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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1,1,3,3,7,7,9,9-octamethyl-5,10-dithiadispiro[3.1.3.2]undecane-2,8-dione 23604-63-9 C17H26O2S2
    1,1,3,3,7,7,9,9-octamethyl-5,10-dithiadispiro[3.1.3.2]undecane-2,8-dione
    —— 2',2',4',4',6,6-hexamethyl-6,7-dihydrospiro-[1,3-benzoxathiole-2,1'-cyclobutane]-3',4(5H)-dione 1450644-23-1 C16H22O3S
    2',2',4',4',6,6-hexamethyl-6,7-dihydrospiro-[1,3-benzoxathiole-2,1'-cyclobutane]-3',4(5H)-dione
    —— 4-amino-3-allylthio-6-methyl-4H-1,2,4-triazin-5-one 220637-24-1 C7H10N4OS
    4-amino-3-allylthio-6-methyl-4H-1,2,4-triazin-5-one
    —— 2,3-Dimethyl-4-thiaoctane 66481-80-9 C9H20S
    2,3-Dimethyl-4-thiaoctane
    —— nonyl-propyl sulfide 62103-66-6 C12H26S
    nonyl-propyl sulfide
    —— 6-Thiadodecane 62103-67-7 C11H24S
    6-Thiadodecane
    —— Trithiacyclohexene 210237-55-1 C4H6S2
    Trithiacyclohexene
    —— Pyrazine, 3-methylthio-2-pentyl 113685-87-3 C10H16N2S
    Pyrazine, 3-methylthio-2-pentyl
    —— Isoamyl-n-amylsulfid 7352-01-4 C10H22S
    Isoamyl-n-amylsulfid
    —— 2,3-Dimethyl-4,5-dithiaoctane 72437-67-3 C8H18S2
    2,3-Dimethyl-4,5-dithiaoctane
    —— ethyl 2-(4-bromo-3-chlorophenylthio)acetate 1308279-94-8 C10H10BrClO2S
    ethyl 2-(4-bromo-3-chlorophenylthio)acetate
    —— 1-hydroxy-3-phenylthio-2-propanone 97798-47-5 C9H10O2S
    1-hydroxy-3-phenylthio-2-propanone
    —— 1,3-Dithiolo[4,5-b]furan, tetrahydro-3a-methyl- 67411-25-0 C6H10OS2
    1,3-Dithiolo[4,5-b]furan, tetrahydro-3a-methyl-
    —— 2-Allyl-2-phenylsulfanylmethyl-oxirane 159099-53-3 C12H14OS
    2-Allyl-2-phenylsulfanylmethyl-oxirane
    —— (5R,6R,9S)-9-Hydroxy-1-oxo-6-p-tolylsulfanyl-2-oxa-spiro[4.5]dec-7-ene-6-carboxylic acid methyl ester 141510-37-4 C18H20O5S
    (5R,6R,9S)-9-Hydroxy-1-oxo-6-p-tolylsulfanyl-2-oxa-spiro[4.5]dec-7-ene-6-carboxylic acid methyl ester
    —— dichloroplatinum;ethene;methylsulfinylmethane 31902-28-0 C4H10Cl2OPtS
    dichloroplatinum;ethene;methylsulfinylmethane
    —— 5-Isopropyl-3-methyl-2-(methylthio)pyrazine 99784-22-2 C9H14N2S
    5-Isopropyl-3-methyl-2-(methylthio)pyrazine
    —— Pyrazine, 2-(methylthio)-3-propyl- 68560-83-8 C8H12N2S
    Pyrazine, 2-(methylthio)-3-propyl-
    —— 2,2-bis(ethylthio)acetimidamide 1196536-37-4 C6H14N2S2
    2,2-bis(ethylthio)acetimidamide
    —— 3-Methyl-5-(2-methylpentyl)-2-(methylthio)pyrazine 78246-18-1 C12H20N2S
    3-Methyl-5-(2-methylpentyl)-2-(methylthio)pyrazine
    —— Methyl propyl tetrasulphide 87148-08-1 C4H10S4
    Methyl propyl tetrasulphide
    —— 1-(Propylthio)propyl methyl disulfide 126876-21-9 C7H16S3
    1-(Propylthio)propyl methyl disulfide
    —— 8-N-(cyclopropylmethyl)-4-N-(2-methylsulfanylphenyl)-2-(4-piperazin-1-ylpiperidin-1-yl)pyrimido[5,4-d]pyrimidine-4,8-diamine 1392889-18-7 C26H35N9S
    8-N-(cyclopropylmethyl)-4-N-(2-methylsulfanylphenyl)-2-(4-piperazin-1-ylpiperidin-1-yl)pyrimido[5,4-d]pyrimidine-4,8-diamine
    —— 3-(Phenylthio)methyl-2-oxolanon 54353-61-6 C11H12O2S
    3-(Phenylthio)methyl-2-oxolanon
    —— 1-(2-Hydroxyethylthio)-2-(vinylthio)ethane 114811-37-9 C6H12OS2
    1-(2-Hydroxyethylthio)-2-(vinylthio)ethane
    —— (+)-n-hexadecyl methyl sulfoxide —— C17H36OS
    (+)-n-hexadecyl methyl sulfoxide
    —— 1,2,4,6-Tetrathiepane, 3,5,7-trimethyl- 115421-49-3 C6H12S4
    1,2,4,6-Tetrathiepane, 3,5,7-trimethyl-
