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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-chloro-8-(4-hydroxy-phenylthio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-12-3 C16H14ClN5O2S
    2-chloro-8-(4-hydroxy-phenylthio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(4-methoxyphenyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-18-9 C17H16ClN5O2S
    2-chloro-8-(4-methoxyphenyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 8-(4-bromophenyl-thio)-2-chloro-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-22-5 C16H13BrClN5OS
    8-(4-bromophenyl-thio)-2-chloro-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(4-chlorophenyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-20-3 C16H13Cl2N5OS
    2-chloro-8-(4-chlorophenyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 5-(2-Hydroxy-ethylsulfanyl)-3-methoxy-thiophene-2,4-dicarbonitrile 119754-44-8 C9H8N2O2S2
    5-(2-Hydroxy-ethylsulfanyl)-3-methoxy-thiophene-2,4-dicarbonitrile
    —— 5-Isopropylsulfanyl-3-methoxy-thiophene-2,4-dicarbonitrile 119754-47-1 C10H10N2OS2
    5-Isopropylsulfanyl-3-methoxy-thiophene-2,4-dicarbonitrile
    —— (S)-methyl 2-methyl-3-methylthiomethoxypropionate 116021-14-8 C7H14O3S
    (S)-methyl 2-methyl-3-methylthiomethoxypropionate
    —— 2,4-dicyano-3-methoxy-5-methylthiothiophene 116170-80-0 C8H6N2OS2
    2,4-dicyano-3-methoxy-5-methylthiothiophene
    —— 2-chloro-8-(2-fluorobenzyl-thio)-4-(1-oxido-thiomorpholino)-pyrimido-[5,4-d]-pyrimidine 77749-30-5 C17H15ClFN5OS2
    2-chloro-8-(2-fluorobenzyl-thio)-4-(1-oxido-thiomorpholino)-pyrimido-[5,4-d]-pyrimidine
    —— 2,4-dicyano-4-hydroxy-5-methylthiothiophene 116170-79-7 C7H4N2OS2
    2,4-dicyano-4-hydroxy-5-methylthiothiophene
    —— 2-chloro-8-(α-methyl-4-methylthiobenzyl-thio)-4-(1-oxido-thiomorpholino)-pyrimido-[5,4-d]-pyrimidine 77749-45-2 C19H20ClN5OS3
    2-chloro-8-(α-methyl-4-methylthiobenzyl-thio)-4-(1-oxido-thiomorpholino)-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-4-(1-oxido-thiomorpholino)-8-(4-tolyl-thio)-pyrimido-[5,4-d]-pyrimidine 77749-27-0 C17H16ClN5OS2
    2-chloro-4-(1-oxido-thiomorpholino)-8-(4-tolyl-thio)-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(4-hydroxyphenyl-thio)-4-(1-oxido-thiomorpholino)-pyrimido-[5,4-d]-pyrimidine 77749-25-8 C16H14ClN5O2S2
    2-chloro-8-(4-hydroxyphenyl-thio)-4-(1-oxido-thiomorpholino)-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(3-fluorobenzyl-thio)-4-(1-oxido-thiomorpholino)-pyrimido-[5,4-d]-pyrimidine 77749-31-6 C17H15ClFN5OS2
    2-chloro-8-(3-fluorobenzyl-thio)-4-(1-oxido-thiomorpholino)-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(2-fluorobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-28-1 C17H15ClFN5OS
    2-chloro-8-(2-fluorobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— Butyl-cyclohexyl-sulfid 7133-40-6 C10H20S
    Butyl-cyclohexyl-sulfid
    —— 6-Benzylthio-3<2-(N-methyl-N-prop-2-inylamino)ethylamino>-1,2,4,5-tetrazin 144582-94-5 C15H18N6S
    6-Benzylthio-3<2-(N-methyl-N-prop-2-inylamino)ethylamino>-1,2,4,5-tetrazin
    —— 2-chloro-8-(3-fluorobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-29-2 C17H15ClFN5OS
    2-chloro-8-(3-fluorobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(2-chlorobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-32-7 C17H15Cl2N5OS
    2-chloro-8-(2-chlorobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 2-chloro-8-(α-methyl-4-methylthiobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77749-44-1 C19H20ClN5OS2
    2-chloro-8-(α-methyl-4-methylthiobenzyl-thio)-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— N-[3,4-dihydro-1,5-benzoxathiepin-3-yl]-(R)-(3-hydroxy-2-(R)-methyl)propionamide 1169760-41-1 C13H17NO3S
    N-[3,4-dihydro-1,5-benzoxathiepin-3-yl]-(R)-(3-hydroxy-2-(R)-methyl)propionamide
    —— [2-[p-(p-chlorophenylmercapto)phenoxy]-ethyl] N-ethylcarbamate 85983-33-1 C17H18ClNO3S
    [2-[p-(p-chlorophenylmercapto)phenoxy]-ethyl] N-ethylcarbamate
