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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-(5,5-Dimethyl-6-hydroxy-hexyl-sulfanyl)-2,2-dimethyl-hexan-1-ol 412934-88-4 C16H34O2S
    6-(5,5-Dimethyl-6-hydroxy-hexyl-sulfanyl)-2,2-dimethyl-hexan-1-ol
    —— 4-(4-methoxyphenylthio)-6-(4-methylpiperazin-1-ylmethyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene 1321891-29-5 C22H26N4OS2
    4-(4-methoxyphenylthio)-6-(4-methylpiperazin-1-ylmethyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene
    —— 4-(4-chlorophenylthio)-6-(4-methylpiperazin-1-ylmethyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene 1321891-26-2 C21H23ClN4S2
    4-(4-chlorophenylthio)-6-(4-methylpiperazin-1-ylmethyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene
    —— 4-(4-fluorophenylthio)-6-(4-methylpiperazin-1-yl-methyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene 1321891-40-0 C21H23FN4S2
    4-(4-fluorophenylthio)-6-(4-methylpiperazin-1-yl-methyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene
    —— 4-(4-methoxyphenylthio)-6-(4-ethylpiperazin-1-yl-methyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene 1321891-33-1 C23H28N4OS2
    4-(4-methoxyphenylthio)-6-(4-ethylpiperazin-1-yl-methyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene
    —— 4-(4-chlorophenylthio)-6-(4-ethylpiperazin-1-ylmethyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene 1321891-25-1 C22H25ClN4S2
    4-(4-chlorophenylthio)-6-(4-ethylpiperazin-1-ylmethyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene
    —— 4-(phenylthio)-6-(4-methylpiperazin-1-ylmethyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene 1321891-27-3 C21H24N4S2
    4-(phenylthio)-6-(4-methylpiperazin-1-ylmethyl)-2,3-dihydro-1H-8-thia-5,7-diazacyclopenta[a]indene
    —— (3-methyl-4-methylsulfanyl-phenyl)-acetic acid methyl ester 1003013-66-8 C11H14O2S
    (3-methyl-4-methylsulfanyl-phenyl)-acetic acid methyl ester
    —— 4-[(4-methylphenyl)thio]thieno[3,2-c]pyridine-2-carbonitrile 251996-27-7 C15H10N2S2
    4-[(4-methylphenyl)thio]thieno[3,2-c]pyridine-2-carbonitrile
    —— 3-mercapto-2-methylpropan-1-ol 76938-91-5 C4H10OS
    3-mercapto-2-methylpropan-1-ol
    —— tert-butyl vinyl sulfoxide 42779-15-7 C6H12OS
    tert-butyl vinyl sulfoxide
    —— 1-Methyl-3-(methylsulfanyl)-1H-1,2,4-triazol-5-yl(phenyl)cyanamide 95113-09-0 C11H11N5S
    1-Methyl-3-(methylsulfanyl)-1H-1,2,4-triazol-5-yl(phenyl)cyanamide
    —— 1-(3-bromo-2,2-dimethylpropyl)-2-phenylthiobenzimidazole 202346-07-4 C18H19BrN2S
    1-(3-bromo-2,2-dimethylpropyl)-2-phenylthiobenzimidazole
    —— 3-((6-oxo-1,6-dihydropyrimidin-2-yl)thio)-N-(trans-4-(5-phenyl-1,3,4-oxadiazol-2-yl)cyclohexyl)propanamide 1507362-03-9 C21H23N5O3S
    3-((6-oxo-1,6-dihydropyrimidin-2-yl)thio)-N-(trans-4-(5-phenyl-1,3,4-oxadiazol-2-yl)cyclohexyl)propanamide
    —— methylsulphoxide 874130-97-9 CH4OS
    methylsulphoxide
    —— 3-methyl-6-(phenylthio)pyrimidine-2,4(1H,3H)-dione 69139-08-8 C11H10N2O2S
    3-methyl-6-(phenylthio)pyrimidine-2,4(1H,3H)-dione
    —— (3,5-Dibromo-thien-2-ylthio)-acetic Acid 58386-15-5 C6H4Br2O2S2
    (3,5-Dibromo-thien-2-ylthio)-acetic Acid
    —— 3-Brom-2,2-dimethylpropylphenylsulfid 16462-87-6 C11H15BrS
    3-Brom-2,2-dimethylpropylphenylsulfid
    —— 3,3-Dimethyl-thietan-1,1-dioxid 27832-56-0 C5H10O2S
    3,3-Dimethyl-thietan-1,1-dioxid
    —— 3,3-dimethyl-1,5-benzodithiepene 28035-14-5 C11H14S2
    3,3-dimethyl-1,5-benzodithiepene
    —— 1-(3-bromo-2,2-dimethylpropyl)-2-phenylthio-1H-indole 202346-03-0 C19H20BrNS
    1-(3-bromo-2,2-dimethylpropyl)-2-phenylthio-1H-indole
