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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-fluoro-4-(1,1,2,3,3,3-hexafluoro-1-propylthio)-N-methylaniline 935440-65-6 C10H8F7NS
    2-fluoro-4-(1,1,2,3,3,3-hexafluoro-1-propylthio)-N-methylaniline
    —— 2-fluoro-N-methyl-4-(2-propynylthio)-aniline 935440-49-6 C10H10FNS
    2-fluoro-N-methyl-4-(2-propynylthio)-aniline
    —— N-(2-hydroxyethyl)-2-fluoro-4-(trifluoromethylthio)aniline 939037-92-0 C9H9F4NOS
    N-(2-hydroxyethyl)-2-fluoro-4-(trifluoromethylthio)aniline
    —— 2,3-dimethyl-N-methyl-4-(1,1,2,2,2-pentafluoroethylthio)-aniline 935440-96-3 C11H12F5NS
    2,3-dimethyl-N-methyl-4-(1,1,2,2,2-pentafluoroethylthio)-aniline
    —— 2,3-dimethyl-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline 935441-04-6 C11H13F4NS
    2,3-dimethyl-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline
    —— 2-fluoro-N-methyl-4-(1,1,2-trifluoro-2-trifluoromethoxyethylthio)-aniline 935440-61-2 C10H8F7NOS
    2-fluoro-N-methyl-4-(1,1,2-trifluoro-2-trifluoromethoxyethylthio)-aniline
    —— 2-chloro-N-methyl-4-(trifluoromethylthio)-aniline 935440-56-5 C8H7ClF3NS
    2-chloro-N-methyl-4-(trifluoromethylthio)-aniline
    —— 2-methyl-N-methyl-4-(pentafluoroethylthio)-aniline 935440-63-4 C10H10F5NS
    2-methyl-N-methyl-4-(pentafluoroethylthio)-aniline
    —— 2-isopropyl-6-nitro-3,1-benzoxathian 148899-05-2 C11H13NO3S
    2-isopropyl-6-nitro-3,1-benzoxathian
    —— 6-amino-2-[(3,4-difluorobenzyl)thio]pyrimidin-4-ol 166751-46-8 C11H9F2N3OS
    6-amino-2-[(3,4-difluorobenzyl)thio]pyrimidin-4-ol
    —— 3,6-Bis[4-(2,3-dihydrothieno[3,4-b][1,4]dithiin-5-yl)phenyl]furo[3,2-g][1]benzofuran-2,7-dione 1353052-00-2 C34H20O4S6
    3,6-Bis[4-(2,3-dihydrothieno[3,4-b][1,4]dithiin-5-yl)phenyl]furo[3,2-g][1]benzofuran-2,7-dione
    —— 5-((3,4-difluorobenzyl)thio)-4H-1,2,4-triazol-3-amine 1446246-55-4 C9H8F2N4S
    5-((3,4-difluorobenzyl)thio)-4H-1,2,4-triazol-3-amine
    —— 2-[3-(4-chlorophenyl)-ureido]-5-{4-[3-(4-chlorophenyl)-ureido]phenylsulfanyl}benzoic acid 1192315-63-1 C27H20Cl2N4O4S
    2-[3-(4-chlorophenyl)-ureido]-5-{4-[3-(4-chlorophenyl)-ureido]phenylsulfanyl}benzoic acid
    —— 2-amino-5-(4-aminophenylthio)benzoic acid 1192319-15-5 C13H12N2O2S
    2-amino-5-(4-aminophenylthio)benzoic acid
    —— methyl 2-[(4-chlorophenyl)sulfanyl]-4-hydroxybutanoate 1369958-09-7 C11H13ClO3S
    methyl 2-[(4-chlorophenyl)sulfanyl]-4-hydroxybutanoate
    —— 1-(4-chlorophenyl)-3-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)urea 1263499-71-3 C19H17ClN4OS
    1-(4-chlorophenyl)-3-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)urea