    —— Dimethyl-(1-phenyl-but-3-enyl)-(1-phenylsulfanyl-cyclopropyl)-silane 166672-27-1 C21H26SSi
    Dimethyl-(1-phenyl-but-3-enyl)-(1-phenylsulfanyl-cyclopropyl)-silane
    —— Dimethyl-(1-phenyl-ethyl)-(1-phenylsulfanyl-cyclopropyl)-silane 166672-26-0 C19H24SSi
    Dimethyl-(1-phenyl-ethyl)-(1-phenylsulfanyl-cyclopropyl)-silane
    —— 3-(((4-aminophenyl)thio)methyl)dihydrofuran-2(3H)-one 1621103-93-2 C11H13NO2S
    3-(((4-aminophenyl)thio)methyl)dihydrofuran-2(3H)-one
    —— 12-methyl-4,6-dioxa-12-azabicyclo<7.2.1>dodecane-5-thione 127655-03-2 C10H17NO2S
    12-methyl-4,6-dioxa-12-azabicyclo<7.2.1>dodecane-5-thione
    —— 5-Isobutyl-3-methyl-2-(methylthio)pyrazine 78246-17-0 C10H16N2S
    5-Isobutyl-3-methyl-2-(methylthio)pyrazine
    —— hexyl-hydroxymethyl sulfone 860248-10-8 C7H16O3S
    hexyl-hydroxymethyl sulfone
    —— (Phenylthio)acetic acid, hexadecyl ester 915696-54-7 C24H40O2S
    (Phenylthio)acetic acid, hexadecyl ester
    —— Thiophosphoric acid S-{N-[1-(4-methylsulfanyl-phenyl)-adamantan-2-ylmethyl]-carbamimidoylmethyl} ester 117077-36-8 C20H29N2O3PS2
    Thiophosphoric acid S-{N-[1-(4-methylsulfanyl-phenyl)-adamantan-2-ylmethyl]-carbamimidoylmethyl} ester
    —— (Phenylthio)acetic acid, 2-phenylethyl ester 959228-28-5 C16H16O2S
    (Phenylthio)acetic acid, 2-phenylethyl ester
    —— (E)-2-(4-chloro-phenylsulfanyl)hex-2-en-1-ol 1217367-21-9 C12H15ClOS
    (E)-2-(4-chloro-phenylsulfanyl)hex-2-en-1-ol
    —— N-Acetyliminodiethylsulfuran 32805-46-2 C6H13NOS
    N-Acetyliminodiethylsulfuran
    —— 2-<(phenylmethyl)thio>barbituric acid 148020-95-5 C11H10N2O2S
    2-<(phenylmethyl)thio>barbituric acid
    —— 3-Chlor-endo-6-(phenylthio)bicyclo<3.1.1>hept-2-en 102870-57-5 C13H13ClS
    3-Chlor-endo-6-(phenylthio)bicyclo<3.1.1>hept-2-en
    —— 3-bromo-6-methyl-4-(4-methylthio)phenyl-pyran-2-one 387866-31-1 C13H11BrO2S
    3-bromo-6-methyl-4-(4-methylthio)phenyl-pyran-2-one
    —— 2-[(4-chloro-phenylsulfanyl)-(2,3,6-trifluoro-phenyl)-methyl]-propane-1,3-diol 944950-53-2 C16H14ClF3O2S
    2-[(4-chloro-phenylsulfanyl)-(2,3,6-trifluoro-phenyl)-methyl]-propane-1,3-diol
    —— (6-Phenylsulfanyl-5-trifluoromethylpyridin-3-yl)carbamic acid, prop-2-ynyl ester 685112-59-8 C16H11F3N2O2S
    (6-Phenylsulfanyl-5-trifluoromethylpyridin-3-yl)carbamic acid, prop-2-ynyl ester
    —— Thiohydroxylamin-S-thiocarbonsaeure-O-butylester 35659-81-5 C5H11NOS2
    Thiohydroxylamin-S-thiocarbonsaeure-O-butylester
    —— 6-methyl-4-(4-methylthio)phenyl-3-phenyl-pyran-2-one 387866-34-4 C19H16O2S
    6-methyl-4-(4-methylthio)phenyl-3-phenyl-pyran-2-one
    —— (E)-2-(p-tolylsulfanyl)hex-2-en-1-ol 1217367-23-1 C13H18OS
    (E)-2-(p-tolylsulfanyl)hex-2-en-1-ol
    —— 3-(3-fluorophenyl)-6-methyl-4-(4-methylthio)phenyl-pyran-2-one 387866-33-3 C19H15FO2S
    3-(3-fluorophenyl)-6-methyl-4-(4-methylthio)phenyl-pyran-2-one
    —— 10<i>H</i>-dipyridazino[4,5-<i>b</i>;4',5'-<i>e</i>][1,4]thiazin-1-ylamine 55271-66-4 C8H6N6S
    10<i>H</i>-dipyridazino[4,5-<i>b</i>;4',5'-<i>e</i>][1,4]thiazin-1-ylamine
    —— 3-phenyl-3<i>H</i>,10<i>H</i>-dipyridazino[4,5-<i>b</i>;4',5'-<i>e</i>][1,4]thiazin-4-one 55271-59-5 C14H9N5OS
    3-phenyl-3<i>H</i>,10<i>H</i>-dipyridazino[4,5-<i>b</i>;4',5'-<i>e</i>][1,4]thiazin-4-one
    —— (E)-2-(phenylsulfanyl)hex-2-en-1-ol 1217367-22-0 C12H16OS
    (E)-2-(phenylsulfanyl)hex-2-en-1-ol