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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 129573-97-3 C20H18ClN5OS
    —— [1-(2-Bromo-propyl)-3-phenylsulfanylmethyl-but-3-enyloxy]-tert-butyl-dimethyl-silane 133621-21-3 C20H33BrOSSi
    [1-(2-Bromo-propyl)-3-phenylsulfanylmethyl-but-3-enyloxy]-tert-butyl-dimethyl-silane
    —— 4-Amino-6-carboxamido-8-chlor-2-(p-toluoylthio)-pyrido<3,2-d>pyrimidin 68409-39-2 C15H12ClN5OS
    4-Amino-6-carboxamido-8-chlor-2-(p-toluoylthio)-pyrido<3,2-d>pyrimidin
    —— 3.3-Dimethyl-1-morpholino-1-p-tolyl-mercapto-butan-2-on 25847-56-7 C17H25NO2S
    3.3-Dimethyl-1-morpholino-1-p-tolyl-mercapto-butan-2-on
    —— (1<i>H</i>-[1,2,4]triazol-3-ylsulfanyl)-acetic acid <i>N</i>'-(phenyl-thiocarbamoyl)-hydrazide 68350-40-3 C11H12N6OS2
    (1<i>H</i>-[1,2,4]triazol-3-ylsulfanyl)-acetic acid <i>N</i>'-(phenyl-thiocarbamoyl)-hydrazide
    —— N-(2-amino-6-methyl-4-pyrimidinyl)-N-[4-(4-pyridinylsulfanyl)phenyl]amine 570415-26-8 C16H15N5S
    N-(2-amino-6-methyl-4-pyrimidinyl)-N-[4-(4-pyridinylsulfanyl)phenyl]amine
    —— (2-Phenylsulfanyl-cyclopentyl)-acetic acid 2-thioxo-2H-pyridin-1-yl ester 125115-32-4 C18H19NO2S2
    (2-Phenylsulfanyl-cyclopentyl)-acetic acid 2-thioxo-2H-pyridin-1-yl ester
    —— N-(2-Chlormethyl-2-propenylsulfinyl)nonafluorbutansulfonamid 81718-52-7 C8H7ClF9NO3S2
    N-(2-Chlormethyl-2-propenylsulfinyl)nonafluorbutansulfonamid
    —— 1-(1-Phenylsulfanyl-cyclopropyl)-prop-2-en-1-ol 728917-60-0 C12H14OS
    1-(1-Phenylsulfanyl-cyclopropyl)-prop-2-en-1-ol
    —— (E)-2,4,4,5-tetramethyl-8-phenylthio-6-octen-3-one 137346-10-2 C18H26OS
    (E)-2,4,4,5-tetramethyl-8-phenylthio-6-octen-3-one
    —— 1-[3-(4-phenylsulfanyl-phenyl)-allyl]-1<i>H</i>-imidazole 69965-19-1 C18H16N2S
    1-[3-(4-phenylsulfanyl-phenyl)-allyl]-1<i>H</i>-imidazole
    —— 7,7-Dichloro-2-phenylsulfanyl-bicyclo[3.2.0]hept-3-en-6-one 79308-00-2 C13H10Cl2OS
    7,7-Dichloro-2-phenylsulfanyl-bicyclo[3.2.0]hept-3-en-6-one
    —— 4-[4-(2,5-difluoro-benzyloxy)-2-(pyrido[2,3-d]pyrimidin-4-ylamino)-phenylsulfanyl]-phenol 944506-25-6 C26H18F2N4O2S
    4-[4-(2,5-difluoro-benzyloxy)-2-(pyrido[2,3-d]pyrimidin-4-ylamino)-phenylsulfanyl]-phenol
    —— 2,5-bis(3,5-difluorophenylsulfanyl)benzonitrile 1118652-71-3 C19H9F4NS2
    2,5-bis(3,5-difluorophenylsulfanyl)benzonitrile
    —— 1027356-05-3 C24H52O2S2Si2
    —— 1,4-bis-pentylsulfanyl-but-1-ene 53943-14-9 C14H28S2
