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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4,5-dimethyl-1,3-dithiol-2-ylidene)-5-hydroxy-6H-[1,3]dithiolo[4,5-d]pyrimidin-7-one 149130-56-3 C10H8N2O2S4
    2-(4,5-dimethyl-1,3-dithiol-2-ylidene)-5-hydroxy-6H-[1,3]dithiolo[4,5-d]pyrimidin-7-one
    —— 6-(4-Chloro-phenyl)-4-methylsulfanyl-2-oxo-2H-pyran-3-carboxylic acid ethyl ester 153391-45-8 C15H13ClO4S
    6-(4-Chloro-phenyl)-4-methylsulfanyl-2-oxo-2H-pyran-3-carboxylic acid ethyl ester
    —— ethyl 3-ethoxy-5-(methylthio)isoxazole-4-carboxylate 1259434-09-7 C9H13NO4S
    ethyl 3-ethoxy-5-(methylthio)isoxazole-4-carboxylate
    —— 6-(4-Chloro-phenylsulfanyl)-2,5-dimethyl-benzothiazole-4,7-dione 650635-70-4 C15H10ClNO2S2
    6-(4-Chloro-phenylsulfanyl)-2,5-dimethyl-benzothiazole-4,7-dione
    —— bis(3,5-dimethylphenyl)sulfide 148278-62-0 C16H18S
    bis(3,5-dimethylphenyl)sulfide
    —— (2-Thioxo-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-5-ylmethyl)-carbamic acid tert-butyl ester 690253-25-9 C11H15NO2S5
    (2-Thioxo-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-5-ylmethyl)-carbamic acid tert-butyl ester
    —— 2-((3,5-dimethylphenyl)thio)benzo[d]thiazole 1335609-16-9 C15H13NS2
    2-((3,5-dimethylphenyl)thio)benzo[d]thiazole
    —— 2-benzylsulfanyl-4-cyclohexyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile 322390-78-3 C18H19N3OS
    2-benzylsulfanyl-4-cyclohexyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 6-(4-Fluoro-phenylsulfanyl)-2,5-dimethyl-benzothiazole-4,7-dione 650635-71-5 C15H10FNO2S2
    6-(4-Fluoro-phenylsulfanyl)-2,5-dimethyl-benzothiazole-4,7-dione
    —— 3-Methylsulfanyl-5-pyridin-3-yl-isothiazole-4-carbonitrile 221006-31-1 C10H7N3S2
    3-Methylsulfanyl-5-pyridin-3-yl-isothiazole-4-carbonitrile
    —— 2,5-Dimethyl-6-p-tolylsulfanyl-benzothiazole-4,7-dione 650635-69-1 C16H13NO2S2
    2,5-Dimethyl-6-p-tolylsulfanyl-benzothiazole-4,7-dione
    —— 9-isopropyl-6-(1-methyl-1H-tetrazol-5-ylthio)-9H-purine 1384277-45-5 C10H12N8S
    9-isopropyl-6-(1-methyl-1H-tetrazol-5-ylthio)-9H-purine
    —— α,β-Diamino-propylmercaptan 133560-02-8 C3H10N2S
    α,β-Diamino-propylmercaptan
    —— ditetradecyl sulfone 41233-81-2 C28H58O2S
    ditetradecyl sulfone
    —— dioctadecyl sulfoxide 99159-40-7 C36H74OS
    dioctadecyl sulfoxide
    —— (Z)-4,5,9-trithiadodeca-1,6-diene 1080588-39-1 C9H16S3
    (Z)-4,5,9-trithiadodeca-1,6-diene
    —— 2-Propylsulfanyl-cyclopenta-1,3-diene 185522-23-0 C8H12S