    —— 1,2-Dithia-cyclododecan 294-67-7 C10H20S2
    1,2-Dithia-cyclododecan
    —— 2-[1-(2-methylsulfanyl-ethylsulfanyl)-heptylsulfanyl]-ethanol 58226-38-3 C12H26OS3
    2-[1-(2-methylsulfanyl-ethylsulfanyl)-heptylsulfanyl]-ethanol
    —— 2-n-Heptylthio-aethanthiol 26718-05-8 C9H20S2
    2-n-Heptylthio-aethanthiol
    —— 1-methoxy-1-(2-methylsulfanyl-ethylsulfanyl)-heptane 58202-96-3 C11H24OS2
    1-methoxy-1-(2-methylsulfanyl-ethylsulfanyl)-heptane
    —— 5-phenyl-2-phenylthiopyrazine-3-carbonitrile 208993-73-1 C17H11N3S
    5-phenyl-2-phenylthiopyrazine-3-carbonitrile
    —— α-thial-methylenecyclopropene 187098-14-2 C5H4S
    α-thial-methylenecyclopropene
    —— 1-Propanol, 2-(decyloxy)-3-(dodecylsulfinyl)- 189140-26-9 C25H52O3S
    1-Propanol, 2-(decyloxy)-3-(dodecylsulfinyl)-
    —— 2-amino-4-(methylthio)phenol 98547-24-1 C7H9NOS
    2-amino-4-(methylthio)phenol
    —— 5'-phenyspiro[adamantane-2,2'(1,3)-oxathiolane] 97462-26-5 C18H22OS
    5'-phenyspiro[adamantane-2,2'(1,3)-oxathiolane]
    —— butyl spiro[adamantane-2,2'-(1,3)-oxathiolane]-5'-carboxylate 97462-28-7 C17H26O3S
    butyl spiro[adamantane-2,2'-(1,3)-oxathiolane]-5'-carboxylate
    —— 2",2",4",4"-tetramethyldispiro[adamantane-2,2'(1,3)-dithiolane-4",3"-cyclobutane]-1"-one 102971-05-1 C19H28OS2
    2",2",4",4"-tetramethyldispiro[adamantane-2,2'(1,3)-dithiolane-4",3"-cyclobutane]-1"-one
    —— 2-methoxy-2-(methylthio)adamantane 97129-84-5 C12H20OS
    2-methoxy-2-(methylthio)adamantane
    —— dispiro9[(1,3)-dithiolane-2',2;4',2"-bis(adamantane)] 99310-98-2 C21H30S2
    dispiro9[(1,3)-dithiolane-2',2;4',2"-bis(adamantane)]
    —— adamantanone Nβ-[2'-(methylthio)adamantyl(2')-thio]-methylenehydrazone 97129-83-4 C22H32N2S2
    adamantanone Nβ-[2'-(methylthio)adamantyl(2')-thio]-methylenehydrazone
    —— adamantanone Nβ-(methylthiomethylene)hydrazone 97129-90-3 C12H18N2S
    adamantanone Nβ-(methylthiomethylene)hydrazone
    —— phenyl(2,2,2-trifluoro-1-phenylethyl)sulfane 123228-00-2 C14H11F3S
    phenyl(2,2,2-trifluoro-1-phenylethyl)sulfane
    —— 2,2-difluorovinyl phenyl sulfide 61698-70-2 C8H6F2S
    2,2-difluorovinyl phenyl sulfide
    —— [(1S)-1-chloro-2,2,2-trifluoroethyl]sulfanylbenzene 114953-71-8 C8H6ClF3S
    [(1S)-1-chloro-2,2,2-trifluoroethyl]sulfanylbenzene
    —— LR-43 412953-74-3 C16H34O3S
    LR-43
    —— 4-acetyl-4-<1-(phenylthio)ethenyl>cyclohexanone 116503-35-6 C16H18O2S
    4-acetyl-4-<1-(phenylthio)ethenyl>cyclohexanone
    —— 6-(1,1-Dioxo-4-phenylsulfanyl-2,5-dihydrothiophen-2-yl)hex-1-en-3-one 197862-50-3 C16H18O3S2
    6-(1,1-Dioxo-4-phenylsulfanyl-2,5-dihydrothiophen-2-yl)hex-1-en-3-one
    —— 2-Acetyl-3-(phenylthio)-1,3-butadiene 116503-24-3 C12H12OS
    2-Acetyl-3-(phenylthio)-1,3-butadiene
    —— (Z)-1,2-bis(phenylthio)-1,3-butadiene 172508-83-7 C16H14S2
    (Z)-1,2-bis(phenylthio)-1,3-butadiene
    —— 2,3-bis(phenylthio)-2-sulfolene 172508-82-6 C16H14O2S3
    2,3-bis(phenylthio)-2-sulfolene
    —— (E)-1,2-bis(phenylthio)-1,3-butadiene 172508-88-2 C16H14S2
    (E)-1,2-bis(phenylthio)-1,3-butadiene
    —— 2-(2-phenylmethyl)-4-(phenylthio)-2,5-dihydrothiophene 1,1-dioxide 110026-89-6 C17H16O2S2
    2-(2-phenylmethyl)-4-(phenylthio)-2,5-dihydrothiophene 1,1-dioxide
    —— 2-bromo-3-phenylthio-2-sulfolene 172508-81-5 C10H9BrO2S2
    2-bromo-3-phenylthio-2-sulfolene
    —— methyl 4-acetyl-5-(phenylthio)-1,4-cyclohexadienecarboxylate 116503-26-5 C16H16O3S
    methyl 4-acetyl-5-(phenylthio)-1,4-cyclohexadienecarboxylate
    —— 2-ethyl-4-(phenylthio)-2,5-dihydrothiophene 1,1-dioxide 110026-87-4 C12H14O2S2
    2-ethyl-4-(phenylthio)-2,5-dihydrothiophene 1,1-dioxide