    —— Sulfamoyl azide, methyl- 33581-88-3 CH4N4O2S
    Sulfamoyl azide, methyl-
    —— 4-(2-bromopropan-2-yl)-4,5-dihydro-2,4'-bithiazole 1581731-05-6 C9H11BrN2S2
    4-(2-bromopropan-2-yl)-4,5-dihydro-2,4'-bithiazole
    —— N-(5-cyano-2-methylsulfanyl-pyrimidin-4-yl)-N-methyl-acetamide 1192132-71-0 C9H10N4OS
    N-(5-cyano-2-methylsulfanyl-pyrimidin-4-yl)-N-methyl-acetamide
    —— N,N-Dimethyl-thiocarbamidsaeure-S-vinylester 89417-21-0 C5H9NOS
    N,N-Dimethyl-thiocarbamidsaeure-S-vinylester
    —— tert-butyl benzyl[2-[4-[(4-hydroxyphenyl)thio]phenyl]ethyl]carbamate 477256-62-5 C26H29NO3S
    tert-butyl benzyl[2-[4-[(4-hydroxyphenyl)thio]phenyl]ethyl]carbamate
    —— N,N-Dimethylthiocarbaminsaeure-O-allylester 5513-30-4 C6H11NOS
    N,N-Dimethylthiocarbaminsaeure-O-allylester
    —— 3-Phenylthiopropylisocyanat 32768-06-2 C10H11NS2
    3-Phenylthiopropylisocyanat
    —— 4,6-dimethylpyrimidin-2-yl dimethylcarbamodithioate 32595-22-5 C9H13N3S2
    4,6-dimethylpyrimidin-2-yl dimethylcarbamodithioate
    —— O-[(2S,3S)-3-(trimethylsilyl)oxiran-2-yl]methyl dimethylthiocarbamate 1236009-41-8 C9H19NO2SSi
    O-[(2S,3S)-3-(trimethylsilyl)oxiran-2-yl]methyl dimethylthiocarbamate
    —— Dimethyl-thiocarbamic acid S-(3-methyl-but-2-enyl) ester 39707-44-3 C8H15NOS
    Dimethyl-thiocarbamic acid S-(3-methyl-but-2-enyl) ester
    —— 1-(2-Methylsulfanyl-ethylsulfanyl)-pentane 112173-31-6 C8H18S2
    1-(2-Methylsulfanyl-ethylsulfanyl)-pentane
    —— 2-{5-[(3-chloropropyl)sulfanyl]-4-methyl-4H-1,2,4-triazol-3-yl}-5-methylpyrazine 1016231-48-3 C11H14ClN5S
    2-{5-[(3-chloropropyl)sulfanyl]-4-methyl-4H-1,2,4-triazol-3-yl}-5-methylpyrazine
    —— 4-[(4-bromo-3,4,4-trifluorobutyl)thio]-6-(2,2,2-trifluoroethoxy)-pyrimidin 155957-67-8 C10H9BrF6N2OS
    4-[(4-bromo-3,4,4-trifluorobutyl)thio]-6-(2,2,2-trifluoroethoxy)-pyrimidin
    —— 7-(butylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide 494226-35-6 C11H14N4OS
    7-(butylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide
    —— 2-(5-Chlor-2-methyl-phenylmercapto)-3-carboxy-pyridin 92044-48-9 C13H10ClNO2S
    2-(5-Chlor-2-methyl-phenylmercapto)-3-carboxy-pyridin
    —— Phenylsulfanyl-acetic acid butyl ester 66132-81-8 C12H16O2S
    Phenylsulfanyl-acetic acid butyl ester
    —— 2-chloro-6-(5-nitro-thiazol-2-ylsulfanyl)-pyrazine 1-oxide 72567-33-0 C7H3ClN4O3S2
    2-chloro-6-(5-nitro-thiazol-2-ylsulfanyl)-pyrazine 1-oxide
    —— 3-[(1,3-dimethyl-4-vinyl-1H-pyrazol-5-yl)thio]phenol 1043919-28-3 C13H14N2OS
    3-[(1,3-dimethyl-4-vinyl-1H-pyrazol-5-yl)thio]phenol
    —— 5-(4-Fluoro-phenyl)-3-(2-pyrrolidin-1-yl-ethylsulfanyl)-[1,2,4]triazine 87992-23-2 C15H17FN4S
    5-(4-Fluoro-phenyl)-3-(2-pyrrolidin-1-yl-ethylsulfanyl)-[1,2,4]triazine
    —— 3-(3-((6-(phenylthio)pyridin-3-yl)methyl)isoxazol-5-yl)pyridin-2-amine 936340-71-5 C20H16N4OS
    3-(3-((6-(phenylthio)pyridin-3-yl)methyl)isoxazol-5-yl)pyridin-2-amine
    —— (6-phenylsulfanyl-pyridin-3-yl)-acetohydroximoyl chloride 936344-40-0 C13H11ClN2OS
    (6-phenylsulfanyl-pyridin-3-yl)-acetohydroximoyl chloride
    —— 2-[(prop-2-en-1-yl)sulfanyl]benzoselenazole 1379002-21-7 C10H9NSSe
    2-[(prop-2-en-1-yl)sulfanyl]benzoselenazole
    —— 1,4-bis<3-(2,4-dinitrophenylmercapto)-4-phenyl-1,2,4-triazol-5-yl>butane 116987-07-6 C32H22N12O12S2
    1,4-bis<3-(2,4-dinitrophenylmercapto)-4-phenyl-1,2,4-triazol-5-yl>butane
    —— 3-(4-chlorophenyl)-5,6-dimethyl-2-(methylthio)pyrimidin-4(3H)-one 1093750-79-8 C13H13ClN2OS
    3-(4-chlorophenyl)-5,6-dimethyl-2-(methylthio)pyrimidin-4(3H)-one
    —— 2-isopropylthio-3-hydroxypyridine 145099-52-1 C8H11NOS
    2-isopropylthio-3-hydroxypyridine
    —— acetylsulfenic acid methyl ester 128250-42-0 C3H6O2S
    acetylsulfenic acid methyl ester
    —— 2-(ethylsulfanyl)benzoselenazole 38159-30-7 C9H9NSSe
    2-(ethylsulfanyl)benzoselenazole
    —— 1,1-diethyl-2,3-diphenyl-isothiourea 1329430-11-6 C17H20N2S
    1,1-diethyl-2,3-diphenyl-isothiourea