    2-Propylsulfanyl-cyclopenta-1,3-diene
    —— (2S)-5-[tert-butyl(dimethyl)silyl]oxy-1-[2-[(2R,3S)-3-[tert-butyl(dimethyl)silyl]oxypent-4-en-2-yl]-1,3-dithian-2-yl]pentan-2-ol 1380242-09-0 C26H54O3S2Si2
    (2S)-5-[tert-butyl(dimethyl)silyl]oxy-1-[2-[(2R,3S)-3-[tert-butyl(dimethyl)silyl]oxypent-4-en-2-yl]-1,3-dithian-2-yl]pentan-2-ol
    —— 7-Chlor-2,4-dimethoxy-1,3,6-triazaphenothiazin 42362-23-2 C11H9ClN4O2S
    7-Chlor-2,4-dimethoxy-1,3,6-triazaphenothiazin
    —— dimethyl 3,4-bis[(phenylthio)methyl]-3-cyclopentene-1,1-dicarboxylate 63133-61-9 C23H24O4S2
    dimethyl 3,4-bis[(phenylthio)methyl]-3-cyclopentene-1,1-dicarboxylate
    —— (E)-10,10-dimethyl-4,5,9-trithiaundeca-1,6-diene 1372558-97-8 C10H18S3
    (E)-10,10-dimethyl-4,5,9-trithiaundeca-1,6-diene
    —— ditetradecyl sulfoxide 62444-29-5 C28H58OS
    ditetradecyl sulfoxide
    —— S-(2,2,2-trifluoroethyl) 2-methylprop-2-ene-1-sulfothioate 847661-08-9 C6H9F3O2S2
    S-(2,2,2-trifluoroethyl) 2-methylprop-2-ene-1-sulfothioate
    —— 2,4-Dimethoxy-8-methyl-1,3,9-triazaphenothiazin 55740-61-9 C12H12N4O2S
    2,4-Dimethoxy-8-methyl-1,3,9-triazaphenothiazin
    —— 2-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-2-yl]amino]-1-pentanol 259102-97-1 C17H19ClN4OS2
    2-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-2-yl]amino]-1-pentanol
    —— 4-Acetylmercapto-3-chlor-2,5,6-trifluorpyridin 16572-71-7 C7H3ClF3NOS
    4-Acetylmercapto-3-chlor-2,5,6-trifluorpyridin
    —— 10,10-dimethyl-4,5,9-trithiaundeca-1,6-diene 1080588-41-5 C10H18S3
    10,10-dimethyl-4,5,9-trithiaundeca-1,6-diene
    —— 3-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-2-yl]amino]-1-propanol 259103-23-6 C15H15ClN4OS2
    3-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-2-yl]amino]-1-propanol
    —— (E)-4,5,9-trithiadodeca-1,6-diene 1080588-37-9 C9H16S3
    (E)-4,5,9-trithiadodeca-1,6-diene
    —— N-[2-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5 d]pyrimidin-2-yl]amino]ethyl]-acetamide 259103-07-6 C16H16ClN5OS2
    N-[2-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5 d]pyrimidin-2-yl]amino]ethyl]-acetamide
    —— 7-Chloro-N-methyl-5-[(phenylmethyl)thio]-thiazolo[4,5-d]pyrimidin-2-amine 259102-56-2 C13H11ClN4S2
    7-Chloro-N-methyl-5-[(phenylmethyl)thio]-thiazolo[4,5-d]pyrimidin-2-amine
    —— 7-Chloro-5-[(phenylmethyl)thio]-N-[(tetrahydro-2-furanyl)methyl]-thiazolo[4,5-d]pyrimidin-2-amine 259102-60-8 C17H17ClN4OS2
    7-Chloro-5-[(phenylmethyl)thio]-N-[(tetrahydro-2-furanyl)methyl]-thiazolo[4,5-d]pyrimidin-2-amine
