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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-(3,5-Dichlorophenylthio)-2-dimethylaminomethyl-4-isopropyl-1-methyl-1H-imidazole 178979-69-6 C16H21Cl2N3S
    5-(3,5-Dichlorophenylthio)-2-dimethylaminomethyl-4-isopropyl-1-methyl-1H-imidazole
    —— 5-ethyl-1-ethoxymethyl-6-(3,5-dimethylphenylthio)uracil 136011-44-4 C17H22N2O3S
    5-ethyl-1-ethoxymethyl-6-(3,5-dimethylphenylthio)uracil
    —— 1-Benzyl-2-carbamoyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole 178979-35-6 C21H21Cl2N3O2S
    1-Benzyl-2-carbamoyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole
    —— 5-(3,5-Dichlorophenylthio)-2-carbamoyloxymethyl-4-isopropyl-1-(pyridin-3-ylmethyl)-1H-imidazole 178979-83-4 C20H20Cl2N4O2S
    5-(3,5-Dichlorophenylthio)-2-carbamoyloxymethyl-4-isopropyl-1-(pyridin-3-ylmethyl)-1H-imidazole
    —— 2-Aminomethyl-4-isopropyl-1-methyl-5-phenylthio-1H-imidazole 178979-65-2 C14H19N3S
    2-Aminomethyl-4-isopropyl-1-methyl-5-phenylthio-1H-imidazole
    —— 3-(5-(3,5-dichlorophenylthio)-1-(2-hydroxyethyl)-4-isopropyl-1H-imidazol-2-yl)-propan-1-ol 178980-57-9 C17H22Cl2N2O2S
    3-(5-(3,5-dichlorophenylthio)-1-(2-hydroxyethyl)-4-isopropyl-1H-imidazol-2-yl)-propan-1-ol
    —— 1H-Imidazole-2-ethanol, 1-((3-aminophenyl)methyl)-5-((3,5-dichlorophenyl)thio)-4-(1-methylethyl)- 178980-35-3 C21H23Cl2N3OS
    1H-Imidazole-2-ethanol, 1-((3-aminophenyl)methyl)-5-((3,5-dichlorophenyl)thio)-4-(1-methylethyl)-
    —— 2-phenylthiomethyl-3(S)-hydroxymethyl-4(S)-pentyl-γ-butyrolactone 777097-32-2 C17H24O3S
    2-phenylthiomethyl-3(S)-hydroxymethyl-4(S)-pentyl-γ-butyrolactone
    —— 5-(4-chlorobenzylthio)pyridazin-3(2H)-one 1243253-45-3 C11H9ClN2OS
    5-(4-chlorobenzylthio)pyridazin-3(2H)-one
    —— (Z)-1-cyclohexyl-2-phenylsulfanylhept-2-en-1-one 206278-56-0 C19H26OS
    (Z)-1-cyclohexyl-2-phenylsulfanylhept-2-en-1-one
    —— 2-But-3-enylsulfinylacetic acid 720719-10-8 C6H10O3S
    2-But-3-enylsulfinylacetic acid
    —— (Z)-2,2-dimethyl-4-phenylsulfanylnon-4-en-3-one 206278-57-1 C17H24OS
    (Z)-2,2-dimethyl-4-phenylsulfanylnon-4-en-3-one
    —— 4(1H)-Pyrimidinone, 2-chloro-6-(phenylthio)- 284682-02-6 C10H7ClN2OS
    4(1H)-Pyrimidinone, 2-chloro-6-(phenylthio)-
    —— (2S,3R)-5-oxo-2-pentyl-4-(phenylsulfanylmethyl)oxolane-3-carboxylic acid 1027976-62-0 C17H22O4S
    (2S,3R)-5-oxo-2-pentyl-4-(phenylsulfanylmethyl)oxolane-3-carboxylic acid
    —— 1,2,3,5,6-Pentathiepane, 4,7-dimethyl- 101517-94-6 C4H8S5
    1,2,3,5,6-Pentathiepane, 4,7-dimethyl-
    —— 1-methyl-2-chloro-3-phenylthioindole 108698-59-5 C15H12ClNS
    1-methyl-2-chloro-3-phenylthioindole
    —— [2-(5-fluoro-1H-indol-3-ylsulfanyl)-benzyl]-carbamic acid tert-butyl ester 857499-96-8 C20H21FN2O2S
    [2-(5-fluoro-1H-indol-3-ylsulfanyl)-benzyl]-carbamic acid tert-butyl ester
    —— 2-(5-fluoro-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 857499-93-5 C16H12FNO2S
    2-(5-fluoro-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester
