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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Didodecylhexanbis(dithioat) 65222-82-4 C30H58S4
    Didodecylhexanbis(dithioat)
    —— (3-benzyl-4-oxo-2-thioxo-thiazolidin-5-yl)-(4-chloro-phenylsulfanyl)-acetic acid methyl ester 54326-52-2 C19H16ClNO3S3
    (3-benzyl-4-oxo-2-thioxo-thiazolidin-5-yl)-(4-chloro-phenylsulfanyl)-acetic acid methyl ester
    —— 1,1-Bis-t-butylsulfonyl-ethan 19170-12-8 C10H22O4S2
    1,1-Bis-t-butylsulfonyl-ethan
    —— 3-Ethoxy-1-methyl-5-methylsulfanyl-1-oxo-1λ<sup>6</sup>-thiopyran-4-carbonitrile 65322-15-8 C10H13NO2S2
    3-Ethoxy-1-methyl-5-methylsulfanyl-1-oxo-1λ<sup>6</sup>-thiopyran-4-carbonitrile
    —— tert-butyl (1S,2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylthio)cyclopent-3-ene-1-carboxylate 909911-52-0 C24H32O4S
    tert-butyl (1S,2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylthio)cyclopent-3-ene-1-carboxylate
    —— (7-chloro-8-methyl-1,1,3-trioxo-3,4-dihydro-2H-1,5,2-benzo[f]dithiazepin-4-yl)acetic acid 958781-93-6 C11H10ClNO5S2
    (7-chloro-8-methyl-1,1,3-trioxo-3,4-dihydro-2H-1,5,2-benzo[f]dithiazepin-4-yl)acetic acid
    —— thiophenyl-β-D-ribo-hexopyranoside-3-ulose 1451062-71-7 C12H14O5S
    thiophenyl-β-D-ribo-hexopyranoside-3-ulose
    —— Phenyl 2,3:4,6-bis-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-1-thio-β-D-glucopyranoside 145259-84-3 C36H68O7SSi4
    Phenyl 2,3:4,6-bis-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-1-thio-β-D-glucopyranoside
    —— (2-amino-phenylsulfanyl)-(3-benzyl-4-oxo-2-thioxo-thiazolidin-5-yl)-acetic acid methyl ester 54255-29-7 C19H18N2O3S3
    (2-amino-phenylsulfanyl)-(3-benzyl-4-oxo-2-thioxo-thiazolidin-5-yl)-acetic acid methyl ester
    —— 1,2-Dichloro-3-(2-chloromethyl-phenylsulfanyl)-benzene 79962-31-5 C13H9Cl3S
    1,2-Dichloro-3-(2-chloromethyl-phenylsulfanyl)-benzene
    —— (3R,3aR,6aS)-3-(hydroxymethyl)-6a-(phenylthio)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one 909911-32-6 C14H14O3S
    (3R,3aR,6aS)-3-(hydroxymethyl)-6a-(phenylthio)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one
    —— ethyl 4-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]butanoate 84608-08-2 C9H13N3O4S
    ethyl 4-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]butanoate
    —— 2-(2,3-Dichlorophenylthio)benzoic Acid 79962-20-2 C13H8Cl2O2S
    2-(2,3-Dichlorophenylthio)benzoic Acid
    —— 2-(2,3-Dichlorophenylthio)benzyl Alcohol 79962-21-3 C13H10Cl2OS
    2-(2,3-Dichlorophenylthio)benzyl Alcohol
    —— 3,6-diethyl-2-cyanomethylthiopyrazine 116196-67-9 C10H13N3S
    3,6-diethyl-2-cyanomethylthiopyrazine
    —— 4,4',6,6'-tetra(pyridin-4-yl)-5H,5'H-2,2'-bi[1,3]dithiolo[4,5-c]pyrrolylidene 1389288-76-9 C30H18N6S4
    4,4',6,6'-tetra(pyridin-4-yl)-5H,5'H-2,2'-bi[1,3]dithiolo[4,5-c]pyrrolylidene
    —— 2-oxo-N-propan-2-yl-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carboxamide 1426959-62-7 C18H22N2O2S
    2-oxo-N-propan-2-yl-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carboxamide
    —— t-butyl S-3,6-diethylpyrazin-2-ylthiolcarbonate 104272-94-8 C13H20N2O2S
    t-butyl S-3,6-diethylpyrazin-2-ylthiolcarbonate
    —— ({[(3-Bromo-2-chloropropyl)sulfanyl](dichloro)methyl}sulfanyl)cyclohexane 19095-93-3 C10H16BrCl3S2
    ({[(3-Bromo-2-chloropropyl)sulfanyl](dichloro)methyl}sulfanyl)cyclohexane
    —— Bis[2-(methylsulfanyl)phenyl](phenyl)arsane 19980-62-2 C20H19AsS2
    Bis[2-(methylsulfanyl)phenyl](phenyl)arsane
    —— Disulfide, bis(2-chloro-1,1-dimethylethyl) 16621-42-4 C8H16Cl2S2
    Disulfide, bis(2-chloro-1,1-dimethylethyl)
    —— 2-(3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-propionic acid ethyl ester 75621-69-1 C8H11N3O4S
    2-(3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-propionic acid ethyl ester
    —— (Z)-2,2-dimethyl-4,7-dihydro-1λ4,3-dithiepine 1-oxide 1242163-10-5 C7H12OS2
    (Z)-2,2-dimethyl-4,7-dihydro-1λ4,3-dithiepine 1-oxide
    —— ethyl 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]octanoate 87733-47-9 C13H21N3O4S