    —— 7-Chloro-5-[(phenylmethyl)thio]-N-(4-piperidinyl)-thiazolo[4,5-d]pyrimidin-2-amine 259103-46-3 C17H18ClN5S2
    7-Chloro-5-[(phenylmethyl)thio]-N-(4-piperidinyl)-thiazolo[4,5-d]pyrimidin-2-amine
    —— 2-(N-methyl-3-piperidylmethylthio)pyridine-N-oxide 478620-32-5 C12H18N2OS
    2-(N-methyl-3-piperidylmethylthio)pyridine-N-oxide
    —— 1-Butene, 1-[(1-methylethyl)thio]-, (E)- 121222-72-8 C7H14S
    1-Butene, 1-[(1-methylethyl)thio]-, (E)-
    —— 1-[5-(3,5-dichloro-1-oxido-pyridin-1-ium-4-yl)sulfanyl-4-nitro-2-thienyl]ethanone 1247819-82-4 C11H6Cl2N2O4S2
    1-[5-(3,5-dichloro-1-oxido-pyridin-1-ium-4-yl)sulfanyl-4-nitro-2-thienyl]ethanone
    —— N-Hydroxy-4-(methylsulfanyl)benzene-1-carboximidoyl chloride 93394-07-1 C8H8ClNOS
    N-Hydroxy-4-(methylsulfanyl)benzene-1-carboximidoyl chloride
    —— Isobutyl-neopentyl-sulfon 10269-16-6 C9H20O2S
    Isobutyl-neopentyl-sulfon
    —— Dineopentyl-sulphon 10269-17-7 C10H22O2S
    Dineopentyl-sulphon
    —— 3,3'-Dithiodipropionamidin 15785-94-1 C6H14N4S2
    3,3'-Dithiodipropionamidin
    —— 1-{5-[(3,5-dichlorophenyl)thio]-4-nitrothiophen-2-yl}ethanone 1247819-69-7 C12H7Cl2NO3S2
    1-{5-[(3,5-dichlorophenyl)thio]-4-nitrothiophen-2-yl}ethanone
    —— (1-Azaniumyl-3-sulfanylpropan-2-yl)azanium;dibromide —— C3H12Br2N2S
    (1-Azaniumyl-3-sulfanylpropan-2-yl)azanium;dibromide
    —— 1-Methyl-2-phenylsulfanyl-cyclododecanol 112418-89-0 C19H30OS
    1-Methyl-2-phenylsulfanyl-cyclododecanol
    —— 1-[5-(3,5-dichloro-4-pyridylsulfanyl)-4-nitro-2-thienyl]ethanone 1247819-81-3 C11H6Cl2N2O3S2
    1-[5-(3,5-dichloro-4-pyridylsulfanyl)-4-nitro-2-thienyl]ethanone
    —— 1-[4-cyano-5-(2,4-dichlorophenyl)sulfanyl-2-thienyl]ethanone 1247819-88-0 C13H7Cl2NOS2
    1-[4-cyano-5-(2,4-dichlorophenyl)sulfanyl-2-thienyl]ethanone
    —— p-methylphenyl 2-deoxy-1-thio-6-O-triisopropylsilyl-D-galactopyranoside 918334-12-0 C22H38O4SSi
    p-methylphenyl 2-deoxy-1-thio-6-O-triisopropylsilyl-D-galactopyranoside
    —— hydroxymethyl-octyl sulfone 62954-90-9 C9H20O3S
    hydroxymethyl-octyl sulfone
    —— 1,1,3,3-tetramethylcyclobutane-2-spiro-2'-1,3-dithiolane-4'-spiro-2''-adamantane-2-one 100281-74-1 C19H28OS2
    1,1,3,3-tetramethylcyclobutane-2-spiro-2'-1,3-dithiolane-4'-spiro-2''-adamantane-2-one
    —— 4,5-dimethyl-[1,3]dioxolane-2-thione 24471-98-5 C5H8O2S
    4,5-dimethyl-[1,3]dioxolane-2-thione
    —— 6-(Hydroxymethyl)-2-(methylthio)nicotinonitrile 474823-68-2 C8H8N2OS
    6-(Hydroxymethyl)-2-(methylthio)nicotinonitrile