(1+), chloro(2,2'-dithiobis(ethanamine)-N,N',S)-, (SP-4-2)-
    —— 2-(3-Hydroxymethyl-2,3-dihydro-benzo[b]thiophen-2-yl)-phenol 79592-73-7 C15H14O2S
    2-(3-Hydroxymethyl-2,3-dihydro-benzo[b]thiophen-2-yl)-phenol
    —— (2-Phenyl-2,3-dihydro-benzo[b]thiophen-3-yl)-methanol 147646-81-9 C15H14OS
    (2-Phenyl-2,3-dihydro-benzo[b]thiophen-3-yl)-methanol
    —— 7H-Thiazolo(3,2-a)pyrimidin-7-one, 2,3-dihydro-3-(2-hydroxyethoxy)-6-(1-methylethyl)-5-(phenylmethyl)- 199852-27-2 C18H22N2O3S
    7H-Thiazolo(3,2-a)pyrimidin-7-one, 2,3-dihydro-3-(2-hydroxyethoxy)-6-(1-methylethyl)-5-(phenylmethyl)-
    —— 6-(phenylthio)hex-5-enenitrile 138942-40-2 C12H13NS
    6-(phenylthio)hex-5-enenitrile
    —— 5-methyl-3-nitro-4-(benzothiazol-2-yl)thio-pyridin-2(1H)-one 172469-87-3 C13H9N3O3S2
    5-methyl-3-nitro-4-(benzothiazol-2-yl)thio-pyridin-2(1H)-one
    —— 6-Methoxy-4-(p-tolylmercapto)quinaldine 5431-56-1 C18H18ClNOS
    6-Methoxy-4-(p-tolylmercapto)quinaldine
    —— 2-[4-(2-Butyl-4-chloro-5-hydroxymethyl-imidazol-1-ylmethyl)-phenylsulfanyl]-benzoic acid 114799-44-9 C22H23ClN2O3S
    2-[4-(2-Butyl-4-chloro-5-hydroxymethyl-imidazol-1-ylmethyl)-phenylsulfanyl]-benzoic acid
    —— 1,2-bis(2-pyridylsulfanylmethyl)benzene 219872-03-4 C18H16N2S2
    1,2-bis(2-pyridylsulfanylmethyl)benzene
    —— 1,3-dimethyl-2-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine 1012787-08-4 C20H20N4S
    1,3-dimethyl-2-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine
    —— 1,12-bis(N,N'-thiomethylcarbonyloxyamidinyl)dodecane 648440-45-3 C18H34N4O4S2
    1,12-bis(N,N'-thiomethylcarbonyloxyamidinyl)dodecane
    —— dibenzo<d,f>dithiepin 220-17-7 C13H10S2
    dibenzo<d,f>dithiepin
    —— 1-Decyl-3-methyl-thiourea 92037-03-1 C12H26N2S
    1-Decyl-3-methyl-thiourea
    —— 3-(2-Methylsulfanyl-phenyl)-prop-2-ynylamine 851902-36-8 C10H11NS
    3-(2-Methylsulfanyl-phenyl)-prop-2-ynylamine
    —— 2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide 67889-22-9 C15H12O4S
    2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide
    —— 2-(methoxycarbonyl)phenyl 2-(methylcarbamoyl)phenyl sulfide 100695-82-7 C16H15NO3S
    2-(methoxycarbonyl)phenyl 2-(methylcarbamoyl)phenyl sulfide
    —— 1-(6-(2-(2-(2-(methylthio)phenyl)ethynyl)phenyl)hex-5-ynyl)piperidin-2-one 1142813-24-8 C26H27NOS
    1-(6-(2-(2-(2-(methylthio)phenyl)ethynyl)phenyl)hex-5-ynyl)piperidin-2-one
    —— 4-(3-Methylthiophenyl)-3-thiosemicarbazide 76457-80-2 C8H11N3S2
    4-(3-Methylthiophenyl)-3-thiosemicarbazide
    —— 2-(3-methoxy-1-propynyl)thioanisole 1448017-00-2 C11H12OS
    2-(3-methoxy-1-propynyl)thioanisole
    —— 7-(3,5-Dimethyl-benzyl)-6-ethyl-3-methoxy-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one 199852-34-1 C18H22N2O2S
    7-(3,5-Dimethyl-benzyl)-6-ethyl-3-methoxy-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one
    —— (2S,3S)-3-(tert-butoxycarbonylamino)-3-phenyl-1-phenylthio-2-propanol 799559-83-4 C20H25NO3S
    (2S,3S)-3-(tert-butoxycarbonylamino)-3-phenyl-1-phenylthio-2-propanol
    —— 5-Methyl-6-phenylsulfanylmethyl-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one 189057-71-4 C12H12N2OS2
    5-Methyl-6-phenylsulfanylmethyl-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one
    —— 6-Phenylthio-5H-benzo<a>phenothiazin-5-one 82105-99-5 C22H13NOS2
    6-Phenylthio-5H-benzo<a>phenothiazin-5-one
    —— 2-Ethylthio-3,6-dihydro-5-methyl-6-oxo-1,3-diphenyl-1-pyrimidinium-4-olat 100083-23-6 C19H18N2O2S
    2-Ethylthio-3,6-dihydro-5-methyl-6-oxo-1,3-diphenyl-1-pyrimidinium-4-olat
    —— 5-methyl-3-nitro-4-(N-methylimidazol-2-yl)thio-pyridin-2(1H)-one 172469-89-5 C10H10N4O3S
    5-methyl-3-nitro-4-(N-methylimidazol-2-yl)thio-pyridin-2(1H)-one
    —— 5-methyl-3-nitro-4-phenylthio-pyridin-2(1H)-one 172469-79-3 C12H10N2O3S
    5-methyl-3-nitro-4-phenylthio-pyridin-2(1H)-one
    —— 1-benzyl-4,5-dibromo-2-phenylthioimidazole 101853-86-5 C16H12Br2N2S
    1-benzyl-4,5-dibromo-2-phenylthioimidazole
    —— 2-bromo-6-(phenylsulfanyl)pyrimidine-4-carbonitrile 1108736-81-7 C11H6BrN3S
    2-bromo-6-(phenylsulfanyl)pyrimidine-4-carbonitrile
    —— 8-(2-(methylthio)phenyl)octa-5,7-diyn-1-ol 1429327-33-2 C15H16OS
    8-(2-(methylthio)phenyl)octa-5,7-diyn-1-ol
    —— 2-methyl-3-(p-tolylthio)-6-tosylpyridin-4-ol 1103495-03-9 C20H19NO3S2
    2-methyl-3-(p-tolylthio)-6-tosylpyridin-4-ol