    ethyl 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]octanoate
    —— Methyl 2-phenylsulfanylcyclohex-3-ene-1-carboxylate 82207-32-7 C14H16O2S
    Methyl 2-phenylsulfanylcyclohex-3-ene-1-carboxylate
    —— 2-(3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-hexanoic acid ethyl ester 87202-56-0 C11H17N3O4S
    2-(3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-hexanoic acid ethyl ester
    —— ethyl 6-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]hexanoate 75621-70-4 C11H17N3O4S
    ethyl 6-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]hexanoate
    —— t-butyl S-3,6-diisobutylpyrazin-2-ylthiolcarbonate 104272-96-0 C17H28N2O2S
    t-butyl S-3,6-diisobutylpyrazin-2-ylthiolcarbonate
    —— 3-(Bis-phenylsulfanyl-methyl)-cyclopentanone 69814-22-8 C18H18OS2
    3-(Bis-phenylsulfanyl-methyl)-cyclopentanone
    —— 4-phenylthiomethyl-5-carbethoxy-1,2,3-thiadiazole 80022-44-2 C12H12N2O2S2
    4-phenylthiomethyl-5-carbethoxy-1,2,3-thiadiazole
    —— 1-[2-(Phenylsulfanyl)cyclohex-3-en-1-yl]ethan-1-one 36715-37-4 C14H16OS
    1-[2-(Phenylsulfanyl)cyclohex-3-en-1-yl]ethan-1-one
    —— 3-(Tris(phenylthio)methyl)cyclopentanone 69814-17-1 C24H22OS3
    3-(Tris(phenylthio)methyl)cyclopentanone
    —— Dimethyl 1-(2-methylphenyl)sulfanylethenyl phosphate 5166-28-9 C11H15O4PS
    Dimethyl 1-(2-methylphenyl)sulfanylethenyl phosphate
    —— 3,4,6-Tri-methylthio-pyridazin 66234-89-7 C7H10N2S3
    3,4,6-Tri-methylthio-pyridazin
    —— N-(dicyclopropylmethyl)-S-methylisothiourea hydroiodide 1269488-04-1 C9H16N2S*HI
    N-(dicyclopropylmethyl)-S-methylisothiourea hydroiodide
    —— 4-(2,4-dinitro-phenylsulfanyl)-pyrimidine 73768-68-0 C10H6N4O4S
    4-(2,4-dinitro-phenylsulfanyl)-pyrimidine
    —— 4-methyl-1,1-bis(methylthio)-3-pentanone 155127-07-4 C8H16OS2
    4-methyl-1,1-bis(methylthio)-3-pentanone
    —— 2-Methoxycarbonylamino-7-phenylthio-imidazo<1,2-a>pyridin 64064-60-4 C15H13N3O2S
    2-Methoxycarbonylamino-7-phenylthio-imidazo<1,2-a>pyridin
    —— 2,4-Bis-(3-nitro-pyridyl-2)-pyrimidyl-2,4-dithioether 73768-64-6 C14H8N6O4S2
    2,4-Bis-(3-nitro-pyridyl-2)-pyrimidyl-2,4-dithioether
    —— 1-[3-(Diphenyl-phosphinoylmethyl)-but-3-en-1-ynyl]-4-methylsulfanyl-benzene 590422-98-3 C24H21OPS
    1-[3-(Diphenyl-phosphinoylmethyl)-but-3-en-1-ynyl]-4-methylsulfanyl-benzene
    —— 2-amino-7-phenyl-6<i>H</i>-[1,3,5]triazino[2,1-<i>b</i>][1,3,4]thiadiazin-4-ylideneamine 59894-16-5 C11H10N6S
    2-amino-7-phenyl-6<i>H</i>-[1,3,5]triazino[2,1-<i>b</i>][1,3,4]thiadiazin-4-ylideneamine
    —— 2-[1-Cyano-2,2-bis(methylsulfanyl)ethenyl]-4,6-bis(methylsulfanyl)pyrimidine-5-carbonitrile 58842-47-0 C12H12N4S4
    2-[1-Cyano-2,2-bis(methylsulfanyl)ethenyl]-4,6-bis(methylsulfanyl)pyrimidine-5-carbonitrile
    —— 6H-1,2,4-Triazolo(4,3-b)(4,1,2)benzothiadiazin-9(9aH)-one, 7,8-dihydro-3,7,7-trimethyl- 60060-31-3 C11H14N4OS
    6H-1,2,4-Triazolo(4,3-b)(4,1,2)benzothiadiazin-9(9aH)-one, 7,8-dihydro-3,7,7-trimethyl-
    —— tert-butyl 2,2-diethoxyethyl sulphone 120948-16-5 C10H22O4S
    tert-butyl 2,2-diethoxyethyl sulphone
    —— N,N'-bis-(chlorothioformyl)-N,N'-dimethyl-ethylenediamine 74683-45-7 C6H10Cl2N2S2
    N,N'-bis-(chlorothioformyl)-N,N'-dimethyl-ethylenediamine
    —— (S)-(+)-2-t-butylthio-3-methylbutanal 155996-74-0 C9H18OS
    (S)-(+)-2-t-butylthio-3-methylbutanal
    —— 5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carbothioic acid butylamide 82118-05-6 C8H15N5S2
    5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carbothioic acid butylamide
    —— 1,4-Bis(p-tolylthiocarbonyl)-piperazin 6442-95-1 C20H22N2O2S2
    1,4-Bis(p-tolylthiocarbonyl)-piperazin
    —— 2-(3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-decanoic acid ethyl ester 87202-58-2 C15H25N3O4S
    2-(3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-decanoic acid ethyl ester
    —— 1,5-methylmercapto-3,4-diformylthiophene 24444-93-7 C8H8O2S3
    1,5-methylmercapto-3,4-diformylthiophene