    —— methyl-(1-methylsulfanyl-ethyl)-disulfane 4413-29-0 C4H10S3
    methyl-(1-methylsulfanyl-ethyl)-disulfane
    —— (4R,5S)-4-<Tris(phenylthio)methyl>-5-pentyl-4,5-dihydro-2(3H)-furanone 165605-80-1 C28H30O2S3
    (4R,5S)-4-<Tris(phenylthio)methyl>-5-pentyl-4,5-dihydro-2(3H)-furanone
    —— 2-(7-bromo-3,5-dioxaheptylthio)-6-(3,5-dimethylbenzyl)-5-ethyl-pyrimidin-4(3H)-one 261899-98-3 C20H27BrN2O3S
    2-(7-bromo-3,5-dioxaheptylthio)-6-(3,5-dimethylbenzyl)-5-ethyl-pyrimidin-4(3H)-one
    —— 4-(3-Fluorobenzyl)-piperazine-1-carboxylic acid 4-(4,6-dimethyl-pyrimidin-2-ylsulfanyl)-phenyl ester 548768-72-5 C24H25FN4O2S
    4-(3-Fluorobenzyl)-piperazine-1-carboxylic acid 4-(4,6-dimethyl-pyrimidin-2-ylsulfanyl)-phenyl ester
    —— 2-Ethylthio-3-methyl-5-(2-methylbutyl)pyrazine 99784-28-8 C12H20N2S
    2-Ethylthio-3-methyl-5-(2-methylbutyl)pyrazine
    —— 3,3,4,4,5,5,6,6,7,7-Decafluoro-1,2-dithiepane 24345-54-8 C5F10S2
    3,3,4,4,5,5,6,6,7,7-Decafluoro-1,2-dithiepane
    —— 4-(4,6-dimethyl-pyrimidin-2-ylsulfanyl)-phenyl chloroformate 548768-73-6 C13H11ClN2O2S
    4-(4,6-dimethyl-pyrimidin-2-ylsulfanyl)-phenyl chloroformate
    —— 3,7-dimethyl-2(E),5(E),7-octatrienyl (phenylthio)acetate 87519-46-8 C18H22O2S
    3,7-dimethyl-2(E),5(E),7-octatrienyl (phenylthio)acetate
    —— 2-[5-(benzylthio)-1,3,4-oxadiazol-2-yl]-N-{4-[5-(benzylthio)-1,3,4-oxadiazol-2-yl]phenyl}aniline 1245567-63-8 C30H23N5O2S2
    2-[5-(benzylthio)-1,3,4-oxadiazol-2-yl]-N-{4-[5-(benzylthio)-1,3,4-oxadiazol-2-yl]phenyl}aniline
    —— 2-[5-(ethylthio)-1,3,4-oxadiazol-2-yl]-N-{4-[5-(ethylthio)-1,3,4-oxadiazol-2-yl]phenyl}aniline 1245567-50-3 C20H19N5O2S2
    2-[5-(ethylthio)-1,3,4-oxadiazol-2-yl]-N-{4-[5-(ethylthio)-1,3,4-oxadiazol-2-yl]phenyl}aniline
    —— 2-[5-(allylthio)-1,3,4-oxadiazol-2-yl]-N-{4-[5-(allylthio)-1,3,4-oxadiazol-2-yl]phenyl}aniline 1245567-64-9 C22H19N5O2S2
    2-[5-(allylthio)-1,3,4-oxadiazol-2-yl]-N-{4-[5-(allylthio)-1,3,4-oxadiazol-2-yl]phenyl}aniline
    —— ethylxanthic acid hydroxymethyl ester 42192-51-8 C4H8O2S2
    ethylxanthic acid hydroxymethyl ester
    —— 4-amino-2,3-dihydro-2-methyl-6-thioxo-6H-thieno[3,2-c]thiopyran-7-carbonitrile 1222510-77-1 C9H8N2S3
    4-amino-2,3-dihydro-2-methyl-6-thioxo-6H-thieno[3,2-c]thiopyran-7-carbonitrile
    —— 3-Methylmercapto-5-methoxy-6-phenyltriazin 37526-35-5 C11H11N3OS
    3-Methylmercapto-5-methoxy-6-phenyltriazin
    —— (1'S,2R,6S,7R,9R,15S)-15-(1-Hydroxyprop-2-enyl)-2,9-bis(phenylthiomethyl)-1,8,13,16-tetraoxadispiro<5.0.5.4>hexadecan-14-one 244155-61-1 C29H34O6S2
    (1'S,2R,6S,7R,9R,15S)-15-(1-Hydroxyprop-2-enyl)-2,9-bis(phenylthiomethyl)-1,8,13,16-tetraoxadispiro<5.0.5.4>hexadecan-14-one
    —— N-[(5-ethylsulfanyl-1,3,4-oxadiazol-2-yl)methyl]aniline 436095-96-4 C11H13N3OS
    N-[(5-ethylsulfanyl-1,3,4-oxadiazol-2-yl)methyl]aniline
    —— 2-Methyl-3-[4-[5-[[5-[4-(2-methyl-4-oxoquinazolin-3-yl)phenyl]-4-phenyl-1,2,4-triazol-3-yl]sulfanyl]-4-phenyl-1,2,4-triazol-3-yl]phenyl]quinazolin-4-one 139447-60-2 C46H32N10O2S