    —— (Z)-3-Amino-4-methyl-pent-2-enethioic acid amide 95882-21-6 C6H12N2S
    (Z)-3-Amino-4-methyl-pent-2-enethioic acid amide
    —— 3-cyclohexyl-1-propylthiourea 70498-34-9 C10H20N2S
    3-cyclohexyl-1-propylthiourea
    —— 4-Aethyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3 53265-23-9 C8H9N3OS
    4-Aethyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3
    —— (2-Methyl-1-phenylthiopropyl)-diphenylphosphinoxid 61173-99-7 C22H23OPS
    (2-Methyl-1-phenylthiopropyl)-diphenylphosphinoxid
    —— (4R,5S)-5-tert-Butyl-4-p-tolylsulfanyl-dihydro-furan-2-one 110968-94-0 C15H20O2S
    (4R,5S)-5-tert-Butyl-4-p-tolylsulfanyl-dihydro-furan-2-one
    —— 1-Isopropyl-2-methylthioacetylen 33563-69-8 C6H10S
    1-Isopropyl-2-methylthioacetylen
    —— 4-Benzyl-2-methyl-2H-pyrazino(2,3-b)-1,4-thiazin-3(4H)-one 53265-28-4 C14H13N3OS
    4-Benzyl-2-methyl-2H-pyrazino(2,3-b)-1,4-thiazin-3(4H)-one
    —— Ethyl (S)-2-hydroxy-2-<<(4-methylphenyl)sulfenyl>methyl>hexadecanoate 154079-04-6 C26H44O3S
    Ethyl (S)-2-hydroxy-2-<<(4-methylphenyl)sulfenyl>methyl>hexadecanoate
    —— (3-thienyl)methyl 3,3-bis(4-fluorophenylthio)-N-(phenyl)thiopropionimidate 1107009-21-1 C26H21F2NS4
    (3-thienyl)methyl 3,3-bis(4-fluorophenylthio)-N-(phenyl)thiopropionimidate
    —— 4-Propyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3 53265-25-1 C9H11N3OS
    4-Propyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3
    —— 4-Methyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3 53265-21-7 C7H7N3OS
    4-Methyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3
    —— Trimethyl-[4-(4-methylsulfanyl-phenylethynyl)-phenylethynyl]-silane 910467-68-4 C20H20SSi
    Trimethyl-[4-(4-methylsulfanyl-phenylethynyl)-phenylethynyl]-silane
    —— triisopropyl((4-(methylthio)phenyl)ethynyl)silane 1235968-75-8 C18H28SSi
    triisopropyl((4-(methylthio)phenyl)ethynyl)silane
    —— 1,12-bis(p-methylthiophenyl)dodeca-1,3,9,11-tetrayne 1227073-43-9 C26H22S2
    1,12-bis(p-methylthiophenyl)dodeca-1,3,9,11-tetrayne
    —— N-phenyl-3,3-bis(phenylthio)thiopropionamide 1107010-52-5 C21H19NS3
    N-phenyl-3,3-bis(phenylthio)thiopropionamide
    —— 2-<2,2-Bis(phenylthio)ethyl>cycloheptanone 151830-58-9 C21H24OS2
    2-<2,2-Bis(phenylthio)ethyl>cycloheptanone
    —— 3-Trifluoromethyl-2-(3-methyl-2-aminophenylthio) benzonitrile 146070-31-7 C15H11F3N2S
    3-Trifluoromethyl-2-(3-methyl-2-aminophenylthio) benzonitrile
    —— 2,5-bis(4-aminophenylenesulfanyl)selenophene 1188338-47-7 C16H14N2S2Se
    2,5-bis(4-aminophenylenesulfanyl)selenophene
    —— 2-Methyl-4-methyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3 53265-22-8 C8H9N3OS