    1,4-bis-pentylsulfanyl-but-1-ene
    —— 2-(N-Phenylamino)-6-phenylthiomethyl-5,6-dihydro-4H-1,3-thiazine 127040-82-8 C17H18N2S2
    2-(N-Phenylamino)-6-phenylthiomethyl-5,6-dihydro-4H-1,3-thiazine
    —— ethyl 3-(3-amino-4-cyano-5-((2,4-difluorobenzyl)thio)thiophen-2-yl)-3-oxopropanoate 1200833-76-6 C17H14F2N2O3S2
    ethyl 3-(3-amino-4-cyano-5-((2,4-difluorobenzyl)thio)thiophen-2-yl)-3-oxopropanoate
    —— 2-tert-butyl-6-(3-tert-butyl-5-methyl-2-oxidophenyl)sulfanyl-4-methylphenolate;propan-2-olate;titanium(4+) 183021-92-3 C56H84O8S2Ti2
    2-tert-butyl-6-(3-tert-butyl-5-methyl-2-oxidophenyl)sulfanyl-4-methylphenolate;propan-2-olate;titanium(4+)
    —— cobalt(3+);cyclopenta-1,3-diene;(Z)-3-methoxy-3-oxo-2-(trimethylsilylmethylsulfanyl)prop-1-ene-1-thiolate 219305-03-0 C13H19CoO2S2Si
    cobalt(3+);cyclopenta-1,3-diene;(Z)-3-methoxy-3-oxo-2-(trimethylsilylmethylsulfanyl)prop-1-ene-1-thiolate
    —— Phenylsulfanyl-acetic acid (4-hydroxyimino-cyclohexa-2,5-dienylidene)-hydrazide 57487-18-0 C14H13N3O2S
    Phenylsulfanyl-acetic acid (4-hydroxyimino-cyclohexa-2,5-dienylidene)-hydrazide
    —— <i>N</i>-(4-<i>tert</i>-butylamino-6-phenylsulfanyl-[1,3,5]triazin-2-yl)-propionamide 37623-72-6 C16H21N5OS
    <i>N</i>-(4-<i>tert</i>-butylamino-6-phenylsulfanyl-[1,3,5]triazin-2-yl)-propionamide
    —— Lithium; dithiobutyrate 74670-33-0 C4H7S2*Li
    Lithium; dithiobutyrate
    —— Ethyl-phosphonothioic acid O-ethyl ester O-(6-methylsulfanyl-pyridazin-3-yl) ester 66089-55-2 C9H15N2O2PS2
    Ethyl-phosphonothioic acid O-ethyl ester O-(6-methylsulfanyl-pyridazin-3-yl) ester
    —— cyclohexyl-(cyclohexylsulfanylmethyl)-phenylimino-λ4-sulfane 102334-15-6 C19H29NS2
    cyclohexyl-(cyclohexylsulfanylmethyl)-phenylimino-λ4-sulfane
    —— syn-2-Methyl-2-phenylthiocyclooctanol 104281-60-9 C15H22OS
    syn-2-Methyl-2-phenylthiocyclooctanol
    —— 4-Hydroxybutyldecylsulfid 68749-09-7 C14H30OS
    4-Hydroxybutyldecylsulfid
    —— 3-(allyloxy)-1-isopropyl-2-(methylsulfanyl)pyrrole 1337541-58-8 C11H17NOS
    3-(allyloxy)-1-isopropyl-2-(methylsulfanyl)pyrrole
    —— sodium (5R)-2-<1-(2-hydroxyethyl)-1H-tetrazol-5-yl>thiomethyl-6-<(E)-1-(hydroxymethyl)ethylidene>penem-3-carboxylate 97129-28-7 C13H14N5O5S2*Na
    sodium (5R)-2-<1-(2-hydroxyethyl)-1H-tetrazol-5-yl>thiomethyl-6-<(E)-1-(hydroxymethyl)ethylidene>penem-3-carboxylate
    —— Dithiophosphoric acid O-ethyl ester S-(2-methylsulfanyl-butyl) ester S'-propyl ester 32065-09-1 C10H23O2PS3