    2-Methyl-3-[4-[5-[[5-[4-(2-methyl-4-oxoquinazolin-3-yl)phenyl]-4-phenyl-1,2,4-triazol-3-yl]sulfanyl]-4-phenyl-1,2,4-triazol-3-yl]phenyl]quinazolin-4-one
    —— (E)-3-methyl-4-[2-(2-methylprop-1-enyl)-1,3-dithian-2-yl]but-2-en-1-ol 1184635-39-9 C13H22OS2
    (E)-3-methyl-4-[2-(2-methylprop-1-enyl)-1,3-dithian-2-yl]but-2-en-1-ol
    —— 2,4-bis(trifluoroacetyl)-1-(4-methylphenylthio)naphthalene 127053-15-0 C21H12F6O2S
    2,4-bis(trifluoroacetyl)-1-(4-methylphenylthio)naphthalene
    —— 2-(2-chloro-4-nitro-phenylsulfanyl)-benzothiazol-5-carboxylic acid 315228-83-2 C14H7ClN2O4S2
    2-(2-chloro-4-nitro-phenylsulfanyl)-benzothiazol-5-carboxylic acid
    —— (4-Methyl-pyrimidin-2-ylsulfanyl)-phenyl-acetic acid 87125-93-7 C13H12N2O2S
    (4-Methyl-pyrimidin-2-ylsulfanyl)-phenyl-acetic acid
    —— Propyl 2-(6-amino-3,5-dicyano-4-ethylpyridin-2-yl)sulfanylacetate 184530-26-5 C14H16N4O2S
    Propyl 2-(6-amino-3,5-dicyano-4-ethylpyridin-2-yl)sulfanylacetate
    —— 5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,8,12-pentaene 111610-02-7 C10H10N4S4
    5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,8,12-pentaene
    —— (1R)-2-{[tert-butyl(dimethyl)silyl]oxy}-1-phenyl-N-[(phenylthio)methyl]ethanamine 1030828-95-5 C21H31NOSSi
    (1R)-2-{[tert-butyl(dimethyl)silyl]oxy}-1-phenyl-N-[(phenylthio)methyl]ethanamine
    —— 9-methyl-5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,8,12-pentaene 111610-03-8 C11H12N4S4
    9-methyl-5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,8,12-pentaene
    —— 1,5-dimethyl-2,6-bis(phenylthio)bicyclo<3.3.0>octa-2,6-diene 139462-71-8 C22H22S2
    1,5-dimethyl-2,6-bis(phenylthio)bicyclo<3.3.0>octa-2,6-diene
    —— 5,13-bis(methylsulfanyl)-N-phenyl-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,8,12-pentaen-9-amine 111609-98-4 C16H15N5S4
    5,13-bis(methylsulfanyl)-N-phenyl-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,8,12-pentaen-9-amine
    —— N-tert-butyl-6-methylsulfanylpyridazine-3-carbothioamide 457613-22-8 C10H15N3S2
    N-tert-butyl-6-methylsulfanylpyridazine-3-carbothioamide
    —— 9-ethyl-5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,8,12-pentaene 111610-04-9 C12H14N4S4
    9-ethyl-5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,8,12-pentaene
    —— 5,13-Bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,12-tetraene-9-thione 111609-94-0 C10H10N4S5
    5,13-Bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,12-tetraene-9-thione
    —— N-ethyl-5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,12-tetraen-9-imine 111622-79-8 C12H15N5S4
    N-ethyl-5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,12-tetraen-9-imine
    —— N-methyl-5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,12-tetraen-9-imine 111609-97-3 C11H13N5S4
    N-methyl-5,13-bis(methylsulfanyl)-4,14-dithia-6,8,10,12-tetrazatricyclo[9.3.0.03,7]tetradeca-1(11),3(7),5,12-tetraen-9-imine