    2-Methyl-4-methyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3
    —— 6-methyl-4-methylthio-2(1H)-pyridone 114361-56-7 C7H9NOS
    6-methyl-4-methylthio-2(1H)-pyridone
    —— 6-methyl-4-methylthio-2-oxo-2H-pyran-3-carboxamide 114361-66-9 C8H9NO3S
    6-methyl-4-methylthio-2-oxo-2H-pyran-3-carboxamide
    —— 6-methyl-4-methylthio-2-oxo-2H-pyran-3-carbonitrile 114361-52-3 C8H7NO2S
    6-methyl-4-methylthio-2-oxo-2H-pyran-3-carbonitrile
    —— 4-Chloro-5-ethylthio-3H-1,2-dithiole-3-thione 52444-69-6 C5H5ClS4
    4-Chloro-5-ethylthio-3H-1,2-dithiole-3-thione
    —— Diethyl (2-Methylthio-5-pyrimidinyloxy)malonate 80306-03-2 C12H16N2O5S
    Diethyl (2-Methylthio-5-pyrimidinyloxy)malonate
    —— 2-(benzylthio)-6-tert-butylpyridine 1429200-00-9 C16H19NS
    2-(benzylthio)-6-tert-butylpyridine
    —— 1,2,3,4-Tetrahydro-3-methyl-1-(2-methylpropyl)-2,4-dioxo-5-(2-thienylthio)-thieno[2,3-d]pyrimidine-6-carboxaldehyde 259862-29-8 C16H16N2O3S3
    1,2,3,4-Tetrahydro-3-methyl-1-(2-methylpropyl)-2,4-dioxo-5-(2-thienylthio)-thieno[2,3-d]pyrimidine-6-carboxaldehyde
    —— 4-Chlorbutyl-aethyl-sulfon 53903-87-0 C6H13ClO2S
    4-Chlorbutyl-aethyl-sulfon
    —— (S)-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((((2-tert-butoxy)carbonyl)oxy)-5-ethoxyphenylthio)phenyl}-2-propylbutan-1-ol 1383617-39-7 C31H44ClNO7S
    (S)-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((((2-tert-butoxy)carbonyl)oxy)-5-ethoxyphenylthio)phenyl}-2-propylbutan-1-ol
    —— 4-[2-(4-tert-butylphenylthio)thien-4-yl]-4-methoxytetrahydropyran 140618-67-3 C20H26O2S2
    4-[2-(4-tert-butylphenylthio)thien-4-yl]-4-methoxytetrahydropyran
    —— (R)-2-allyl-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((5-ethoxy-2-hydroxyphenyl)thio)phenyl}butan-1-ol 1383617-32-0 C26H34ClNO5S
    (R)-2-allyl-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((5-ethoxy-2-hydroxyphenyl)thio)phenyl}butan-1-ol
    —— (R)-2-allyl-2-amino-4-{2-chloro-4-((5-ethoxy-2-hydroxy)phenylthio)phenyl}butylphosphoric acid monoester 1383617-29-5 C21H27ClNO6PS
    (R)-2-allyl-2-amino-4-{2-chloro-4-((5-ethoxy-2-hydroxy)phenylthio)phenyl}butylphosphoric acid monoester
    —— 4-Benzyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3 53265-27-3 C13H11N3OS
    4-Benzyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3
    —— 3-bromo-5-trifluoromethylphenyl 4-tolyl sulphide 135049-05-7 C14H10BrF3S
    3-bromo-5-trifluoromethylphenyl 4-tolyl sulphide
    —— 5-(6-(6-amino-9-(3-(isopropylamino)propyl)-9H-purin-8-ylthio)benzo[d][1,3]dioxol-5-yl)furan-2-carbaldehyde 1289543-84-5 C23H24N6O4S
    5-(6-(6-amino-9-(3-(isopropylamino)propyl)-9H-purin-8-ylthio)benzo[d][1,3]dioxol-5-yl)furan-2-carbaldehyde