    Dithiophosphoric acid O-ethyl ester S-(2-methylsulfanyl-butyl) ester S'-propyl ester
    —— 1092529-56-0 C24H27FO3S
    —— cyclopenta-1,3-diene;iodocobalt(2+);(Z)-3-methoxy-2-methylsulfanyl-3-oxoprop-1-ene-1-thiolate 219137-34-5 C10H12CoIO2S2
    cyclopenta-1,3-diene;iodocobalt(2+);(Z)-3-methoxy-2-methylsulfanyl-3-oxoprop-1-ene-1-thiolate
    —— 2-adamantyl allyl sulfide 65566-48-5 C13H20S
    2-adamantyl allyl sulfide
    —— 2-[o-(thioethyl)phenylazo]imidazole 887114-96-7 C11H12N4S
    2-[o-(thioethyl)phenylazo]imidazole
    —— ethyl 2-phenylsulfanylheptadec-4-enoate 101125-43-3 C25H40O2S
    ethyl 2-phenylsulfanylheptadec-4-enoate
    —— 35206-98-5 C3H6Cl3N3O
    —— Tetraethylthioformalazin 34817-52-2 C10H20N2S4
    Tetraethylthioformalazin
    —— cyclopentyl(4-(methylamino)-2-(methylthio)pyrimidin-5-yl)methanone 1584151-25-6 C12H17N3OS
    cyclopentyl(4-(methylamino)-2-(methylthio)pyrimidin-5-yl)methanone
    —— tris(dodecylthiomethyl)(bromomethyl)methane 105198-28-5 C41H83BrS3
    tris(dodecylthiomethyl)(bromomethyl)methane
    —— n-butyltin(IV)tris(N,N-diethylmonothiocarbamate) 86292-33-3 C19H39N3O3S3Sn
    n-butyltin(IV)tris(N,N-diethylmonothiocarbamate)
    —— 1-(3-(allylsulfonyl)prop-1-en-1-yl)-2-phenyldisulfane 1380688-19-6 C12H14O2S3
    1-(3-(allylsulfonyl)prop-1-en-1-yl)-2-phenyldisulfane
    —— 2-(Methylsulfonylmethyl)-acrylnitril 89323-92-2 C5H7NO2S
    2-(Methylsulfonylmethyl)-acrylnitril
    —— 7-Chloro-1-methoxy-7-phenylsulfanyl-bicyclo[4.1.0]heptane 68002-07-3 C14H17ClOS
    7-Chloro-1-methoxy-7-phenylsulfanyl-bicyclo[4.1.0]heptane
    —— Thiocyanatomethyl-aethylsulfid 13880-77-8 C4H7NS2
    Thiocyanatomethyl-aethylsulfid
    —— <i>trans</i>-1,2-bis-<i>tert</i>-butylsulfanyl-ethene 83173-54-0 C10H20S2
    <i>trans</i>-1,2-bis-<i>tert</i>-butylsulfanyl-ethene
    —— (isothiocyanatomethyl)cyclobutane 1095592-84-9 C6H9NS
    (isothiocyanatomethyl)cyclobutane
    —— 3-(2-methanesulfinyl-1-methyl-2-methylsulfanyl-ethyl)-octan-2-one 67148-26-9 C13H26O2S2
    3-(2-methanesulfinyl-1-methyl-2-methylsulfanyl-ethyl)-octan-2-one
    —— 1-(phenylthio)hept-2-yn-4-ol 122663-89-2 C13H16OS
    1-(phenylthio)hept-2-yn-4-ol
    —— cis-1-Brom-2-isopropylthioethen 53715-33-6 C5H9BrS
    cis-1-Brom-2-isopropylthioethen
    —— <i>tert</i>-butoxy-<i>tert</i>-butylsulfanyl-methyl 62285-19-2 C9H19OS
    <i>tert</i>-butoxy-<i>tert</i>-butylsulfanyl-methyl